Quantifying Dielectric Material Charge Trapping and De-Trapping Ability Via Ultra-Fast Charge Self-Injection Technique.

Recently, utilizing the air breakdown effect in the charge excitation strategy proves as an efficient charge injection technique to increase the surface charge density of dielectric polymers for triboelectric nanogenerators (TENGs). However, quantitative characterization of the ability of dielectric polymers to trap reverse charges and the effect on the startup time of secondary self-charge excitation (SSCE) are essential for extensive applications. Here, an ultra-fast charge self-injection technique based on a self-charge excitation strategy is proposed, and a standard method to quantify the charge trapping and de-trapping abilities of 23 traditional tribo-materials is introduced. Further, the relationship among the distribution of dielectric intrinsic deep, shallow trap states, and transportation of trapped charges is systematically analyzed in this article. It shows that the de-trapping rate of charges directly determines the reactivation and failure of SSCE. Last, independent of TENG contact efficiency, an ultra-high charge density of 2.67 mC m-2 and an ultra-fast startup time of SSCE are obtained using a 15 µm poly(vinylidene fluoride-trifluoroethylene) film, breaking the historical record for material modification. As a standard for material selection, this work quantifies the charge trapping and de-trapping ability of the triboelectric dielectric series and provides insights for understanding the charge transport in dielectrics.

Boosting Output Performance of Sliding Mode Triboelectric Nanogenerator by Shielding Layer and Shrouded-Tribo-Area Optimized Ternary Electrification Layered Architecture.

Sliding mode triboelectric nanogenerator (S-TENG) is effective for low-frequency mechanical energy harvesting owing to their more efficient mechanical energy extraction capability and easy packaging. Ternary electrification layered (TEL) architecture is proven useful for improving the output performance of S-TENG. However, the bottleneck of electric output is the air breakdown on the interface of tribo-layers, which seriously restricts its further improvement. Herein, a strategy is adopted by designing a shielding layer to prevent air breakdown on the central surface of tribo-layers. And the negative effects of air breakdown on the edge of sliding layer are averted by increasing the shrouded area of tribo-layers on slider. Output charge of this shielding-layer and shrouded-tribo-area optimized ternary electrification layered triboelectric nanogenerator (SS-TEL-TENG) achieves 3.59-fold enhancement of traditional S-TENG and 1.76-fold enhancement of TEL-TENG. Furthermore, even at a very low speed of 30 rpm, output charge, current, and average power of the rotation-type SS-TEL-TENG reach 4.15 µC, 74.9 µA, and 25.4 mW (2.05 W m-2 Hz-1 ), respectively. With such high-power output, 4248 LEDs can be lighted brightly by SS-TEL-TENG directly. The high-performance SS-TEL-TENG demonstrated in this work will have great applications for powering ubiquitous sensor network in the Internet of Things (IoT).

Conversion of Dielectric Surface Effect into Volume Effect for High Output Energy.

Improving the output energy and durability of triboelectric nanogenerators (TENGs) remains a considerable challenge for their practical applications. Owing to the interface effect of triboelectrification and electrostatic induction, thinner films with higher dielectric constants yield a higher output; however, they are not durable for practical applications. Herein, the dielectric surface effect is changed into a volume effect by adopting a millimeter-thick dielectric film with an inner porous network structure so that charges can hop in the surface state of the network. Charge migration inside the dielectric film is the key factor affecting the output of the triboelectric nanogenerator (TENG) with a thick film, based on which each working stage follows the energy-maximization principle in the voltage-charge plot. The maximum peak and average power densities of the TENG with polyurethane foam film in 1 mm thickness reach 40.9 and 20.7 W m-2  Hz-1 , respectively, under environmental conditions, and the output charge density is 5.14 times that of TENGs with a poly(tetrafluoroethylene) film of the same thickness. Superdurability is achieved in the rotary-mode TENG after 200 000 operation cycles. This study identifies the physical mechanism of the thick dielectric film used in TENGs and provides a new approach to promote the output and durability of TENGs.

Large Harvested Energy by Self-Excited Liquid Suspension Triboelectric Nanogenerator with Optimized Charge Transportation Behavior.

To enhance the durability of triboelectric nanogenerator (TENG), liquid lubrication has been used to reduce mechanical abrasion. However, as the charge transportation behavior in dielectric liquid is not clearly understood, the output energy is still low although some improvements have been reported. Herein, the charge transportation behaviors in dielectric liquid by self-excited liquid suspension triboelectric nanogenerator (LS-TENG) are systematically investigated. The important role of solid-liquid triboelectrification effect, charge-liquid transmission and dissipation effect, and the homogeneous dielectric induction effect in promoting its output performance is found. The LS-TENG with a dual dielectric tribolayer has advantages of slight driving force and long lifetime for harvesting micro energy. The output of LS-TENG remains almost constant for more than 234 k operating cycles. A high charge density of 704 µC m-2 is obtained, 2.7 times as much as that of the current highest record in non-contact TENG. Additionally, the rotary LS-TENG lights up 4200 LEDs and continuously powers a variety of wireless sensors by harvesting wind energy at low wind speed. This work provides an important insight toward the charge transportation mechanism in dielectric liquid, and a prospective strategy for achieving highly robust TENG in micro energy harvesting for practical applications.

Matching Mechanism of Charge Excitation Circuit for Boosting Performance of a Rotary Triboelectric Nanogenerator.

The triboelectric nanogenerator (TENG) as an ideal low-frequency mechanical energy harvester has received extensive attention, while low output charge density limits its application. A charge excitation strategy is one of the techniques to effectively improve the surface charge density of the TENG. However, there is little in-depth research on the matching factors between the TENG and excitation circuit. Herein, a soft-contact charge excitation rotary TENG (SCER-TENG) is developed to explore the matching mechanism of different charge excitation strategies. The total output power transferred by the voltage-multiplying circuit (VMC) is 2.13 times that of the full-wave bridge rectifier, which effectively improves the output performance of the SCER-TENG. Moreover, through the established capacitor model and the theoretically calculated maximum output charge of the SCER-TENG with VMC and Zener diodes (VMC-Z), it is found that the output of the Main TENG is mainly affected by capacitors and Zener diodes. The theories have been verified by experiments. After optimization, the output charge of the Main TENG with VMC-Z (1.54 µC) is 3850% higher than that without excitation (0.04 µC). The SCER-TENG successfully harvests low-speed (2.5 m s-1) wind energy to form a self-powered system. This work has crucial instructive implications for using charge excitation strategies to improve the performance of the rotary TENG.

Ultrahigh Performance Triboelectric Nanogenerator Enabled by Charge Transmission in Interfacial Lubrication and Potential Decentralization Design.

Triboelectric nanogenerator (TENG) is a promising strategy for harvesting low frequency mechanical energy. However, the bottlenecks of limited electric output by air/dielectric breakdown and poor durability by material abrasion seriously restrict its further improvement. Herein, we propose a liquid lubrication promoted sliding mode TENG to address both issues. Liquid lubrication greatly reduces interface material abrasion, and its high breakdown strength and charge transmission effect further enhance device charge density. Besides, the potential decentralization design by the voltage balance bar effectively suppresses the dielectric breakdown. In this way, the average power density up to 87.26 W·m-2·Hz-1, energy conversion efficiency of 48%, and retention output of 90% after 500,000 operation cycles are achieved, which is the highest average power density and durability currently. Finally, a cell phone is charged to turn on by a palm-sized TENG device at 2 Hz within 25 s. This work has a significance for the commercialization of TENG-based self-powered systems.

High Output Performance and Ultra-Durable DC Output for Triboelectric Nanogenerator Inspired by Primary Cell.

Triboelectric nanogenerator (TENG) is regarded as an effective strategy to convert environment mechanical energy into electricity to meet the distributed energy demand of large number of sensors in the Internet of Things (IoTs). Although TENG based on the coupling of triboelectrification and air-breakdown achieves a large direct current (DC) output, material abrasion is a bottleneck for its applications. Here, inspired by primary cell and its DC signal output characteristics, we propose a novel primary cell structure TENG (PC-TENG) based on contact electrification and electrostatic induction, which has multiple working modes, including contact separation mode, freestanding mode and rotation mode. The PC-TENG produces DC output and operates at low surface contact force. It has an ideal effective charge density (1.02 mC m-2). Meanwhile, the PC-TENG shows a superior durability with 99% initial output after 100,000 operating cycles. Due to its excellent output performance and durability, a variety of commercial electronic devices are powered by PC-TENG via harvesting wind energy. This work offers a facile and ideal scheme for enhancing the electrical output performance of DC-TENG at low surface contact force and shows a great potential for the energy harvesting applications in IoTs.

Achieving Remarkable Charge Density via Self-Polarization of Polar High-k Material in a Charge-Excitation Triboelectric Nanogenerator.

Boosting output charge density is top priority for achieving high-performance triboelectric nanogenerators (TENGs). The charge-excitation strategy is demonstrated to be a superior approach to acquire high output charge density. Meanwhile, the molecular charge behaviors in the dielectric under a strong electric field from high charge density bring new physics that are worth exploring. Here, a rapid self-polarization effect of a polar dielectric material by the superhigh electric field in a charge-excitation TENG is reported, by which the permittivity of the polar dielectric material realizes self-increase to a saturation, and thus enhances the output charge density. Consequently, an ultrahigh charge density of 3.53 mC m-2 is obtained with 7 µm homemade lead zirconate titanate-poly(vinylidene fluoride) composite film in the atmosphere with 5% relative humidity, which is the highest charge density for TENGs with high durability currently. This work provides new guidance for dielectric material optimization under charge excitation to boost the output performance of TENGs toward practical applications.

An Ultrarobust and High-Performance Rotational Hydrodynamic Triboelectric Nanogenerator Enabled by Automatic Mode Switching and Charge Excitation.

The triboelectric nanogenerator (TENG) is an emerging technology for ambient mechanical energy harvesting, which provides a possibility to realize wild environment monitoring by self-powered sensing systems. However, TENGs are limited in some practical applications as a result of their low output performance (low charge density) and mechanical durability (material abrasion). Herein, an ultrarobust and high-performance rotational TENG enabled by automatic mode switching (contact mode at low speed and noncontact at high speed) and charge excitation is proposed. It displays excellent stability, maintaining 94% electrical output after 72 000 cycles, much higher than that of the normal contact-mode TENG (30%). Due to its high electrical stability and large electrical output, this TENG powers 944 green light-emitting diodes to brightness in series. Furthermore, by harvesting water-flow energy, various commercial capacitors can be charged quickly, and a self-powered fire alarm and self-powered temperature and humidity detection are realized. This work provides an ideal scheme for enhancing the mechanical durability, broadening the range of working frequency, and improving the electrical output of TENGs. In addition, the high-performance hydrodynamic TENG demonstrated in this work will have great applications for Internet of Things in remote areas.