Internally-cooled atmospheric water harvesting enabling improved productivity.

Sorption-based atmospheric water harvesting holds promise for alleviating water scarcity, but current prototypes have not shown significant increases in practical yields despite efforts in the enlarged engineering scale. This is due to weakened heat and mass transfer with a packed sorbent bed. In this work, the desiccant-coated adsorbers were employed to fabricate the water harvesting device that incorporates internal fluid for cooling and heating during sorption and desorption. Featured with an internal cooling effect, practical water productivity could be improved by 1.75-9.96 times with a low desorption temperature (45-62 °C). The continuous water harvesting system could produce 0.77-3.98 Lwater/kgsorbent/day with a thermal energy consumption of 7.7-30.4 MJ/kg in wide climates from 20 % to 80 % RH, providing a reference for device design in the engineering view. The demonstration revealed that using natural cooling in the sorption stage has great benefits in improving water harvesting performance, which can be integrated into the building sectors or a wider range of scenarios.

An atmospheric water harvesting system based on the "Optimal Harvesting Window" design for worldwide water production.

Atmospheric water harvesting (AWH) is a promising solution to the water shortage problem. Current sorption-based AWH (SAWH) systems seldom obtain both wide climatic adaptability and high energy efficiency due to the lack of thermodynamic optimization. To achieve the ideal harvesting circulation in SAWH systems, the "optimal harvesting window" (OHW) design based on thermodynamic analysis was first proposed and validated by our prototype. The "OHW" theory indicates the water production rate and energy efficiency could be improved by properly reducing the adsorption temperature. As the humidity increases, the optimal adsorption temperature should be closer to the dew point of the environment. Experimental results revealed that, loaded with 3 kg widely adopted silica gel, the daily water production could reach 5.76-17.64 L/d with ultrahigh energy efficiency of 0.46-1.5 L/kWh. This prototype could also achieve optimal performance in wide climatic conditions in terms of 13-35 °C and 18%-72% RH. Lastly, the performance of photovoltaic (PV)-driven SAWH was evaluated. Results showed that a 1 m2 PV panel could generate 0.66-2 L water per day in Shanghai throughout the year, the highest in opening literature. Notably, this work introduces a promising concept that can help achieve large-scale, ultra-fast, energy-efficient AWH worldwide.

Pathways to Energy-efficient Water Production from the Atmosphere.

Atmospheric water harvesting (AWH) provides a fascinating chance to facilitate a sustainable water supply, which obtains considerable attention recently. However, ignoring the energy efficiency of AWH leads to high energy consumption in current prototypes (ca. 101 to 102  MJ kg-1 ), misfitting with the high-strung and complicated water-energy nexus. In this perspective, a robust evaluation of existing AWHs is conducted and a detailed way to high-efficiency AWH is paved. The results suggest that using cooling-assisted adsorption will weaken the bounds of climate to sorbent selections and have the potential to improve efficiency by more than 50%. For device design, the authors deeply elucidate how to perfect heat/mass transfer to narrow the gap between lab and practices. Reducing heat loss, recovering heat and structured sorbent are the main paths to improve efficiency on the device scale, which is more significant for a large-scale AWH. Besides efficiency, the techno-economic evaluation reveals that developing a cost-effective AWH is also crucial for sustainability, which can be contributed by green synthesis routes and biomass-based sorbents. These analyses provide a uniform platform to guide the next-generation AWH to mitigate the global water crisis.

Recent advances in direct air capture by adsorption.

Significant progress has been made in direct air capture (DAC) in recent years. Evidence suggests that the large-scale deployment of DAC by adsorption would be technically feasible for gigatons of CO2 capture annually. However, great efforts in adsorption-based DAC technologies are still required. This review provides an exhaustive description of materials development, adsorbent shaping, in situ characterization, adsorption mechanism simulation, process design, system integration, and techno-economic analysis of adsorption-based DAC over the past five years; and in terms of adsorbent development, affordable DAC adsorbents such as amine-containing porous materials with large CO2 adsorption capacities, fast kinetics, high selectivity, and long-term stability under ultra-low CO2 concentration and humid conditions. It is also critically important to develop efficient DAC adsorptive processes. Research and development in structured adsorbents that operate at low-temperature with excellent CO2 adsorption capacities and kinetics, novel gas-solid contactors with low heat and mass transfer resistances, and energy-efficient regeneration methods using heat, vacuum, and steam purge is needed to commercialize adsorption-based DAC. The synergy between DAC and carbon capture technologies for point sources can help in mitigating climate change effects in the long-term. Further investigations into DAC applications in the aviation, agriculture, energy, and chemical industries are required as well. This work benefits researchers concerned about global energy and environmental issues, and delivers perspective views for further deployment of negative-emission technologies.

Viability of a practical multicyclic sorption-based water harvester with improved water yield.

Sorption-based atmospheric water harvesting (SAWH) has emerged as an attractive way to relieve water scarcity. However, the daily water yield of currently reported SAWH devices remains low to satisfy the rising demand for drinking water. The sorption and desorption kinetics, long-term stability and especially facile scaling-fabrication of adsorbents and scaled-up device implementation have become the bottleneck to such large-scale SAWH application. To overcome these challenges, an air-cooled SAWH device was fabricated to investigate its atmospheric water harvesting (AWH) performance under real island climate and its feasibility of multicyclic operation. Under monocyclic operation, the device demonstrated the superior water productivity as much as 3.9 kg day-1, or 0.39 kgwater kgadsorbent-1 day-1, at 31 °C and 70% RH, with a thermal efficiency of 25.4% (desorption at 94 °C). The SAWH device demonstrated successful water production through 2 adsorption-desorption cycles within one day, with increased thermal efficiency to as high as 32.2% and increased water harvesting performance up to 0.42 kgwater kgadsorbent-1 day-1 by 20-90%. This is the first demonstration in multicyclic SAWH at large scales, holding the promise of large-scale and practical water supply in island areas while opening up new applications such as indoor dehumidification.

Vegetal fiber paper matrix impregnated with silica gel for benzene removal.

Removing benzene from indoor space plays an important role in indoor air purification. A novel filter with vegetal fiber paper (VFP) as matrix hosting silica gel is proposed in this paper for benzene removal. In order to investigate the feasibility and performance of this idea, firstly, three pieces of VFP samples impregnated with different amounts of silica gel are fabricated and their benzene adsorption quantities are tested. The results show that three times is recommended as the optimal number for impregnating. The VFP sample impregnated with silica gel after the third impregnating exhibits commendable coating stability and good benzene adsorption performance. Additionally, at low relative pressure (Pb /Ps  ≤ 0.05), the experimental data of benzene adsorption isotherms fit well with the Langmuir model with R2 greater than 0.97. Then, two actual filters made of VFP impregnated with silica gel after the third impregnating were fabricated. It is found that the pressure drop of the actual filter is only 1200 Pa/m when the air velocity is 2 m/s. Besides, the one-pass efficiency of the filter can reach to 19.44%. It is expected that the silica gel coated on the filter can be modified to improve the purification performance of the filter.

Effects of disposable plastics and wooden chopsticks on the anaerobic digestion of food waste.

A common challenge for the anaerobic digestion (AD) of food waste (FW) is the contamination by disposable plastic materials and utensils. The objective of this batch study was to investigate the effects of disposable plastic materials - polystyrene (PS), polypropylene (PP), high density polyethylene (HDPE) and wooden chopsticks (WC) on the AD of FW. Results showed that methane production from the AD of FW was inhibited to different extents when different materials were present in FW. PS and PP were found to reduce methane production from food waste more than HDPE and WC. The reduction in methane production was hypothesized to be due to the production of toxic plastic by-products or due to reduced contact between microbes and FW. Pyrosequencing and Field Emission Scanning Electron Microscope (FESEM) results indicated that the reduction in methane production was more likely due to the interference of good contact necessary between microbes and FW for biodegradation, and that the biological processes of AD were not affected by the contamination of plastics. Greater reductions in methane yields were also observed when the surface areas of the disposable materials were increased. Studying the effects of disposable materials on the AD of FW would provide plant operators with more information that could optimise the process of resource recovery from food waste.

Monitoring of microbial communities in anaerobic digestion sludge for biogas optimisation.

This study characterised and compared the microbial communities of anaerobic digestion (AD) sludge using three different methods - (1) Clone library; (2) Pyrosequencing; and (3) Terminal restriction fragment length polymorphism (T-RFLP). Although high-throughput sequencing techniques are becoming increasingly popular and affordable, the reliance of such techniques for frequent monitoring of microbial communities may be a financial burden for some. Furthermore, the depth of microbial analysis revealed by high-throughput sequencing may not be required for monitoring purposes. This study aims to develop a rapid, reliable and economical approach for the monitoring of microbial communities in AD sludge. A combined approach where genetic information of sequences from clone library was used to assign phylogeny to T-RFs determined experimentally was developed in this study. In order to assess the effectiveness of the combined approach, microbial communities determined by the combined approach was compared to that characterised by pyrosequencing. Results showed that both pyrosequencing and clone library methods determined the dominant bacteria phyla to be Proteobacteria, Firmicutes, Bacteroidetes, and Thermotogae. Both methods also found that sludge A and B were predominantly dominated by acetogenic methanogens followed by hydrogenotrophic methanogens. The number of OTUs detected by T-RFLP was significantly lesser than that detected by the clone library. In this study, T-RFLP analysis identified majority of the dominant species of the archaeal consortia. However, many of the more highly diverse bacteria consortia were missed. Nevertheless, the combined approach developed in this study where clone sequences from the clone library were used to assign phylogeny to T-RFs determined experimentally managed to accurately predict the same dominant microbial groups for both sludge A and sludge B, as compared to the pyrosequencing results. Results showed that the combined approach of clone library and T-RFLP accurately predicted the dominant microbial groups and thus is a reliable and more economical way to monitor the evolution of microbial systems in AD sludge.