RESUMEN
Structural colors offer a myriad of advantages over conventional pigment-based colors, which often rely on toxic chemical substances that are prone to UV degradation. To take advantage of these benefits in demanding environments, there is growing interest in producing structural colors from ceramics. Polymer-derived ceramics (PDCs) emerge as a compelling choice, presenting two distinct advantages: their enhanced shape ability in their polymeric state associated with impressive temperature resistance once converted to ceramics. This study pioneers the fabrication of noniridescent structural colors from silicon oxycarbide (SiOC) PDC, enabled by the nanostructuring of an inverse photonic glass within the PDC material. This design, a functionally graded material with an inverse photonic glass (FGM-PhG) structure, leverages the innate light-absorbing properties of SiOC, yielding a vivid structural color that maintains its saturation even in white surroundings. This study elucidates the process-structure-properties relationship for the obtained structural colors by investigating each layer of the functionally graded material (FGM) in a stepwise coating deposition process. To further emphasize the exceptional processing flexibility of PDCs, the three-step process is later transferred to an additive manufacturing approach. Finally, the FGM-PhG structural colors are demonstrated to have remarkable thermal stability up to 1000 °C for 100 h, possibly making them the most thermally stable ceramic structural colors to date.
RESUMEN
Flexible piezocapacitive sensors utilizing nanomaterial-polymer composite-based nanofibrous membranes offer an attractive alternative to more traditional piezoelectric and piezoresistive wearable sensors owing to their ultralow powered nature, fast response, low hysteresis, and insensitivity to temperature change. In this work, we propose a facile method of fabricating electrospun graphene-dispersed PVAc nanofibrous membrane-based piezocapacitive sensors for applications in IoT-enabled wearables and human physiological function monitoring. A series of electrical and material characterization experiments were conducted on both the pristine and graphene-dispersed PVAc nanofibers to understand the effect of graphene addition on nanofiber morphology, dielectric response, and pressure sensing performance. Dynamic uniaxial pressure sensing performance evaluation tests were conducted on the pristine and graphene-loaded PVAc nanofibrous membrane-based sensors for understanding the effect of two-dimensional (2D) nanofiller addition on pressure sensing performance. A marked increase in the dielectric constant and pressure sensing performance was observed for graphene-loaded spin coated membrane and nanofiber webs respectively, and subsequently the micro dipole formation model was invoked to explain the nanofiller-induced dielectric constant enhancement. The robustness and reliability of the sensor have been underscored by conducting accelerated lifetime assessment experiments entailing at least 3000 cycles of periodic tactile force loading. A series of tests involving human physiological parameter monitoring were conducted to underscore the applicability of the proposed sensor for IoT-enabled personalized health care, soft robotics, and next-generation prosthetic devices. Finally, the easy degradability of the sensing elements is demonstrated to emphasize their suitability for transient electronics applications.
