Mechanically strong micro-nano fibrillated cellulose paper with improved barrier and water-resistant properties for replacing plastic.

Replacing nonbiodegradable plastics with environmentally friendly cellulose materials has emerged as a key trend in environmental protection. This study highlights the development of a strong and hydrophobic micro-nano fibrillated cellulose paper (MNP) through the incorporation of micro-nano fibrillated cellulose fiber (MNF) and chitin nanocrystal (Ch), followed by the impregnation of polymethylsiloxane (PMHS). A low-acid, heat-assisted colloidal grinding strategy was employed to prepare MNF with a high aspect ratio effectively. Ch was incorporated as a reinforcing matrix into the cellulose fiber scaffold through straightforward mechanical mixing and mechanical hot-pressing treatments. Compared to pure MNP, the 5Ch-MNP exhibited a 25 % improvement in tensile strength, reaching 170 MPa, and showed enhanced barrier properties against oxygen and water vapor. The impregnation of PMHS rapidly confers environmentally resistant hydrophobic properties to 1 % PMHS-5Ch-MNP, leading to a water contact angle exceeding 112°, and a 290 % increase in tensile strength under wet conditions. Additionally, the paper demonstrated excellent antibacterial adhesion properties, with the adhesion rates for E. coli and S. aureus exceeding 98 %. This study successfully produced functional cellulose paper with remarkable mechanical properties and barrier properties, as well as hydrophobicity, using a simple, efficient, and environmentally friendly method, making it a promising substitute for petroleum-based plastics.

Micro- and nano-hybrid cellulose fibers prepared by straightforward and high-efficiency hot water soaking-assisted colloid grinding for high-performance cellulose paper.

Micro- and nano-hybrid cellulose fiber (MNCF) stands out as a versatile cellulosic nanomaterial with promising applications in various fields owing to its excellent intrinsic nature and outstanding characteristics. However, the inefficiency in preparing MNCF, attributed to a complex multi-step processing, hinders its widespread adoption. In this study, a straightforward and highly efficient method for MNCF preparation was developed via a hot water soaking-assisted colloid grinding strategy. Active water molecules in hot water facilitating stronger transverse shrinkage and longitudinal expansion in fiber crystallized region, and thus improving the fibrillation degree of cellulose fibers. As a result, MNCFs with a mean diameter of 37.5 ± 22.2 nm and high concentration (2 wt%) were successfully achieved though pure mechanical method. The micro and nano-hybrid structure leads to the corresponding resulting cellulose paper with micro- and nano-hybrid structure possesses a compact stacking and fewer defects, leading to extraordinary mechanical properties including tensile strength of 204.5 MPa, Young's modulus of 6.3 GPa and elongation of 10.1 %. This work achieves significant progress towards straightforward and highly efficient production of MNCFs, offering an appreciable prospect for the development of multifunctional MNCF-based materials.

Molecularly imprinted polypyrrole nanotubes based electrochemical sensor for glyphosate detection.

An electrochemical sensor based on molecularly imprinted polypyrrole nanotubes (MIPNs) has been developed for the detection of glyphosate (Gly) with high sensitivity and specificity. Herein, the MIPNs are prepared by imprinting Gly sites on the surface of polypyrrole (PPy) nanotubes. The synthesized MIPNs have high electrical conductivity and exhibit rapid adsorption rate, enhanced affinity and specificity to Gly. An electrochemical sensor for Gly detection is fabricated by assembling MIPNs-modified screen-printed electrodes with a 3D-printed electrode holder, which is highly portable and suitable for real-time detection. The results demonstrate that the MIPNs-based electrochemical sensor for Gly exhibits a wide detection range of 2.5-350 ng/mL with a limit of detection (LOD) of 1.94 ng/mL. Besides, the Gly sensor possessed good stability, reproducibility, and excellent selectivity against other interferents. The practicability of the sensor is verified by detecting Gly in orange juice and rice beverages, indicating that the sensor is suitable for monitoring pesticides in actual food and environmental samples.

Photocuring Three-Dimensional Printing of Thermoplastic Polymers Enabled by Hydrogen Bonds.

The advent of 3D printing has led to a new era of highly customized products. Printing reprocessable thermoplastic polymers is limited to slow printing techniques such as fused deposition modeling. Photocuring 3D printing is a high-speed 3D printing technique suitable for photocurable thermosetting resins because the cross-linked 3D network could achieve rapid solid-liquid separation during printing. However, thermoplastics usually cannot be printed via photocuring 3D printers because rapid solid-liquid separation is hard to be achieved due to the diffusion/dissolution of linear molecular chains in their liquid precursor. Herein, we hypothesize that hydrogen bonds (H-bonds) between monomers may accelerate polymerization and reduce solubility of the polymer in liquid precursors to achieve rapid solid-liquid separation. Using this strategy, a series of UV-curable methacrylic and acrylic monomers was selected as inks to demonstrate the role of H-bonds in photocuring 3D printing. The hypothesis was further verified by using blended inks of N-vinyl-2-pyrrolidinone (NVP) and acrylic acid (AA) via experimental and molecular dynamic simulation. Oil palm occupies the top position of plantation species in southeastern Asian forests. Palm oil (PO) has the lowest price compared with other plant oils. Thus, a PO-based vinyl monomer was selected as the raw material for 3D printing thermoplastic polymers. Various biobased thermoplastics were successfully printed from the PO-based monomer and commercial monomers. The amide structure in the PO monomer formed H-bonds with polar monomers, including NVP and AA, resulting in printed 3D objects with surprising functionalities such as high stretchability and self-healing ability.

Preparation and Performance of Cement Mortar Reinforced by Modified Bamboo Fibers.

This study aims to prepare bamboo-fiber-reinforced cement composites and provide a solution to the issue of poor interfacial adhesion between bamboo fibers and cement matrix. The original bamboo fibers were modified by three moderately low-cost and easy-to-handle treatments including glycerol, aluminate ester, and silane treatments. The performance of the modified bamboo-fiber-reinforced cement composites was evaluated by a series of mechanical and durability tests, including flexural and compressive strength, water absorption, chloride ion penetration, drying shrinkage, freeze-thaw resistance, and carbonization. In addition, the microstructures of composites were characterized using a scanning electron microscope (SEM). The results showed that the composites reinforced with glycerol-modified bamboo fibers had 14% increased flexural strength and comparable compressive strength. From durability perspectives, all treatments showed similar performance in drying shrinkage, whereas aluminate ester treatment was the most effective in terms of impermeability, chloride resistance, freeze-thaw resistance, and carbonization. The results could provide insights to efficient and effective natural fiber treatment to enable better performance of natural-fiber-reinforced cement-based materials.

A Review on Styrene Substitutes in Thermosets and Their Composites.

In recent decades, tremendous interest and technological development have been poured into thermosets and their composites. The thermosets and composites with unsaturated double bonds curing system are especially concerned due to their versatility. To further exploit such resins, reactive diluents (RDs) with unsaturated sites are usually incorporated to improve their processability and mechanical properties. Traditional RD, styrene, is a toxic volatile organic compound and one of the anticipated carcinogens warned by the National Institute of Health, USA. Most efforts have been conducted on reducing the usage of styrene in the production of thermosets and their composites, while very few works have systematically summarized these literatures. Herein, recent developments regarding styrene substitutes in thermosets and their composites are reviewed. Potential styrene alternatives, such as vinyl derivatives of benzene and (methyl)acrylates are discussed in details. Emphasis is focused on the strategies on developing novel RD monomers through grafting unsaturated functional groups on renewable feedstocks such as carbohydrates, lignin, and fatty acids. This review also highlights the development and characteristics of RD monomers and their influence on processability and mechanical performance of the resulting thermosets and composites.

Preparation and Evaluation of Green Composites from Microcrystalline Cellulose and a Soybean-Oil Derivative.

The present work aimed at developing fully green composites from renewable materials, i.e., acrylated epoxidized soybean oil (AESO) and microcrystalline cellulose (MCC) by a solution casting method. The reinforcing effect of MCC on AESO resins was optimized by adjusting MCC loading from 20 to 40 wt % in terms of physical, mechanical, and thermal properties as well as water absorption of the resulting MCC/AESO composites. The interaction between MCC and AESO was characterized by Fourier transform infrared (FTIR) analysis, which revealed possible hydrogen bonds between the ⁻OH groups of MCC along with the polar components of AESO including C=O, ⁻OH, and epoxy groups. This was further evidenced by a benign interfacial adhesion between MCC and AESO resins as revealed by scanning electron microscope (SEM) analysis. The incorporation of MCC into AESO resins significantly increased the density, hardness, flexural strength, and flexural modulus of the MCC/AESO composites, indicative of a significant reinforcing effect of MCC on AESO resins. The composite with 30 wt % MCC obtained the highest physical and mechanical properties due to the good dispersion and interfacial interaction between MCC and AESO matrix; the density, hardness, flexural strength, and flexural modulus of the composite were 15.7%, 25.0%, 57.2%, and 129.7% higher than those of pure AESO resin, respectively. However, the water resistance at room temperature and 100 °C of the composites were dramatically decreased due to the inherent hydrophilicity of MCC.