RESUMEN
Imidazolium salts were prepared which possess 2-ethoxyethyl pivalate or 2-(2-ethoxyethoxy)ethyl pivalate groups as amphiphilic side chains with oxygen donors as well as n-butyl substituents as hydrophobic groups. The N-heterocyclic carbenes of the salts, characterized by 7Li and 13C NMR spectroscopy as well as by Rh and Ir complex formation, were used as starting materials for the preparation of the corresponding imidazole-2-thiones and imidazole-2-selenones. Flotation experiments in Hallimond tubes under variation of the air flow, pH, concentration and flotation time were performed. The title compounds proved to be suitable collectors for the flotation of lithium aluminate and spodumene for lithium recovery. Recovery rates up to 88.9% were obtained when the imidazole-2-thione was used as collector.
RESUMEN
In the present work experiments for single mineral flotation against LiAlO2 and melilite s.s. were carried out for seven ionic liquids (ILs). From these, IL-1 with an imidazolium cation and a bromide anion and IL-7 with a pyridinium cation and a bromide anion were selected for further flotation experiments (dosage, pH). Flotation experiments were also conducted using naphthenic acid, a conventional flotation fatty acid-based collector, and FS-2, a commercial collector in order to compare the results with ILs. Moreover, the effects of different anions in the ILs on the flotation were evaluated and a significant influence on the hardness of anions was found on the flotation process. Finally, a pre-functionalization was also explored with modified cholesterol derivatives, comparing the effect of cholesterylsulfate and cholesterylphosphate on the flotation of LiAlO2 and melilite s.s. This study is vital for the further optimization of lithium recovery from the pyrometallurgical recycling path of lithium-ion batteries and the flotation of primary minerals such as aluminosilicates.
RESUMEN
In this work froth flotation studies with LiAlO2 (lithium-containing phase) and Melilite solid solution (gangue phase) are presented. The system was optimized with standard collectors and with compounds so far not applied as collectors. Furthermore, the principle of self-assembled monolayers was introduced to a froth flotation process for the first time resulting in excellent yields and selectivities.
RESUMEN
Electromobility will play a key role in order to reach the specified ambitious greenhouse gas reduction targets in the German transport sector of 42% between 1990 and 2030. Subsequently, a significant rise in the sale of electric vehicles (EVs) is to be anticipated in future. The amount of EVs to be recycled will rise correspondingly after a delay. This includes the recyclable power electronics modules which are incorporated in every EV as an important component for energy management. Current recycling methods using car shredders and subsequent post shredder technologies show high recycling rates for the bulk metals but are still associated with high losses of precious and strategic metals such as gold, silver, platinum, palladium and tantalum. For this reason, the project 'Electric vehicle recycling 2020 - key component power electronics' developed an optimised recycling route for recycling power electronics modules from EVs which is also practicable in series production and can be implemented using standardised technology. This 'WEEE recycling route' involves the disassembly of the power electronics from the vehicle and a subsequent recycling in an electronic end-of-life equipment recycling plant. The developed recycling process is economical under the current conditions and raw material prices, even though it involves considerably higher costs than recycling using the car shredder. The life cycle assessment shows basically good results, both for the traditional car shredder route and the developed WEEE recycling route: the latter provides additional benefits from some higher recovery rates and corresponding credits.