Halloysite nanotubes enhanced polyimide/oxidized-lignin nanofiber separators for long-cycling lithium metal batteries.

The high energy density and robust cycle properties of lithium-ion batteries contribute to their extensive range of applications. Polyolefin separators are often used for the purpose of storing electrolytes, hence ensuring the efficient internal ion transport. Nevertheless, the electrochemical performance of lithium-ion batteries is constrained by its limited interaction with electrolytes and poor capacity for cation transport. This work presents the preparation of a new bio-based nanofiber separator by combining oxidized lignin (OL) and halloysite nanotubes (HNTs) with polyimide (PI) using an electrospinning technique. Analysis was conducted to examine and compare the structure, morphology, thermal characteristics, and EIS of the separator with those of commercially available polypropylene separator (PP). The results indicate that the PI@OL and PI-OL@ 10 % HNTs separators exhibit higher lithium ion transference number and ionic conductivity. Moreover, the use of HNTs successfully impeded the proliferation of lithium dendrites, hence exerting a beneficial impact on both the cycle performance and multiplier performance of the battery. Consequently, after undergoing 300 iterations, the battery capacity of LiFePO4|PI-OL@ 10 % HNTs|Li stays at 92.1 %, surpassing that of PP (86.8 %) and PI@OL (89.6 %). These findings indicate that this new bio-based battery separator (PI-OL@HNTs) has the great potential to serve as a substitute for the commonly used PP separator in lithium metal batteries.

Effect of Nasal Inhalation on Drug Particle Deposition and Size Distribution in the Upper Airway: With Soft Mist Inhalers.

Delivery of drugs to the lungs is commonly achieved using nasal and/or oral breathing-assisted techniques. The route of inhalation can substantially change the fate of inhaled droplets. The Respimat® Soft Mist™ Inhaler (SMI) is a commercially available efficient inhaler with 40-60% effectiveness. In the present study, we used computational fluid dynamics (CFD) with a custom setup to investigate the effect of a combined oral/nasal inhalation route on the SMI's regional droplet deposition, size distribution, and flow field. Our setup used a modified induction port (MIP) to mimic nasal inhalation inside the human respiratory tract. Six different oral/nasal flow rate ratios inside the MIP were applied (total flow rate of 30 l/min). An overall good agreement was achieved between simulation outcomes and in vitro results. Our results confirmed that the combined inhalation route affects the flow field, altering the MIP's droplet deposition and size distribution. The lowest depositional loss, mainly in the mouth area, was observed at oral/nasal flow rate ratios of O/N = 1 and O/N = 2 with 3% and 7.7% values, respectively. Droplets with a 2-5 µm diameter range showed the highest droplet mass inside the MIP at all combined flow rates. We observed less intense vortexes followed by a lower level of turbulent kinetic energy at the oral/nasal ratio of 1. Increasing the relative humidity (RH) at oral/nasal flow rate ratios of 0.07, 1, and 14 led to an increase in droplet deposition at the outlet of the MIP.

Production and characterization of starch-lignin based materials: A review.

In their pristine state, starch and lignin are abundant and inexpensive natural polymers frequently considered green alternatives to oil-based and synthetic polymers. Despite their availability and owing to their physicochemical properties; starch and lignin are not often utilized in their pristine forms for high-performance applications. Generally, chemical and physical modifications transform them into starch- and lignin-based materials with broadened properties and functionality. In the last decade, the combination of starch and lignin for producing reinforced materials has gained significant attention. The reinforcing of starch matrices with lignin has received primary focus because of the enhanced water sensitivity, UV protection, and mechanical and thermal resistance that lignin introduces to starch-based materials. This review paper aims to assess starch-lignin materials' production and characterization technologies, highlighting their physicochemical properties, outcomes, challenges, and opportunities. First, this paper describes the current status, sources, and chemical modifications of lignin and starch. Next, the discussion is oriented toward starch-lignin materials and their production approaches, such as blends, composites, plasticized/crosslinked films, and coupled polymers. Special attention is given to the characterization methods of starch-lignin materials, focusing on their advantages, disadvantages, and expected outcomes. Finally, the challenges, opportunities, and future perspectives in developing starch-lignin materials, such as adhesives, coatings, films, and controlled delivery systems, are discussed.

Fractionated lignin as a polyol in polyurethane fabrication.

The main purpose of this paper was to systematically evaluate the effect of lignin, which was fractioned by green solvents into different molecular weights and used as polyol in the production of polyurethane foams (PUF). The results indicated that the foams prepared with the lower molecular weight lignin had uniform and complete pore structure and improved the mechanical strength. However, the higher molecular weight fraction lignin improved the density and thermal stability of the foam more significantly at the expense of inferior mechanical strength and pore structure deficiency. When the substitution degree of lignin in the PUF was 2 %-30 %, 99.13 % of the lowest molecular weight lignin was participated in the reaction to produce PUF, which improved the elongation at break (Eb) and tensile strength (Ts) of PUF to 834 % and 0.90 MPa, respectively. Also, thermal stability and the amount of unreacted lignin in PUF were increased at a higher substitution degree of lignin in PUF.

Dual lignin-derived polymeric system for peptone removal from simulated wastewater.

The long-term existence of peptone can breed a large number of bacteria and cause the eutrophication of municipal wastewater. Thus, removing peptone in the wastewater is a major challenge facing the current industry. This study used cationic and anionic lignin polymers, i.e., kraft lignin-[2-(methacryloyloxy)ethyl] trimethylammonium methyl sulfate (cationic lignin polymer, CLP) and kraft lignin-acrylic acid (anionic lignin polymer, ALP), as flocculants to eliminate peptone from model wastewater in the single and dual component systems. The affinity of peptone for ALP or CLP was assessed by quartz crystal microbalance with dissipation, X-ray photoelectron spectroscopy, contact angle, and vertical scan analyzer. Results illustrated that the adsorption effect of CLP for peptone was significantly superior to that of ALP owing to the stronger vital interaction between cationic polymer and peptone molecules. Based on destabilization and sedimentation analyses, introducing CLP triggered the preliminary flocculation of peptone via bridging action, as indicated by a considerable increment in the destabilization index (from 1.1 to 10.6). Moreover, peptone adsorbed more on the CLP coated surface than on the ALP coated one (14.8 vs 5.4 mg/m2), while ALP facilitated its further adsorption in the dual polymer system. This is because CLP adsorbed a part of peptone molecules on its surface. Then, ALP entrapped the unattached peptone onto the CLP coated surface through electrostatic interaction. Compared with the single polymer system, mixing ALP and CLP subsequently into the peptone solution in the dual system generated larger size aggregates (mean diameter of 6.1 µm) and made the system destabilization (Turbiscan stability index up to 58.1), thereby yielding more flocculation and sedimentation. Finally, peptone was removed successfully from simulated wastewater with a turbidity removal efficiency of 92.5%. These findings confirmed that the dual-component system containing two lignin-derived polymers with opposite charges could be viable for treating peptone wastewater.

Surface properties of membrane materials and their role in cell adhesion and biofilm formation of microalgae.

In this study, the effects of surface properties of membrane materials on microalgae cell adhesion and biofilm formation were investigated using Chlorella vulgaris and five different types of membrane materials under hydrodynamic conditions. The results suggest that the contact angle (hydrophobicity), surface free energy, and free energy of cohesion of membrane materials alone could not sufficiently elucidate the selectivity of microalgae cell adhesion and biofilm formation on membrane materials surfaces, and membrane surface roughness played a dominant role in controlling biofilm formation rate, under tested hydrodynamic conditions. A lower level of biofilm EPS production was generally associated with a larger amount of biofilm formation. The zeta potential of membrane materials could enhance initial microalgae cell adhesion and biofilm formation through salt bridging or charge neutralization mechanisms.

A post-sulfonated one-pot synthesized magnetic cellulose nanocomposite for Knoevenagel and Thorpe-Ziegler reactions.

The development of biodegradable and active cellulosic-based heterogeneous catalysts for the synthesis of different organic compounds would be attractive in pharmaceutical and petrochemical-related industries. Herein, a post-sulfonated composite of one-pot synthesized magnetite (Fe3O4) and cellulose nanocrystals (CNCs) was used as an effective and easily separable heterogeneous catalyst for activating the Knoevenagel and Thorpe-Ziegler reactions. The composite was developed hydrothermally from microcrystalline cellulose (MCC), iron chlorides, urea, and hydrochloric acid at 180 °C for 20 h in a one-pot reaction. After collecting the magnetic CNCs (MCNCs), post-sulfonation was performed using chlorosulfonic acid (ClSO3H) in DMF at room temperature producing sulfonated MCNCs (SMCNCs). The results confirmed the presence of sulfonated Fe3O4 and CNCs with a hydrodynamic size of 391 nm (±25). The presence of cellulose was beneficial for preventing Fe3O4 oxidation or the formation of agglomerations without requiring the presence of capping agents, organic solvents, or an inert environment. The SMCNC catalyst was applied to activate the Knoevenagel condensation and the Thorpe-Ziegler reaction with determining the optimal reaction conditions. The presence of the SMCNC catalyst facilitated these transformations under green procedures, which enabled us to synthesize a new series of olefins and thienopyridines, and the yields of some isolated olefins and thienopyridines were up to 99% and 95%, respectively. Besides, the catalyst was stable for five cycles without a significant decrease in its reactivity, and the mechanistic routes of both reactions on the SMCNCs were postulated.

Microalgae cell adhesions on hydrophobic membrane substrates using quartz crystal microbalance with dissipation.

Microalgal cell adhesion and biofilm formation are affected by interactions between microalgae strains and membrane materials. Variations of surface properties of microalgae and membrane materials are expected to affect cell-membranes and cell-cell interactions and thus initial microalgal cell adhesion and biofilm formation rates. Hence, it should be possible to identify the dominant mechanisms controlling microalgal cell adhesion and biofilm formation. The effects of surface properties of three different microalgal strains and three different types of membrane materials on microalgal cell adhesion and biofilm formation were systematically investigated in real time by monitoring changes in the oscillation frequency and dissipation of the quartz crystal resonator (QCM-D). The results revealed that in general a higher surface free energy, more negative zeta potential, and higher surface roughness of membrane materials positively correlated with a larger quantity of microalgae cell deposition, while a more hydrophilic microalgae with a larger negative zeta potential preferred to attach to a more hydrophobic membrane material. The adhered microalgal layers exhibited viscoelastic properties. The relative importance of these mechanisms in controlling microalgae cell attachment and biofilm formation might vary, depending on the properties of specific microalgae species and hydrophobic membrane materials used.

A new solvent-free pathway for inducing quaternized lignin-derived high molecular weight polymer.

In this work, kraft lignin (KL) was polymerized with vinylbenzyl chloride (VBC) in a molar ratio of 1.8:1 (KL: VBC) using sodium persulfate (Na2S2O8) as an initiator at pH 9-10 and temperature of 80-90 °C for 3 h to produce polymer kraft lignin-g-poly(4-vinylbenzyl chloride) KL-poly(VBC) 1. Then, the grafting reaction was conducted with two different imidazole-based monomers of different side-chain lengths (methyl and n-butyl), namely, 1-methylimidazole (MIM), 1-n-butylimidazole (BIM), which led to the formation of novel polymers, kraft lignin-g-poly(4-vinylbenzyl-1-methylimidazolium chloride) KL-poly(VBC-MIM) 2a and kraft lignin-g-poly(4-vinylbenzyl-1-n-butyl imidazolium chloride) KL-poly(VBC-BIM) 2b. The polymer 2a generated a larger molecular weight polymer with a higher charge density and solubility than polymer 2b since the n-butyl group would cause steric hindrance and weaker monomer to react with intermediate polymer 1 in the second stage. The contact angle analysis confirmed more hydrophilicity of polymer 2a, and elemental analysis confirmed the more successful polymerization of polymer 2a. Applying the generated polymers as flocculants for a kaolin suspension confirmed that polymer 2a had similar performance with commercial cationic polyacrylamide (CPAM) flocculants, even though polymer 2a had a smaller molecular weight. This polymerization offers a promising pathway for generating cationic polymers with excellent performance as a flocculant for suspensions.

In Situ Copolymerization Studies of Lignin, Acrylamide, and Diallyldimethylammonium Chloride: Mechanism, Kinetics, and Rheology.

In this work, free-radical polymerization of kraft lignin, acrylamide (AM), and diallyldimethylammonium chloride (DADMAC) was studied in detail. In situ nuclear magnetic resonance (NMR), rheological analysis, and particle size techniques were conducted to understand the physicochemical characteristics of this copolymerization system. The copolymerization of lignin-AM and lignin-DADMAC had activation energies of 65.7 and 69.3 kJ/mol, respectively, and followed the first-order kinetic model, which was monitored by in situ H1 NMR results. The highest conversions of AM and DADMAC were 96 and 68%, respectively, in the copolymerization of lignin, AM, and DADMAC at the molar ratio of 5.5:2.4:1, pH 2 and 85 °C. The results illustrated that the participation of AM in the reaction was essential for polymerizing DADMAC to lignin due to less steric hindrance of AM than DADMAC facilitating its bridging performance. The monomer conversion ratio and dynamic rheology of the reaction system indicated that lignin acted as an inhibitor in the copolymerization reaction. The particle size analysis of the reaction mixtures reflected the alteration in the size of particles from coarse particles (>300 µm) to fine particles (<10 and 10-50 µm) and suspension to colloidal systems when the reaction progressed. The oscillation study of the reaction media confirmed the gradual increase in the viscosity of the reaction media, illustrating the crosslinking of lignin, AM, and DADMAC.

Production of nanocellulose using acidic deep eutectic solvents based on choline chloride and carboxylic acids: A review.

Nowadays, nanocellulose production processes with numerous merits of green, eco-friendly, and cost-effective are in urgent need. Acidic deep eutectic solvent (ADES), as an emerging green solvent, has been widely applied in the preparation of nanocellulose over the past few years, owing to its unique advantages, including non-toxicity, low cost, easy synthesis, recyclability, and biodegradability. At present, several studies have explored the effectiveness of ADESs in nanocellulose production, particularly those based on choline chloride (ChCl) and carboxylic acids. Various acidic deep eutectic solvents have been employed, with representative ones such as ChCl-oxalic/lactic/formic/acetic/citric/maleic/levulinic/tartaric acid. Herein, we comprehensively reviewed the latest progress of these ADESs, focusing on the treatment procedures and key superiorities. In addition, the challenges and outlooks of ChCl/carboxylic acids-based DESs implementation in the fabrication of nanocellulose were discussed. Finally, some suggestions were proposed to advance the industrialization of nanocellulose, which would help for the roadmap of sustainable and large-scale production of nanocellulose.

MXene/bacterial cellulose/Fe3O4/methyltrimethoxylsilane flexible film with hydrophobic for effective electromagnetic shielding.

Electromagnetic (EM) pollution has become a serious problem in modern society as it affects human lives. The fabrication of strong and highly flexible materials for electromagnetic interference (EMI) shielding applications is extremely urgent. Herein, a MXene Ti3C2Tx/Fe3O4 & bacterial cellulose (BC)/Fe3O4&Methyltrimethoxysilane (MTMS) flexible hydrophobic electromagnetic shielding film (SBTFX-Y, X and Y were the number of layers of BC/Fe3O4 and the layers of Ti3C2Tx/Fe3O4), was fabricated. In the prepared film, MXene Ti3C2Tx absorbs a large amount of radio waves through polarization relaxation and conduction loss. Because of its extremely low reflectance of electromagnetic waves, BC@Fe3O4, as the outermost layer of the material, allows more electromagnetic waves to incident inside the material. The maximum electromagnetic interference (EMI) shielding efficiency (SE) of 68 dB was achieved for the composite film at 45 µm thickness. What's more, the SBTFX-Y films show excellent mechanical properties, hydrophobicity and flexibility. The unique stratified structure of the film provides a new strategy for designing high-performance EMI shielding films with excellent surface and mechanical properties.

Temperature responsive crosslinked starch-kraft lignin macromolecule.

Starch is a natural polymer with a relatively simple structure and limited solubility in water. Kraft lignin (KL) is a complex biopolymer obtained as a by-product from the delignification of wood and grasses. The present work reports developing a temperature-responsive high molecular weight macromolecule from crosslinking KL and starch (KLS). The NMR and XPS analyses quantified the changes in the aromatic and anhydroglucose units of KL and starch, observing a higher content of C-O-C bonds, which confirms the presence of glycerol ether cross-linkages between starch and KL in KLS. The rheological analysis of KLS dispersions revealed the formation of a thermo-responsive structured network. The temperature-dependent water solubility and rheological characteristics of KLS were related to the presence of hydrophilic starch chains, crosslinking degree, and physicochemical characteristics of KL. The incorporation of KL and ether crosslinks increased the thermal stability of KLS. Because of its multiple functional groups and large molecular weight (3.6-4.2 × 105 g/mol) that was arranged in an extended globular shape, KLS-5 formed a gel-like structure after a heating-cooling treatment. Overall, the results confirmed that incorporating lignin in starch would fabricate sustainable materials with potentially altered applications, such as temperature-responsive hydrogels and films.

Deep learning-based electrocardiographic screening for chronic kidney disease.

BACKGROUND: Undiagnosed chronic kidney disease (CKD) is a common and usually asymptomatic disorder that causes a high burden of morbidity and early mortality worldwide. We developed a deep learning model for CKD screening from routinely acquired ECGs. METHODS: We collected data from a primary cohort with 111,370 patients which had 247,655 ECGs between 2005 and 2019. Using this data, we developed, trained, validated, and tested a deep learning model to predict whether an ECG was taken within one year of the patient receiving a CKD diagnosis. The model was additionally validated using an external cohort from another healthcare system which had 312,145 patients with 896,620 ECGs between 2005 and 2018. RESULTS: Using 12-lead ECG waveforms, our deep learning algorithm achieves discrimination for CKD of any stage with an AUC of 0.767 (95% CI 0.760-0.773) in a held-out test set and an AUC of 0.709 (0.708-0.710) in the external cohort. Our 12-lead ECG-based model performance is consistent across the severity of CKD, with an AUC of 0.753 (0.735-0.770) for mild CKD, AUC of 0.759 (0.750-0.767) for moderate-severe CKD, and an AUC of 0.783 (0.773-0.793) for ESRD. In patients under 60 years old, our model achieves high performance in detecting any stage CKD with both 12-lead (AUC 0.843 [0.836-0.852]) and 1-lead ECG waveform (0.824 [0.815-0.832]). CONCLUSIONS: Our deep learning algorithm is able to detect CKD using ECG waveforms, with stronger performance in younger patients and more severe CKD stages. This ECG algorithm has the potential to augment screening for CKD.

Chronic kidney disease (CKD) is a common condition involving loss of kidney function over time and results in a substantial number of deaths. However, CKD often has no symptoms during its early stages. To detect CKD earlier, we developed a computational approach for CKD screening using routinely acquired electrocardiograms (ECGs), a cheap, rapid, non-invasive, and commonly obtained test of the heart's electrical activity. Our model achieved good accuracy in identifying any stage of CKD, with especially high accuracy in younger patients and more severe stages of CKD. Given the high global burden of undiagnosed CKD, novel and accessible CKD screening strategies have the potential to help prevent disease progression and reduce premature deaths related to CKD.

Influence of structure and functional group of modified kraft lignin on adsorption behavior of dye.

Utilization of kraft lignin to produce bio-based adsorptive material for effective dye adsorption from industrial wastewater is essential to fulfilling the significant environmental protection needs. Lignin is the most abundant byproduct material with a chemical structure containing various functional groups. However, the complicated chemical structure makes it somewhat hydrophobic and incompatible, which limits its direct application as an adsorption material. Chemical modification is a common way to enhance lignin properties. In this work, the kraft lignin was modified through direct amination using Mannich reaction and oxidization followed by amination as new route of lignin modification. The prepared lignins, including aminated lignin (AL), oxidized lignin (OL), and aminated-oxidized lignin (AOL), as well as unmodified kraft lignin, were analyzed by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), elemental analysis and 1H-nuclear magnetic resonance measurements (1HNMR). The adsorption behaviors of modified lignins for the malachite green in aqueous solution were investigated well and discussed, as well as the adsorption kinetics and thermodynamic equations. Compared with other aminated lignin (AL), the AOL displayed a high adsorption capacity of 99.1 % dye removal, due to its more effective functional groups. The change in structure and functional groups on the lignin molecules during oxidation and amination had no effect on its adsorption mechanisms. The adsorption process of malachite green on different kinds of lignin belongs to endothermic chemical adsorption, which mainly consists of monolayer adsorption. The modification of lignin through oxidation followed by amination process, afforded kraft lignin a broad potential application in the field of wastewater treatment.

Latest development in the fabrication and use of lignin-derived humic acid.

Humic substances (HS) are originated from naturally decaying biomass. The main products of HS are humic acids, fulvic acids, and humins. HS are extracted from natural origins (e.g., coals, lignite, forest, and river sediments). However, the production of HS from these resources is not environmentally friendly, potentially impacting ecological systems. Earlier theories claimed that the HS might be transformed from lignin by enzymatic or aerobic oxidation. On the other hand, lignin is a by-product of pulp and paper production processes and is available commercially. However, it is still under-utilized. To address the challenges of producing environmentally friendly HS and accommodating lignin in valorized processes, the production of lignin-derived HS has attracted attention. Currently, several chemical modification pathways can be followed to convert lignin into HS-like materials, such as alkaline aerobic oxidation, alkaline oxidative digestion, and oxidative ammonolysis of lignin. This review paper discusses the fundamental aspects of lignin transformation to HS comprehensively. The applications of natural HS and lignin-derived HS in various fields, such as soil enrichment, fertilizers, wastewater treatment, water decontamination, and medicines, were comprehensively discussed. Furthermore, the current challenges associated with the production and use of HS from lignin were described.

Evaluation of Soft Mist Inhaler Aerosol Velocity, Size, and Deposition Inside the Mouth-A Computational Fluid Dynamics Study.

Respiratory diseases debilitate more than 250 million people around the world. Among available inhalation devices, the soft mist inhaler (SMI) is the most efficient at delivering drugs to ease respiratory disease symptoms. In this study, we analyzed the SMI performance in terms of the aerosol's velocity profiles, flow pattern, size distribution, and deposition by employing computational fluid dynamics (CFD) simulations. We modeled two different simplified mouth geometries, idealized mouth (IM), and standard mouth (SM). Three different locations (x = 0, x = 5, and x = 10 mm) for the SMI nozzle orifice were chosen along the mouth cavity centerlines, followed by two different SMI nozzle angles (10 deg and 20 deg) for IM geometry. A flowrate of 30 L/min was applied. The simulation results were evaluated against experimental data. It was found that the SMI could be simulated successfully with a level of error of less than 10%. The inhalation flowrate significantly impacted the aerosol's velocity profile and deposition efficiency on both the IM and SM walls. The lowest particle deposition on the mouth wall occurred when a fixed flowrate (30 L/min) was applied inside both geometries, and the SMI nozzle position moved forward to x = 10 mm from the IM and SM inlets. An increase in the SMI nozzle angle increased particle deposition and decreased the deposition fraction for particles with a diameter above 5 µm inside the IM.

One-pot synthesis of magnetic cellulose nanocrystal and its post-functionalization for doxycycline adsorption.

The composite of magnetite (Fe3O4) and cellulose nanocrystal (CNC) is considered a potential adsorbent for water treatment and environmental remediation. In the current study, a one-pot hydrothermal procedure was utilized for magnetic cellulose nanocrystal (MCNC) development from microcrystalline cellulose (MCC) in the presence of ferric chloride, ferrous chloride, urea, and hydrochloric acid. The x-ray photoelectron spectroscopy (XPS), x-ray diffraction (XRD), and Fourier-transform infrared spectroscopy analysis confirmed the presence of CNC and Fe3O4, while transmission electron microscopy (TEM) and dynamic light scattering (DLS) analysis verified their respective sizes (< 400 nm and ≤ 20 nm) in the generated composite. To have an efficient adsorption activity for doxycycline hyclate (DOX), the produced MCNC was post-treated using chloroacetic acid (CAA), chlorosulfonic acid (CSA), or iodobenzene (IB). The introduction of carboxylate, sulfonate, and phenyl groups in the post-treatment was confirmed by FTIR and XPS analysis. Such post treatments decreased the crystallinity index and thermal stability of the samples but improved their DOX adsorption capacity. The adsorption analysis at different pHs revealed the increase in the adsorption capacity by reducing the basicity of the medium due to decreasing electrostatic repulsions and inducing strong attractions.

Generation of Sulfonated Lignin-Starch Polymer and Its Use As a Flocculant.

This paper reports the polymerization of tall oil lignin (TOL), starch, and 2-methyl-2-propene-1-sulfonic acid sodium salt (MPSA), a sulfonate-containing monomer, in a three-component system to generate flocculants for colloidal systems. By utilizing the advanced 1H, COSY, HSQC, HSQC-TOCSY, and HMBC NMR techniques, it was confirmed that the phenolic substructures of TOL and the anhydroglucose unit of starch were covalently polymerized by the monomer to generate the three-block copolymer. The molecular weight, radius of gyration, and shape factor of the copolymers were fundamentally correlated to the structure of lignin and starch, as well as the polymerization outcomes. The deposition behavior of the copolymer, studied by a quartz crystal microbalance with dissipation (QCM-D) analysis, revealed that the copolymer with a larger molecular weight (ALS-5) deposited more and generated more compact adlayer than the copolymer with a smaller molecular weight on a solid surface. Owing to its higher charge density, molecular weight, and extended coil-like structure, ALS-5 produced larger flocs with faster sedimentation in the colloidal systems, regardless of the extent of agitation and gravitational force. The results of this work provide a new approach to preparing a lignin-starch polymer, i.e., a sustainable biomacromolecule with excellent flocculation performance in colloidal systems.

Robust, Scalable, and Cost-Effective Surface Carbonized Pulp Foam for Highly Efficient Solar Steam Generation.

Recently, a solar-driven evaporator has been applied in seawater desalination, but the low stability, high cost, and complex fabrication limit its further application. Herein, we report a novel, low-cost, scalable, and easily fabricated pulp-natural rubber (PNR) foam with a unique porous structure, which was directly used as a solar-driven evaporator after facile surface carbonization. This surface carbonized PNR (CPNR) foam without interface adhesion or modification was composed of a top photothermal layer with light absorption ability and a bottom hydrophilic foam layer with a porous and interconnected network structure. Due to the strong light absorption ability (93.2%) of the carbonized top layer, together with the low thermal conductivity (0.1 W m K-1) and good water adsorption performance (9.9 g g-1) of the bottom layer, the evaporation rate and evaporation efficiency of the pulp foam evaporator under 1 sun of illumination attained 1.62 kg m-2 h-1 and 98.09%, respectively, which were much higher than those of most cellulose-based solar-driven evaporators. Furthermore, the CPNR foam evaporator with high cost-effectiveness presented high light-thermal conversion, heat localization, and good salt rejection properties due to the unique porous structure. Additionally, the CPNR foam evaporator exhibited potential applications in the treatments of simulated sewage, metal ion concentration, and seawater desalination. Its cost-effectiveness was clearly higher than that of most reported evaporators as well. Therefore, this novel, low-cost, and stable pulp foam evaporator demonstrated here can be a very promising solution for water desalination and purification.