Environmental impact assessment via life cycle analysis on ultrafiltration membrane fabricated from polyethylene terephthalate waste to treat microalgal cultivation wastewater for reusability.

The current study had conducted the life cycle analysis (LCA) to assess the environmental impact of microalgal wastewater treatment via an integrated membrane bioreactor. The functional unit selected for this analysis was 1 kg of treated microalgal wastewater with contaminants eliminated by ultrafiltration membrane fabricated from recycled polyethylene terephthalate waste. Meanwhile, the applied system boundary in this study was distinguished based on two scenarios, namely, cradle-to-gate encompassed wastewater treatment only and cradle-to-cradle which included the reutilization of treated wastewater to cultivate microalgae again. The environmental impacts and hotspots associated with the different stages of the wastewater treatment process had clearly elucidated that membrane treatment had ensued the highest impact, followed by microalgal harvesting, and finally cultivation. Among the environmental impact categories, water-related impact was found to be prominent in the following series: freshwater ecotoxicity, freshwater eutrophication and marine ecotoxicity. Notably, the key performance indicator of all environmental impact, i.e., the global warming potential was found to be very much lower at 2.94 × 10-4 kg CO2 eq as opposed to other literatures reported on the LCA of wastewater treatments using membranes. Overall, this study had proffered insights into the environmental impact of microalgal wastewater treatment and its stimulus for sustainable wastewater management. The findings of this study can be instrumental in making informed decision for optimizing microalgal wastewater treatment and reutilization assisted by membrane technology with an ultimate goal of enhancing sustainability.

The role of sheet-like TiO2 in polyamide reverse osmosis membrane for enhanced removal of endocrine disrupting chemicals.

Thin film composite (TFC) reverse osmosis (RO) membrane shows good promise for treating wastewater containing endocrine disrupting chemical (EDC) pollutants. The incorporation of functional materials with exceptional structural and physico-chemical properties offers opportunities for the membranes preparation with enhanced permselectivity and better antifouling properties. The present study aims to improve the EDC removal efficiency of TFC RO membrane using two-dimensional titania nanosheets (TNS). RO membrane was prepared by incorporating TNS in the dense layer of polyamide (PA) layer to form thin film nanocomposite (TFN) membrane. The TNS loading was varied and the influences on membrane morphology, surface hydrophilicity, surface charge, as well as water permeability and rejection of EDC were investigated. The results revealed that the inclusion of TNS in the membrane resulted in the increase of water permeability and EDC rejection. When treating the mixture of bisphenol A (BPA) and caffeine at 100 ppm feed concentration, the TFN membrane incorporated with 0.05% TNS achieved water permeability of 1.45 L/m2·h·bar, which was 38.6% higher than that of unmodified TFC membrane, while maintaining satisfactory rejection of >97%. The enhancement of water permeability for TFN membrane can be attributed to their hydrophilic surface and unique nanochannel structure created by the nanoscale interlayer spacing via staking of TiO2 nanosheets. Furthermore, the 0.05TFN membrane exhibited excellent fouling resistance towards BPA and caffeine pollutants with almost 100% flux recovery for three cycles of operations.

Ultrafiltration membrane fabricated from polyethylene terephthalate plastic waste for treating microalgal wastewater and reusing for microalgal cultivation.

Current study had made a significant progress in microalgal wastewater treatment through the implementation of an economically viable polyethylene terephthalate (PET) membrane derived from plastic bottle waste. The membrane exhibited an exceptional pure water flux of 156.5 ± 0.25 L/m2h and a wastewater flux of 15.37 ± 0.02 L/m2h. Moreover, the membrane demonstrated remarkable efficiency in selectively removing a wide range of residual parameters, achieving rejection rates up to 99%. The reutilization of treated wastewater to grow microalgae had resulted in a marginal decrease in microalgal density, from 10.01 ± 0.48 to 9.26 ± 0.66 g/g. However, this decline was overshadowed by a notable enhancement in lipid production with level rising from 181.35 ± 0.42 to 225.01 ± 0.11 mg/g. These findings signified the membrane's capacity to preserve nutrients availability within the wastewater; thus, positively influencing the lipid synthesis and accumulation within microalgal cells. Moreover, the membrane's comprehensive analysis of cross-sectional and surface topographies revealed the presence of macropores with a highly interconnected framework, significantly amplifying the available surface area for fluid flow. This exceptional structural attribute had substantially contributed to the membrane's efficacy by facilitating superior filtration and separation process. Additionally, the identified functional groups within the membrane aligned consistently with those commonly found in PET polymer, confirming the membrane's compatibility and efficacy in microalgal wastewater treatment.

Perspectives on human movement considerations in indoor airflow assessment: a comprehensive data-driven systematic review.

Understanding particle dispersion characteristics in indoor environments is crucial for revising infection prevention guidelines through optimized engineering control. The secondary wake flow induced by human movements can disrupt the local airflow field, which enhances particle dispersion within indoor spaces. Over the years, researchers have explored the impact of human movement on indoor air quality (IAQ) and identified noteworthy findings. However, there is a lack of a comprehensive review that systematically synthesizes and summarizes the research in this field. This paper aims to fill that gap by providing an overview of the topic and shedding light on emerging areas. Through a systematic review of relevant articles from the Web of Science database, the study findings reveal an emerging trend and current research gaps on the topic titled Impact of Human Movement in Indoor Airflow (HMIA). As an overview, this paper explores the effect of human movement on human microenvironments and particle resuspension in indoor environments. It delves into the currently available methods for assessing the HMIA and proposes the integration of IoT sensors for potential indoor airflow monitoring. The present study also emphasizes incorporating human movement into ventilation studies to achieve more realistic predictions and yield more practical measures. This review advances knowledge and holds significant implications for scientific and public communities. It identifies future research directions and facilitates the development of effective ventilation strategies to enhance indoor environments and safeguard public health.

Recent Development of Nanocomposite Membranes for Water and Wastewater Treatment.

The field of membrane technology has experienced significant growth in recent years, especially in the areas of wastewater treatment and desalination [...].

Evaluation of Surface Properties and Separation Performance of NF and RO Membranes for Phthalates Removal.

Many studies indicated that phthalates, a common plasticizer, lurk silently in water bodies and can potentially harm living organisms. Therefore, removing phthalates from water sources prior to consumption is crucial. This study aims to evaluate the performance of several commercial nanofiltrations (NF) (i.e., NF3 and Duracid) and reverse osmosis (RO) membranes (i.e., SW30XLE and BW30) in removing phthalates from simulated solutions and further correlate the intrinsic properties of membranes (e.g., surface chemistry, morphology, and hydrophilicity) with the phthalates removal. Two types of phthalates, i.e., dibutyl phthalate (DBP) and butyl benzyl phthalate (BBP), were used in this work, and the effects of pH (ranging from 3 to 10) on the membrane performance were studied. The experimental findings showed that the NF3 membrane could yield the best DBP (92.5-98.8%) and BBP rejection (88.7-91.7%) regardless of pH, and these excellent results are in good agreement with the surface properties of the membrane, i.e., low water contact angle (hydrophilicity) and appropriate pore size. Moreover, the NF3 membrane with a lower polyamide cross-linking degree also exhibited significantly higher water flux compared to the RO membranes. Further investigation indicated that the surface of the NF3 membrane was severely covered by foulants after 4-h filtration of DBP solution compared to the BBP solution. This could be attributed to the high concentration of DBP presented in the feed solution owing to its high-water solubility (13 ppm) compared to BBP (2.69 ppm). Further research is still needed to study the effect of other compounds (e.g., dissolved ions and organic/inorganic matters that might be present in water) on the performance of membranes in removing phthalates.

Modification of Liquid Separation Membranes Using Multidimensional Nanomaterials: Revealing the Roles of Dimension Based on Classical Titanium Dioxide.

Membrane technology has become increasingly popular and important for separation processes in industries, as well as for desalination and wastewater treatment. Over the last decade, the merger of nanotechnology and membrane technology in the development of nanocomposite membranes has emerged as a rapidly expanding research area. The key motivation driving the development of nanocomposite membranes is the pursuit of high-performance liquid separation membranes that can address the bottlenecks of conventionally used polymeric membranes. Nanostructured materials in the form of zero to three-dimensions exhibit unique dimension-dependent morphology and topology that have triggered considerable attention in various fields. While the surface hydrophilicity, antibacterial, and photocatalytic properties of TiO2 are particularly attractive for liquid separation membranes, the geometry-dependent properties of the nanocomposite membrane can be further fine-tuned by selecting the nanostructures with the right dimension. This review aims to provide an overview and comments on the state-of-the-art modifications of liquid separation membrane using TiO2 as a classical example of multidimensional nanomaterials. The performances of TiO2-incorporated nanocomposite membranes are discussed with attention placed on the special features rendered by their structures and dimensions. The innovations and breakthroughs made in the synthesis and modifications of structure-controlled TiO2 and its composites have enabled fascinating and advantageous properties for the development of high-performance nanocomposite membranes for liquid separation.

Development of Ultrahigh Permeance Hollow Fiber Membranes via Simple Surface Coating for CO2/CH4 Separation.

Most researchers focused on developing highly selective membranes for CO2/CH4 separation, but their developed membranes often suffered from low permeance. In this present work, we aimed to develop an ultrahigh permeance membrane using a simple coating technique to overcome the trade-off between membrane permeance and selectivity. A commercial silicone membrane with superior permeance but low CO2/CH4 selectivity (in the range of 2-3) was selected as the host for surface modification. Our results revealed that out of the three silane agents tested, only tetraethyl orthosilicate (TEOS) improved the control membrane's permeance and selectivity. This can be due to its short structural chain and better compatibility with the silicone substrate. Further investigation revealed that higher CO2 permeance and selectivity could be attained by coating the membrane with two layers of TEOS. The surface integrity of the TEOS-coated membrane was further improved when an additional polyether block amide (Pebax) layer was established atop the TEOS layer. This additional layer sealed the pin holes of the TEOS layer and enhanced the resultant membrane's performance, achieving CO2/CH4 selectivity of ~19 at CO2 permeance of ~2.3 × 105 barrer. This performance placed our developed membrane to surpass the 2008 Robeson Upper Boundary.

Graphene Quantum Dot-Added Thin-Film Composite Membrane with Advanced Nanofibrous Support for Forward Osmosis.

Forward osmosis (FO) technology for desalination has been extensively studied due to its immense benefits over conventionally used reverse osmosis. However, there are some challenges in this process such as a high reverse solute flux (RSF), low water flux, and poor chlorine resistance that must be properly addressed. These challenges in the FO process can be resolved through proper membrane design. This study describes the fabrication of thin-film composite (TFC) membranes with polyethersulfone solution blown-spun (SBS) nanofiber support and an incorporated selective layer of graphene quantum dots (GQDs). This is the first study to sustainably develop GQDs from banyan tree leaves for water treatment and to examine the chlorine resistance of a TFC FO membrane with SBS nanofiber support. Successful GQD formation was confirmed with different characterizations. The performance of the GQD-TFC-FO membrane was studied in terms of flux, long-term stability, and chlorine resistance. It was observed that the membrane with 0.05 wt.% of B-GQDs exhibited increased surface smoothness, hydrophilicity, water flux, salt rejection, and chlorine resistance, along with a low RSF and reduced solute flux compared with that of neat TFC membranes. The improvement can be attributed to the presence of GQDs in the polyamide layer and the utilization of SBS nanofibrous support in the TFC membrane. A simulation study was also carried out to validate the experimental data. The developed membrane has great potential in desalination and water treatment applications.

Microalgae-Enabled Wastewater Remediation and Nutrient Recovery through Membrane Photobioreactors: Recent Achievements and Future Perspective.

The use of microalgae for wastewater remediation and nutrient recovery answers the call for a circular bioeconomy, which involves waste resource utilization and ecosystem protection. The integration of microalgae cultivation and wastewater treatment has been proposed as a promising strategy to tackle the issues of water and energy source depletions. Specifically, microalgae-enabled wastewater treatment offers an opportunity to simultaneously implement wastewater remediation and valuable biomass production. As a versatile technology, membrane-based processes have been increasingly explored for the integration of microalgae-based wastewater remediation. This review provides a literature survey and discussion of recent progressions and achievements made in the development of membrane photobioreactors (MPBRs) for wastewater treatment and nutrient recovery. The opportunities of using microalgae-based wastewater treatment as an interesting option to manage effluents that contain high levels of nutrients are explored. The innovations made in the design of membrane photobioreactors and their performances are evaluated. The achievements pave a way for the effective and practical implementation of membrane technology in large-scale microalgae-enabled wastewater remediation and nutrient recovery processes.

Improved Forward Osmosis Performance of Thin Film Composite Membranes with Graphene Quantum Dots Derived from Eucalyptus Tree Leaves.

The major challenges in forward osmosis (FO) are low water flux, high specific reverse solute flux (SRSF), and membrane fouling. The present work addresses these problems by the incorporation of graphene quantum dots (GQDs) in the polyamide (PA) layer of thin-film composite (TFC) membranes, as well as by using an innovative polyethersulfone nanofiber support for the TFC membrane. The GQDs were prepared from eucalyptus leaves using a facile hydrothermal method that requires only deionized water, without the need for any organic solvents or reducing agents. The nanofiber support of the TFC membranes was prepared using solution blow spinning (SBS). The polyamide layer with GQDs was deposited on top of the nanofiber support through interfacial polymerization. This is the first study that reports the fouling resistance of the SBS-nanofiber-supported TFC membranes. The effect of various GQD loadings on the TFC FO membrane performance, its long-term FO testing, cleaning efficiency, and organic fouling resistance were analyzed. It was noted that the FO separation performance of the TFC membranes was improved with the incorporation of 0.05 wt.% GQDs. This study confirmed that the newly developed thin-film nanocomposite membranes demonstrated increased water flux and salt rejection, reduced SRSF, and good antifouling performance in the FO process.

Enhanced Removal of Endocrine-Disrupting Compounds from Wastewater Using Reverse Osmosis Membrane with Titania Nanotube-Constructed Nanochannels.

This paper presents a comprehensive study of the performance of a newly developed titania nanotube incorporated RO membrane for endocrine-disrupting compound (EDC) removal at a low concentration. EDCs are known as an emerging contaminant, and if these pollutants are not properly removed, they can enter the water cycle and reach the water supply for residential use, causing harm to human health. Reverse osmosis (RO) has been known as a promising technology to remove EDCs. However, there is a lack of consensus on their performance, especially on the feed concentrations of EDC that vary from one source to another. In this study, polyamide thin-film composite (PA TFC) membrane was incorporated with one-dimensional titania nanotube (TNT) to mitigate trade-off between water permeability and solute rejection of EDC. The characterization indicated that the membrane surface hydrophilicity has been greatly increased with the presence of TNT. Using bisphenol A (BPA) and caffeine as model EDC, the removal efficiencies of the pristine TFC and thin-film nanocomposite (TFN) membranes were evaluated. Compared to TFC membrane, the membrane modified with 0.01% of TNT exhibited improved permeability of 50% and 49% for BPA and caffeine, respectively. A satisfactory BPA rejection of 89.05% and a caffeine rejection of 97.89% were achieved by the TNT incorporated TFN membranes. Furthermore, the greater hydrophilicity and smoother surface of 0.01 TFN membrane led to lower membrane fouling tendency under long-term filtration.

Synthesis and Optimization of Superhydrophilic-Superoleophobic Chitosan-Silica/HNT Nanocomposite Coating for Oil-Water Separation Using Response Surface Methodology.

In this current study, facile, one-pot synthesis of functionalised nanocomposite coating with simultaneous hydrophilic and oleophobic properties was successfully achieved via the sol-gel technique. The synthesis of this nanocomposite coating aims to develop a highly efficient, simultaneously oleophobic-hydrophilic coating intended for polymer membranes to spontaneously separate oil-in-water emulsions, therefore, mitigating the fouling issue posed by an unmodified polymer membrane. The simultaneous hydrophilicity-oleophobicity of the nanocoating can be applied onto an existing membrane to improve their capability to spontaneously separate oil-in-water substances in the treatment of oily wastewater using little to no energy and being environmentally friendly. The synthesis of hybrid chitosan-silica (CTS-Si)/halloysite nanotube (HNT) nanocomposite coating using the sol-gel method was presented, and the resultant coating was characterised using FTIR, XPS, XRD, NMR, BET, Zeta Potential, and TGA. The wettability of the nanocomposite coating was evaluated in terms of water and oil contact angle, in which it was coated onto a polymer substrate. The coating was optimised in terms of oil and water contact angle using Response Surface Modification (RSM) with Central Composite Design (CCD) theory. The XPS results revealed the successful grafting of organosilanes groups of HNT onto the CTS-Si denoted by a wide band between 102.6-103.7 eV at Si2p. FTIR spectrum presented significant peaks at 3621 cm-1; 1013 cm-1 was attributed to chitosan, and 787 cm-1 signified the stretching of Si-O-Si on HNT. 29Si, 27Al, and 13H NMR spectroscopy confirmed the extensive modification of the particle's shells with chitosan-silica hybrid covalently linked to the halloysite nanotube domains. The morphological analysis via FESEM resulted in the surface morphology that indicates improved wettability of the nanocomposite. The resultant colloids have a high colloid stability of 19.3 mV and electrophoretic mobility of 0.1904 µmcm/Vs. The coating recorded high hydrophilicity with amplified oleophobic properties depicted by a low water contact angle (WCA) of 11° and high oil contact angle (OCA) of 171.3°. The optimisation results via RSM suggested that the optimised sol pH and nanoparticle loadings were pH 7.0 and 1.05 wt%, respectively, yielding 95% desirability for high oil contact angle and low water contact angle.

Removal of emerging organic micropollutants via modified-reverse osmosis/nanofiltration membranes: A review.

Hazardous micropollutants (MPs) such as pharmaceutically active compounds (PhACs), pesticides and personal care products (PCPs) have emerged as a critical concern nowadays for acquiring clean and safe water resources. In the last few decades, innumerable water treatment methods involving biodegradation, adsorption and advanced oxidation process have been utilized for the removal of MPs. Of these methods, membrane technology has proven to be a promising technique for the removal of MPs due to its sustainability, high efficiency and cost-effectiveness. Herein, the aim of this article is to provide a comprehensive review regarding the MPs rejection mechanisms of reverse osmosis (RO) and nanofiltration (NF) membranes after incorporation of nanomaterials and also surface modification atop the PA layer. Size exclusion, adsorption and electrostatic charge interaction mechanisms play important roles in governing the MP removal rate. In addition, this review also discusses the state-of-the-art research on the surface modification of thin film composite (TFC) membrane and nanomaterials-incorporated thin film nanocomposite (TFN) membrane in enhancing MPs removal performance. It is hoped that this review can provide insights in modifying the physicochemical properties of NF and RO membranes to achieve better performance in water treatment process, particularly for the removal of emerging hazardous substances.

Development of ß-cyclodextrin crosslinked citric acid encapsulated in polypropylene membrane protected-µ-solid-phase extraction device for enhancing the separation and preconcentration of endocrine disruptor compounds.

Endocrine disruptor compounds (EDCs) such as plasticisers, surfactants, pharmaceutical products, personal care products and pesticides are frequently released into the environmental waters. Therefore, a sensitive and environmentally friendly method is entailed to quantify these compounds at their trace level concentrations. This study encapsulated the ß-cyclodextrin crosslinked with citric acid in a polypropylene membrane protected-µ-solid phase extraction (BCD-CA µ-SPE) device for preconcentrating the EDCs (triclosan, triclocarban, 2-phenylphenol, 4-tert-octylphenols and bisphenol A) in real water samples before the analysis by high-performance liquid chromatography. FT-IR and TGA results indicated that BCD-CA was successfully synthesised with the formation of ester linkage (1078.33 cm-1) and O-H stretching from carboxylic acid (3434.70 cm-1) with higher thermal stability as compared with native CD with the remaining weight above 72.1% at 500 °C. Several critical parameters such as the sorbent loading, type and amount of salts, extraction time, sample volume, sample pH, type and volume of desorption solvents and desorption time were sequentially optimised and statistically validated. Under the optimum condition, the use of BCD-CA µ-SPE device had manifested good linearity (0.5-500 µg L-1) with the determination of the coefficient range of 0.9807-0.9979. The p-values for the F-test and t-test (6.60 × 10-8 - 1.77 × 10-5) were lesser than 0.05 and low detection limits ranging from 0.27 to 0.84 µg L-1 for all studied EDCs. The developed technique was also successfully applied for EDC analyses in four distinct real water samples, namely, wastewater, river water, tap water and mineral water, with good EDCs recoveries (80.2%-99.9%), low relative standard deviations (0.1%-3.8%, n = 3) with enrichment factor ranging from 9 to 82 folds. These results signified the potential of the BCD-CA µ-SPE device as an efficient, sensitive, and environmentally friendly approach for analyzing EDCs.

Biomolecule-Enabled Liquid Separation Membranes: Potential and Recent Progress.

The implementation of membrane surface modification to enhance the performance of membrane-based separation has become a favored strategy due to its promise to address the trade-off between water permeability and salt rejection as well as to improve the durability of the membranes. Tremendous work has been committed to modifying polymeric membranes through physical approaches such as surface coating and ontology doping, as well as chemical approaches such as surface grafting to introduce various functional groups to the membrane. In the context of liquid separation membranes applied for desalination and water and wastewater treatment, biomolecules have gained increasing attention as membrane-modifying agents due to their intriguing structural properties and chemical functionalities. Biomolecules, especially carbohydrates and proteins, exhibit attractive features, including high surface hydrophilicity and zwitterionic and antimicrobial properties that are desired for liquid separation membranes. In this review, we provide an overview of the recent developments in biomolecule-enabled liquid separation membranes. The roles and potentials of some commonly explored biomolecules in heightening the performance of polymeric membranes are discussed. With the advancements in material synthesis and the need to answer the call for more sustainable materials, biomolecules could serve as attractive alternatives for the development of high-performance composite membranes.

The State-of-the-Art Functionalized Nanomaterials for Carbon Dioxide Separation Membrane.

Nanocomposite membrane (NCM) is deemed as a practical and green separation solution which has found application in various fields, due to its potential to delivery excellent separation performance economically. NCM is enabled by nanofiller, which comes in a wide range of geometries and chemical features. Despite numerous advantages offered by nanofiller incorporation, fabrication of NCM often met processing issues arising from incompatibility between inorganic nanofiller and polymeric membrane. Contemporary, functionalization of nanofiller which modify the surface properties of inorganic material using chemical agents is a viable approach and vigorously pursued to refine NCM processing and improve the odds of obtaining a defect-free high-performance membrane. This review highlights the recent progress on nanofiller functionalization employed in the fabrication of gas-separative NCMs. Apart from the different approaches used to obtain functionalized nanofiller (FN) with good dispersion in solvent and polymer matrix, this review discusses the implication of functionalization in altering the structure and chemical properties of nanofiller which favor interaction with specific gas species. These changes eventually led to the enhancement in the gas separation efficiency of NCMs. The most frequently used chemical agents are identified for each type of gas. Finally, the future perspective of gas-separative NCMs are highlighted.

Recent Advances of Polymeric Membranes in Tackling Plasticization and Aging for Practical Industrial CO2/CH4 Applications-A Review.

Membranes are a promising technology for bulk CO2 separation from natural gas mixtures due to their numerous advantages. Despite the numerous fundamental studies on creating better quality membrane efficiency, scaling up the research work for field testing requires huge efforts. The challenge is to ensure the stability of the membrane throughout the operation while maintaining its high performance. This review addresses the key challenges in the application of polymeric technology for CO2 separation, focusing on plasticization and aging. A brief introduction to the properties and limitations of the current commercial polymeric membrane is first deliberated. The effect of each plasticizer component in natural gas towards membrane performance and the relationship between operating conditions and the membrane efficiency are discussed in this review. The recent technological advancements and techniques to overcome the plasticization and aging issues covering polymer modification, high free-volume polymers, polymer blending and facilitated transport membranes (FTMs) have been highlighted. We also give our perspectives on a few main features of research related to polymeric membranes and the way forwards. Upcoming research must emphasize mixed gas with CO2 including minor condensable contaminants as per real natural gas, to determine the competitive sorption effect on CO2 permeability and membrane selectivity. The effects of pore blocking, plasticization and aging should be given particular attention to cater for large-scale applications.

Nanocrystalline cellulose incorporated biopolymer tailored polyethersulfone mixed matrix membranes for efficient treatment of produced water.

Membrane technology is a sustainable method to remove pollutants from petroleum wastewater. However, the presence of hydrophobic oil molecules and inorganic constituents can cause membrane fouling. Biomass derived biopolymers are promising renewable materials for membrane modification. In this study, fouling resistant biopolymer N-phthaloylchitosan (CS)- based polythersulfone (PES) mixed matrix membranes (MMMs) incorporated with nanocrystalline cellulose (NCC) was fabricated via phase inversion method and applied for produced water (PW) treatment. The morphological and Fourier-transform infrared spectroscopy (FTIR) analyses of the as-prepared NCC evidenced the formation of fibrous sheet-like structure and the presence of hydrophilic group. The membrane morphology and AFM analysis showed that the NCC altered the surface and cross-sectional morphology of the CS-PES MMMs. The tensile strength of NCC-CS-PES MMMs was also enhanced. 0.5 wt% NCC-CS-PES MMMs displayed a water permeability of 1.11 × 10-7 m/s.kPa with the lowest contact angle value of 61°. It affirmed that its hydrophilicity increased through the synergetic interaction between CS biopolymer and NCC. The effect of process variables such as transmembrane pressure (TMP) and synthetic produced water (PW) concentration were evaluated for both neat PES and NCC-CS-PES MMMs membranes. 0.5 wt% NCC-CS-PES MMMs exhibited the highest PW rejection of 98% when treating 50 mgL-1 of synthetic PW at a transmembrane pressure (TMP) of 200 kPa. The effect of nano silica and sodium chloride on the long-term PW filtration of NCC-CS-PES MMMs was also investigated.

Low-cost silica based ceramic supported thin film composite hollow fiber membrane from guinea corn husk ash for efficient removal of microplastic from aqueous solution.

In this study, an economic silica based ceramic hollow fiber (HF) microporous membrane was fabricated from guinea cornhusk ash (GCHA). A silica interlayer was coated to form a defect free silica membrane which serves as a support for the formation of thin film composite (TFC) ceramic hollow fiber (HF) membrane for the removal of microplastics (MPs) from aqueous solutions. Polyacrylonitrile (PAN), polyvinyl-chloride (PVC), polyvinylpyrrolidone (PVP) and polymethyl methacrylate (PMMA) are the selected MPs The effects of amine monomer concentration (0.5 wt% and 1 wt%) on the formation of poly (piperazine-amide) layer via interfacial polymerization over the GCHA ceramic support were also investigated. The morphology analysis of TFC GCHA HF membranes revealed the formation of a poly (piperazine-amide) layer with narrow pore arrangement. The pore size of TFC GCHA membrane declined with the formation of poly (piperazine-amide) layer, as evidenced from porosimetry analysis. The increase of amine concentration reduced the porosity and water flux of TFC GCHA HF membranes. During MPs filtration, 1 wt% (piperazine) based TFC GCHA membrane showed a lower transmission percentage of PVP (2.7%) and other suspended MPs also displayed lower transmission. The impact of humic acid and sodium alginate on MPs filtration and seawater pretreatment were also analyzed.