RESUMEN
The increasing accumulation of rock waste obtained due to ore processing and its environmental impacts, such as acid mine drainage and elevated concentrations of heavy metals in soils, necessitates the transformation of mining technologies based on the concept of circular waste management. The research is aimed at improving the parameters of the mechanical activation effect produced on technogenic georesources, as well as at expanding the application scope of disintegrators in the field of using the partial backfill of the mined-out space when developing stratified deposits. In this regard, the research purpose was to substantiate the parameters of extracting metals from enrichment tailings using their mechanochemical activation to ensure cyclic waste management. The research involved the application of three-dimensional interpolation methods used for processing the data and the graphical representation. As a result, the following was found to be characteristic of the waste of the Sadonsky mine management. The degree of extracting zinc from pre-activated tailings increases logarithmically when the H2SO4 concentration and the NaCl proportion decrease 3.5 times. The degree of extracting lead from the activated tailings increases according to the Fourier law when decreasing the NaCl mass concentration, and an optimal range of the H2SO4 (0.38-0.51%) proportion decreases six times. One of the key results of the research is the justification of expanding the scope of applying disintegrators in the case of a directed activation influence exerted on the components of the stowing strips. The obtained results expand the understanding of the mechanism of the influence of the mechanochemical activation of dry tailings on the reactivity unevenness when extracting several metals from them.
RESUMEN
The aim of the work is to develop an energy-saving device that provides the conversion of thermal energy into electrical energy. The design and materials of the thermoelectric converter unit, consisting of 12 thermoelectric converter modules, a cooling radiator and a switching unit, were developed and selected. Based on the test results, the zone of the maximum temperatures in the section of the gas duct recommended for the installation of a gas cooling module using a thermoelectric converter was determined. The technology for cooling gases with the help of a thermoelectric converter was tested on the site located in front of the experimental heat exchanger. An assessment of the efficiency of the conversion of heat into electrical energy was conducted using the design of the thermoelectric converter unit, based on thermoelectric modules TGM 127-1.4-1.2. It was determined that the device is capable of generating electricity stably for production needs. The data obtained showed that, at a temperature difference of 75-80 °C between the wall surface of the gas duct section and the coolant, the power of one thermoelectric converter block of the gas cooling system reaches 9 W.
RESUMEN
This article presents the results of a study of the characteristics of hydration and properties of a composite biocidal cement binder containing hydrosilicates of barium, copper or zinc. It was found that copper hydrosilicates block hydration processes, and when zinc hydrosilicates are used, the rate of hydration is determined by the content of silicic acid. The limiting concentrations of biocidal modifiers have been established: zinc hydrosilicates-no more than 4% and copper hydrosilicates-no more than 0.5%, which are advisable to use for the manufacture of a biocidal composite binder. It is shown that modifying additives slow down the setting time, the amount of tricalcium silicate in cement stones increases, and their strength for some compositions decreases. Active binding of portlandite with the formation of calcium hydrosilicates occurs when the content of zinc hydrosilicates is 2%, which leads to an increase in the strength of the materials.
