RESUMEN
HgCdTe-based heterostructures with quantum wells (QWs) are a promising material for semiconductor lasers in the atmospheric transparency window (3-5 µm) thanks to the possibility of suppressing Auger recombination due to the no-parabolic law of carrier dispersion. In this work, we analyze the thresholds of stimulated emission (SE) under optical pumping from heterostructures with a different number of QWs in the active region of the structure. Total losses in structures are determined from the comparison of thresholds for the different number of QWs in the active region. It is shown that, thanks to the increased modal gain, a higher number of QWs results in lower threshold pumping intensity and, consequently, higher temperature of SE. These results indicate that improvements to the modal gain can result in a moderate uplift in the temperature of SE from mid-infrared HgCdTe-based heterostructures. On the other hand, at a high enough QW count threshold, the intensity no longer depends on the number of the QWs and is determined by the transparency concentration of a single QW.
RESUMEN
Heterostructures with thin Hg(Cd)Te/CdHgTe quantum wells (QWs) are attractive for the development of mid-infrared interband lasers. Of particular interest are room-temperature operating emitters for the short-wavelength infrared range (SWIR, typically defined as 1.7-3 µm). In this work, we report on the observation of stimulated emission (SE) in the 2.65-2.75 µm wavelength range at room temperature in an optically pumped HgCdTe QW laser heterostructure. We study a series of three samples with lengths ranging from 2.5 to 7 mm and discuss the effects related to the non-uniformity of the excitation beam profile. SE threshold intensity and the magnitude of pump-induced carrier heating are found to be effectively dependent on the chip size, which should be accounted for in possible designs of HgCdTe-based optical converters. We also pay attention to the problem of active medium engineering in order to push the SE wavelength towards the 3-5 µm atmospheric window and to lower the SE threshold.
RESUMEN
HgTe/CdHgTe quantum well (QW) heterostructures have attracted a lot of interest recently due to insights they provided towards the physics of topological insulators and massless Dirac fermions. Our work focuses on HgCdTe QWs with the energy spectrum close to the graphene-like relativistic dispersion that is supposed to suppress the non-radiative Auger recombination. We combine various methods such as photoconductivity, photoluminescence and magneto-optical measurements as well as transmission electron microscopy to retrofit growth parameters in multi-QW waveguide structures, designed for long wavelengths lasing in the range of 10-22 µm. The results reveal that the attainable operating temperatures and wavelengths are strongly dependent on Cd content in the QW, since it alters the dominating recombination mechanism of the carriers.
RESUMEN
Optical and vibrational properties of a novel allotrope of elemental germanium Ge(oP32), which crystallizes in the structure corresponding to the orthorhombic space group Pbcm, are studied experimentally by means of absorption and polarized Raman scattering measurements and theoretically using the first principles density functional theory. Material is found to be a direct band gap semiconductor with E g = 0.33 eV. Out of theoretically predicted 48 Raman-active modes, 27 are observed in the spectra and assigned to the specific lattice eigenmodes of the crystal based on their symmetry and a comparison with the results of first principles lattice dynamics calculations. Remarkably, the highest frequency vibration is observed at 316 cm-1, that is higher than the cubic crystalline [Formula: see text]-Ge mode at 300 cm-1. Exceptional sharpness of observed phonon lines (between 0.8 and 2.5 cm-1 at T = 10 K) implies excellent crystallinity of Ge(oP32) crystals.
RESUMEN
An epitaxial layer of HgCdTe-a THz detector-was studied in magnetotransmission, magnetoconductivity and magnetophotoconductivity experiments at cryogenic temperatures. In the optical measurements, monochromatic excitation with photon frequency ranging from 0.05 THz to 2.5 THz was used. We show a resonant response of the detector at magnetic fields as small as 10 mT with the width of the resonant line equal to about 5 mT. Application of a circular polarizer at 2.5 THz measurements allowed for confirming selection rules predicted by the theory of optical transitions in a narrow-gap semiconductor and to estimate the band-gap to be equal to about 4.5 meV. The magnetoconductivity tensor was determined as a function of magnetic field and temperature 2 K < T < 120 K and analysed with a standard one-carrier conductivity model and the mobility spectrum technique. The sample showed n-type conductivity at all temperatures. At temperatures above about 30 K, conductivity was found to be reasonably described by the one-carrier model. At lower temperatures, this description is not accurate. The algorithm of the spectrum of mobility applied to data measured below 30 K showed presence of three types of carriers which were tentatively interpreted as electrons, light holes and heavy holes. The mobility of electrons and light holes is of the order of 10 6 cm 2 /Vs at the lowest temperatures. Magnetophotoconductivity experiments allowed for proposing a detector working at 2 K and 50 mT with a flat response between 0.05 THz and 2.5 THz.
RESUMEN
: Cyclotron resonance study of HgTe/CdTe-based quantum wells with both inverted and normal band structures in quantizing magnetic fields was performed. In semimetallic HgTe quantum wells with inverted band structure, a hole cyclotron resonance line was observed for the first time. In the samples with normal band structure, interband transitions were observed with wide line width due to quantum well width fluctuations. In all samples, impurity-related magnetoabsorption lines were revealed. The obtained results were interpreted within the Kane 8·8 model, the valence band offset of CdTe and HgTe, and the Kane parameter EP being adjusted.
RESUMEN
Equilibrium atomic configurations and electron energy structure of ethanol adsorbed on the Si (111) surface are studied by the first principles density functional theory. Geometry optimization is performed by the total energy minimization method. Equilibrium atomic geometries of ethanol, both undissociated and dissociated, on the Si (111) surface are found and analysed. Reaction pathways and predicted transition states are discussed in comparison with available experimental data in terms of the feasibility of the reactions occurring. Analysis of atom and orbital resolved projected density of states indicates substantial modifications of the Si surface valence and conduction electron bands due to the adsorption of ethanol affecting the electronic properties of the surface.
