RESUMEN
Urban sewage sludge (SL) is a major concern due to the number of environmental problems it causes. Its application for different purposes is strictly regulated, limiting the possibilities of recycling and reusing this material. Thus, in this work, a complete study of a simple method to convert SL into activated carbon (AC) was carried out. The comprehensive study involves an evaluation of the main process parameters, such as the activating agent (AA) content (25 %, 33 %, 50 %), using the lowest amount of AA as novelty, different pyrolysis temperatures (600 and 800 °C), and purification conditions (6 M HCl:AC ratio, v:w). Under controlled and optimised conditions and through a single combined activation and pyrolysis step followed by acid purification, ACs with well-developed porosity can be obtained. Surface area values of around 870 m2/g and over 60 % carbon content were achieved, demonstrating that the prepared ACs could have applications in a wide variety of fields as high-value products. As an innovative aspect in this research, the gases streams and liquid effluents generated during the global process were analysed, achieving elimination of over 63 % of the concentration of the chemical elements contained in the SL during the chemical purification stage. Finally, mass, energy, and economic balances were carried out to estimate the production cost of AC derived from SL (< 8/kg AC).
Asunto(s)
Carbón Orgánico , Aguas del Alcantarillado , Aguas del Alcantarillado/química , Porosidad , Carbón Orgánico/química , Gases , ReciclajeRESUMEN
CuxO-TiO2 (x = 1, 2) nanomaterials are synthesized on polycrystalline Ti substrates by a convenient chemical vapor deposition (CVD) approach, based on the initial growth of a CuxO matrix (at 400 and 550 °C for x = 1 and 2, respectively) and the subsequent overdispersion of TiO2 at 400 °C. All CVD processes are carried out in an oxygen atmosphere saturated with water vapor. The obtained systems are investigated by means of glancing incidence X-ray diffraction (GIXRD), X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), field emission-scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and electrochemical experiments. Galvanostatic charge/discharge measurements indicate that Cu2O-TiO2 nanomaterials exhibit very attractive high-rate capabilities (â¼400 mA h g(-1) at 1 C; â¼325 mA h g(-1) at 2 C) and good stability after 50 operating cycles, with a retention of 80% of the initial capacity. This phenomenon is mainly due to the presence of TiO2 acting as a buffer material, i.e., minimizing volume changes occurring in the electrochemical conversion. In a different way, CuO-TiO2 systems exhibit worse electrochemical performances as a consequence of their porous morphology and higher thickness. In both cases, the obtained values are among the best ever reported for CuxO-based systems, candidating the present nanomaterials as extremely promising anodes for eventual applications in thin film lithium batteries.