RESUMEN
The exploration of high-performance and low-cost wide-bandgap polymer donors remains critical to achieve high-efficiency nonfullerene organic solar cells (OSCs) beyond current thresholds. Herein, the 1,2,3-benzothiadiazole (iBT), which is an isomer of 2,1,3-benzothiadiazole (BT), is used to design wide-bandgap polymer donor PiBT. The PiBT-based solar cells reach efficiency of 19.0%, which is one of the highest efficiencies in binary OSCs. Systemic studies show that isomerization of BT to iBT can finely regulate the polymers' photoelectric properties including i) increasing the extinction coefficient and photon harvest, ii) downshifting the highest occupied molecular orbital energy levels, iii) improving the coplanarity of polymer backbones, iv) offering good thermodynamic miscibility with acceptors. Consequently, the PiBT:Y6 bulk heterojunction (BHJ) device simultaneously reaches advantageous nanoscale morphology, efficient exciton generation and dissociation, fast charge transportation, and suppressed charge recombination, leading to larger VOC of 0.87 V, higher JSC of 28.2 mA cm-2, greater fill factor of 77.3%, and thus higher efficiency of 19.0%, while the analog-PBT-based OSCs reach efficiency of only 12.9%. Moreover, the key intermediate iBT can be easily afforded from industry chemicals via two-step procedure. Overall, this contribution highlights that iBT is a promising motif for designing high-performance polymer donors.
RESUMEN
The development of conjugated polymers especially n-type polymer semiconductors is powered by the design and synthesis of electron-deficient building blocks. Herein, a strong acceptor building block with di-metallaaromatic structure was designed and synthesized by connecting two electron-deficient metallaaromatic units through a π-conjugated bridge. Then, a double-monomer polymerization methodology was developed for inserting it into conjugated polymer scaffolds to yield metallopolymers. The isolated well-defined model oligomers indicated polymer structures. Kinetic studies based on nuclear magnetic resonance and ultraviolet-visible spectroscopies shed light on the polymerization process. Interestingly, the resulted metallopolymers with dπ -pπ conjugations are very promising electron transport layer materials which can boost photovoltaic performance of an organic solar cell, with power conversion efficiency up to 18.28 % based on the PM6 : EH-HD-4F non-fullerene system. This work not only provides a facile route to construct metallaaromatic conjugated polymers with various functional groups, but also discovers their potential applications for the first time.
RESUMEN
In the field of organic solar cells (OSCs), the interfacial layer plays the role of enhancing carrier extraction/transportation, inhibiting their recombination, etc. In contrast to the wide variety of cathode interfacial materials with good modification ability, much less effort has been reported for anode interfacial materials. In this study, we report a polyoxometalate-based inorganic molecular cluster, zinc phosphotungstate (Zn3P2W24O80, denoted ZnPW), as an anode interfacial layer. Based on the PM6/EH-HD-4F/L8-BO-F ternary system, the device with ZnPW modification achieved a high power conversion efficiency (PCE) and a fill factor of up to 18.67 and 80.29%, respectively, which are higher than the counterpart device (PCE of 18.01%) with PEDOT/PSS as the anode interfacial layer. Detailed studies revealed that under the modification of ZnPW, the devices obtained promoted light absorption and suitable energy level matching between the active layer and the electrode, reduced contact resistance, and suppressed charge recombination. In addition, the ZnPW-modified devices had improved photostability and storage stability compared to PEDOT/PSS-modified devices. Our work shows that the polyoxometalate-based inorganic nanocluster ZnPW has great advantages in enhancing the device performance and stability of OSCs.
RESUMEN
Five carbazole and diketopyrrolopyrrole-based donor-acceptor (D-A) new π-conjugated oligomers (π-COs) with gradually elongated lengths are facilely synthesized via a single pot of direct C-H arylation with merits of atom- and step-economy. The structure-property-performance correlations of these π-COs and their parent polymer are studied in detail by opto-electronic characterizations and bulk heterojunction (BHJ) organic photovoltaic (OPV) devices. It is found that the π-COs having longer lengths enable better performance in OPVs owing to the enhanced intermolecular interaction with the elongation of the conjugations. The above results not only highlight the powerful synthetic strategy here provided, but also reveal that π-COs with unique properties might find promising application in OPVs.
