Preparation of phosphorus containing products by co-incineration of sludge ash and calcium-based additives: Focusing one-step and multi-step method.

Due to the irreplaceable nature of phosphorus (P) in biological growth and the shortage of P rock, it is necessary to recover P from waste, such as sludge ash. P-containing products were prepared using sludge ash and calcium-based additives (CaCO3 and eggshell). In addition, the effects of different incineration methods (one-step method (OSM) and multi-step method (MSM)), additive doses, and incineration temperature on the P content and species in the products were investigated. The results indicated that as the dose of calcium-based additives increased, total P (TP) content in P-containing products reduced, apatite P (AP) content increased, non-apatite P (NAIP) content declined, and P solubility in citric acid content decreased. The amount of AP increased, NAIP reduced, and P solubility in citric acid decreased as the incineration temperature climbed. Although P in P-containing products prepared by OSM and MSM changed in a similar way at different additive doses and temperatures, P-containing products prepared by MSM had at least a 6.1% increase in P solubility in citric acid. Compared with OSM, MSM could save 10% of calcium-based additives when reaching the maximum AP value. Additionally, pure materials were employed to investigate how P species changed during the incineration procedure. The advantage of the MSM-prepared product over the OSM-prepared product may be explained by the high concentration of Ca3(PO4)2 and low concentration of amorphous calcium bound P (Ca-P). Overall, MSM is an effective method to reduce the dose of calcium-based additives and increase the bioavailability of P in P-containing products.

Phosphorus recovery from incinerated sewage sludge ash using electrodialysis coupled with plant extractant enhancement technology.

Phosphorus (P) is an integral mineral nutrient for the growth of plants and animals. As the increasing population worldwide, the demand for P resources keeps increasing. Therefore, it is necessary to recover P from secondary resources. Unlike conventional P recovery processes, this work focused on the recovery of P from incinerated sewage sludge ash (ISSA) using electrodialysis as the main technology coupled with plant extractants. In this study, Amaranthus and hydrolyzed polymaleic anhydride (HPMA) were used as P extractants, investigating the effects of HPMA concentration and pH of the compound agent on the migration of P and heavy metals from ISSA. The results showed that the concentration of HPMA and pH of the compound agent had a significant influence on the mobility of P and heavy metals. Meanwhile, the impacts of eggshell additions and voltage on the recovery efficiency of P was also studied by using waste eggshells as calcium sources. We found that when eggshells were added at 10 g/L and the voltage was 10 V, the recovery efficiency of P reached 96.05%. Moreover, XRD patterns revealed that the mineral phase of recovered P-containing products was predominantly hydroxyapatite, which had good environmental benefits. Generally, the favorable results have been achieved in the recovery efficiency of P and has practical implications for P recovery from ISSA.

Transformation of phosphorus by MgCl2 and CaCl2 during sewage sludge incineration.

Phosphorus (P) recovery from sewage sludge (SS) have been regarded as an effective method of P recycling. The effects of incineration temperature, incineration time, and chlorine additives on the distribution of P speciation during sludge incineration were studied. Moreover, the reactions between model compounds AlPO4 and additives (MgCl2 and CaCl2) were investigated by thermogravimetric differential thermal analysis and X-ray diffraction measurements. The results demonstrated that the increase in temperature and time stimulated the volatilization of non-apatite inorganic phosphorus (NAIP) instead of apatite phosphorus (AP). MgCl2 and CaCl2 can greatly promote the conversion of NAIP to AP. Additionally, AlPO4 reacted with MgCl2 are incinerated at 500-600 °C to form Mg3(PO4)2, which is mainly due to the reaction of the intermediate product MgO and AlPO4. Reactions between AlPO4 and CaCl2 occurred at 700-750 °C and produced Ca2PO4Cl, which can be directly used with high bioavailability. These findings suggested that chlorine additives in the SS incineration process can obtain phosphorus-containing minerals with higher bioavailability to realize the resource utilization of P in sludge.

An efficient strategy of phosphorus recovery: Electrochemical pretreatment enhanced the anaerobic fermentation of waste activated sludge.

The anaerobic fermentation (AF) of waste activated sludge (WAS) with an electrochemical pretreatment (EPT) was investigated to determine its correlation with the release of phosphorus and the disintegration of WAS. The sludge was pretreated by holding under 4.5 V for 60 min, followed by AF for 9 days. Untreated sludge was used as the control group (no-EPT). Results showed that, with pretreatment, the total dissolved P (TDP), orthophosphate (PO43--P) and organic P (OP) reached the maximum values of 7.30 mg/L, 4.77 mg/L and 2.35 mg/L on day 8, respectively, which were approximately 5.3, 9.2 and 2.7 times greater than that in the control group. The analysis of soluble chemical oxygen demand (SCOD), protein and polysaccharides showed that the EPT promoted the disintegration of sludge, thereby enhancing the P release. The SCOD reached 1625 mg/L on day 6 in pretreatment experiment, which was about 9.8 times greater than that in control group. Additionally, the EPT contributed to fewer metal ions in sludge supernatant. This mechanism might have been due to the anions accumulating in the supernatant from the greater degree of sludge collapse after EPT, which caused the released metal ions to combine with anions to form insoluble compounds. In conclusion, EPT could be a promising method for the dissolution of sludge and the recovery of phosphorus from WAS under AF. Besides, the economic benefit evaluation showed the potential value of EPT for P recovery.