1.
Angew Chem Int Ed Engl
; 62(49): e202313696, 2023 Dec 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-37871290
RESUMEN
We here present how rebalancing the interplay between H-bonds and dispersive forces (Van der Waals/π-π stacking) may induce or not the generation of kinetic metastable states. In particular, we show that extending the aromatic content and favouring the interchain VdW interactions causes a delay into the cooperative supramolecular polymerization of a new family of toluene bis-amide derivatives by trapping the metastable inactive state.