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1.
Sci Rep ; 12(1): 12922, 2022 Jul 28.
Artículo en Inglés | MEDLINE | ID: mdl-35902619

RESUMEN

The paper introduces a method for the measurement of monochromatic light using the geometric phase shift in a polarizing interferometer and applying the Fourier transform spectroscopy method. This is achieved with no mirror displacement or change in the actual optical path difference. Our method uses the rotation of a half-wave plate with increments on the order of degrees of arc, which is easier to control and reliable to reproduce. This approach provides flexibility in choosing the spectral range and a novel way of performing such measurements. It is demonstrated how the achromatic nature of the geometric phase allows only for monochromatic measurements to be acquired. The method is described theoretically and its performance is validated via measurements of several low-coherence light sources. Three possible applications of the method are also described, two of which are advantaged by using a detector array and, surprisingly, the achromaticity of the geometric phase.

2.
Beilstein J Nanotechnol ; 12: 354-365, 2021.
Artículo en Inglés | MEDLINE | ID: mdl-33968560

RESUMEN

The influence of film thickness on the structural and optical properties of silicon dioxide (SiO2) and zinc oxide (ZnO) thin films deposited by radio frequency magnetron sputtering on quartz substrates was investigated. The deposition conditions were optimized to achieve stoichiometric thin films. The orientation of crystallites, structure, and composition were investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), while the surface topography of the samples was analyzed using scanning electron microscopy (SEM). The optical characteristics were measured for samples with the same composition but obtained with different deposition parameters, such as increasing thickness. The optical constants (i.e., the refractive index n, the extinction coefficient k, and the absorption coefficient α) of the SiO2 and ZnO oxide films were determined from the transmission spectra recorded in the range of 190-2500 nm by using the Swanepoel method, while the energy bandgap was calculated from the absorption spectra. The influence of thickness on the structural and optical properties of the oxide films was investigated. Good optical quality and performance were noticed, which makes these thin films worthy of integration into metamaterial structures.

3.
Beilstein J Nanotechnol ; 10: 1511-1522, 2019.
Artículo en Inglés | MEDLINE | ID: mdl-31431863

RESUMEN

In this work, rapid thermal annealing (RTA) was applied to indium tin oxide (ITO) films in ambient atmosphere, resulting in significant improvements of the quality of the ITO films that are commonly used as conductive transparent electrodes for photovoltaic structures. Starting from a single sintered target (purity 99.95%), ITO thin films of predefined thickness (230 nm, 300 nm and 370 nm) were deposited at room temperature by radio-frequency magnetron sputtering (rfMS). After deposition, the films were subjected to a RTA process at 575 °C (heating rate 20 °C/s), maintained at this temperature for 10 minutes, then cooled down to room temperature at a rate of 20 °C/s. The film structure was modified by changing the deposition thickness or the RTA process. X-ray diffraction investigations revealed a cubic nanocrystalline structure for the as-deposited ITO films. After RTA, polycrystalline compounds with a textured (222) plane were observed. X-ray photon spectroscopy was used to confirm the beneficial effect of the RTA treatment on the ITO chemical composition. Using a Tauc plot, values of the optical band gap ranging from 3.17 to 3.67 eV were estimated. These values depend on the heat treatment and the thickness of the sample. Highly conductive indium tin oxide thin films (ρ = 7.4 × 10-5 Ω cm) were obtained after RTA treatment in an open atmosphere. Such films could be used to manufacture transparent contact electrodes for solar cells.

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