Volatilization of Zn and Pb and preparation of integrated micro-electrolysis filter from copper slag and its application for removing Cr(VI) from aqueous solution.

In this study, copper slag was treated by carbothermal reduction technology for preparing an integrated micro-electrolysis filter (IMEF) and recovery of Zn and Pb. The influence of roasting conditions on the volatilization of Zn and Pb, and on the performance of IMEF in removing Cr(VI) from water were studied. The results showed that increasing the roasting temperature, time, and dosage of coal facilitated the generation of zero-valent iron (ZVI) and volatilization of Zn and Pb. The IMEF, roasted at 1150 °C for 40 min with 25% anthracite, had the best reduction effect on Cr(VI), and the volatilization efficiencies of Zn and Pb were 97.38% and 96.77%, respectively. The prepared IMEF had a porous structure with a porosity of 75.20%. A great number of nano/micro-sized ZVI particles were generated on the surface of silicate pore, and had super reactivity. The removal of Cr(VI) was promoted by increasing IMEF dosage and solution temperature, and decreasing the pH of the Cr(VI) solution. The IMEF presented good mechanical strength and excellent long-term performance in removing Cr(VI). Cr(VI) was reduced into Cr(III) and then mineralized to FeCr2O4 during reaction.

Preparation of porous silicate supported micro-nano zero-valent iron from copper slag and used as persulfate activator for removing organic contaminants.

Porous silicate supported micro-nano zero-valent iron (PSi@ZVI) was prepared from copper slag (CS) through carbothermal reduction technology, and used as a persulfate (PS) activator for removing organic contaminants. Results showed that the properties of the activator were greatly affected by the preparation conditions. Calcination for 20 min at 1100 °C with 20% anthracite was considered the optimum preparation condition for degradation of orange G (OG). The removal rate of OG was improved by increasing the dosages of PSi@ZVI or PS and raising the reaction temperature. Moreover, PSi@ZVI exhibited excellent PS activator ability in a wide range of initial pH, good degradation capability for eosin Y, methyl orange, acid fuchsine, and methylene blue. The reusability and safety of PSi@ZVI were verified. Electron paramagnetic resonance and radical quenching tests indicated that sulfate radical (SO4-) was the main active species in the PSi@ZVI/PS system. The X-ray diffraction results indicated that a high calcination temperature (1100 °C) was beneficial to the reduction of iron-bearing minerals to ZVI. Scanning electron microscopy and energy-dispersive spectroscopy results revealed that the formation of porous structure of PSi@ZVI and the generation of nano to micro-sized ZVI particles on the surface of the silicate holes. The X-ray photoelectron spectra showed that ZVI was first convert into Fe(II), which mainly activated PS and generated Fe(III) in the PSi@ZVI/PS system. Furthermore, the intermediates of OG were detected using gas chromatography-mass spectrometry, and the possible degradation pathway of OG was proposed. This study provides a novel approach for reuse of CS as a heterogeneous activator to effectively activate PS.