RESUMEN
One of the most enticing approaches to environmental restoration and energy conversion is photocatalysis powered by solar light. Traditional photocatalysts have limited practical uses due to inadequate light absorption, charge separation, and unknown reaction mechanisms. Discovering new visible-light photocatalysts and investigating their modification is crucial in photocatalysis. Bi-based photocatalytic nanomaterials have gotten much interest as they exhibit distinctive geometric shapes, flexible electronic structures, and good photocatalytic performance under visible light. They can be employed as stand-alone photocatalysts for pollution control and energy production, but they do not have optimum efficacy. As a result, their photocatalytic effectiveness has been significantly improved in the recent decades. Numerous newly created concepts and methodologies have brought significant progress in defining the fundamental features of photocatalysts, upgrading the photocatalytic ability, and understanding essential reactions of the photocatalytic process. This paper provides insights into the characteristics of Bi-based photocatalysts, making them a promising future nanomaterial for environmental remediation. The current review discusses the fabrication techniques and enhancement in Bi-based semiconductor photocatalysts. Various environmental applications, such as H2 generation and elimination of water pollutants, are also discussed in terms of semiconductor photocatalysis. Future developments will be guided by the uses, issues, and possibilities of Bi-based photocatalysts.
RESUMEN
CONTEXT: Spontaneous spinal epidural hematoma (SSEH) is a rare idiopathic condition that leads to acute onset of neurological deficits, which if not recognized early can have catastrophic consequences. The definition and pathophysiology of this condition remain controversial. High index of suspicion followed by T2-weighted gradient echo sequences are particularly useful in early diagnosis. Management consists of prompt surgical decompression of the hematoma though a recent trend is toward non-surgical treatment. FINDINGS: A 70-year-old man presented with acute onset neck pain with a radicular component and rapidly progressive quadriparesis. Magnetic resonance imaging revealed a posteriorly located cervical extradural hematoma with cord compression that was promptly evacuated. Functional recovery to near normal function occurred within 24 hours of surgery. CONCLUSION: SSEH in its true idiopathic form is a rare pathologic entity. Because of the high risk of poor outcome without treatment, SSEH should be a diagnostic possibility when presentation is even slightly suggestive. Prompt surgical evacuation of the hematoma leads to a favorable neurological outcome, whereas delay in treatment can be disastrous. The role of conservative management needs to be proven and should be tailored on an individual basis.