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1.
Sci Rep ; 13(1): 22650, 2023 Dec 19.
Artículo en Inglés | MEDLINE | ID: mdl-38114537

RESUMEN

This paper investigates the hemp limecrete mechanical and microstructural performance of a new sustainable and environmental friendly building material. Several studies have investigated the hemp limecrete focusing on the non-structural applications. The newly developed hemp limecrete consists of high mechanical and microstructural properties. The specimens were prepared with varying lengths and proportions of hemp fibers with lime and tested for compressive strength, flexural strength, thermal conductivity and microstructural analysis like SEM and EDS. The study found that the optimal fiber content for making mortars was between 2 and 4%. This conclusion was reached after analyzing the influence of fiber length and ratio on the properties of the mortars. The dry unit weight decreased when the fiber content was higher than 4%. In terms of strength, the study found that the flexural strength of the hemp limecrete improved with an increase in fiber ratio, but the compressive strength decreased. However, with 2% hemp fiber, compressive strengths of 3.48 MPa and above were obtained. The study also highlighted the good thermal insulation properties and dimensional stability of hemp limecrete. These findings have important implications for the use of hemp limecrete as a sustainable building material. The results suggest that hemp limecrete has the potential to be a viable alternative to conventional concrete in specific applications, particularly in areas where environmental sustainability is a priority.

2.
Sci Rep ; 13(1): 2350, 2023 02 09.
Artículo en Inglés | MEDLINE | ID: mdl-36759530

RESUMEN

Lignocellulose biomass has a tremendous potential as renewable biomaterials for fostering the "bio-based society" and circular bioeconomy paradigm. It requires efficient use and breakdown of fiber cell walls containing mainly cellulose, hemicellulose and lignin biopolymers. Despite their great importance, there is an extensive debate on the true structure of fiber walls and knowledge on the macromolecular nano-organization is limited and remains elusive in 3D. We employed dual-axis electron tomography that allows visualization of previously unseen 3D macromolecular organization/biopolymeric nano-architecture of the secondary S2 layer of Norway spruce fiber wall. Unprecedented 3D nano-structural details with novel insights into cellulose microfibrils (~ 2 nm diameter), macrofibrils, nano-pore network and cell wall chemistry (volume %) across the S2 were explored and quantified including simulation of structure related permeability. Matrix polymer association with cellulose varied between microfibrils and macrofibrils with lignin directly associated with MFs. Simulated bio-nano-mechanical properties revealed stress distribution within the S2 and showed similar properties between the idealized 3D model and the native S2 (actual tomogram). Present work has great potential for significant advancements in lignocellulose research on nano-scale understanding of cell wall assembly/disassembly processes leading to more efficient industrial processes of functionalization, valorization and target modification technologies.


Asunto(s)
Lignina , Nanoestructuras , Lignina/metabolismo , Tomografía con Microscopio Electrónico/métodos , Celulosa/química , Pared Celular/metabolismo
3.
Materials (Basel) ; 15(12)2022 Jun 10.
Artículo en Inglés | MEDLINE | ID: mdl-35744203

RESUMEN

The production and utilization of concrete and concrete-based products have drastically increased with the surge of construction activities over the last decade, especially in countries such as China and India. Consequently, this has resulted in a corresponding increase in the energy used for the production of ready-mixed concrete. One approach to reduce the cost of concrete manufacturing is to reduce the energy required for the manufacturing process. The main hypothesis of this study is that the power required for mixing the concrete can be reduced through the use of mineral admixtures in the mix design. Optimization of energy consumption during mixing using admixtures in concrete manufacturing is the predominant focus of this article. To achieve this objective, power consumption data were measured and analyzed throughout the concrete mixing process. The power consumption curve is the only source to distinguish the behavior of the different materials used in the concrete in a closed chamber. In the current research, fly ash and ground granulated blast-furnace slag (GGBS) were used as mineral admixtures to produce ready-mixed concrete. The experimental study focused on the influence of GGBS and fly ash on power consumption during concrete mixing. The results indicated that the use of a higher content of GGBS is more beneficial in comparison to the use of fly ash in the mix due to the lower mixing time required to achieve homogeneity in the mixing process. It was found that the amount of energy required for mixing is directly related to the mixing time for the mix to achieve homogeneity.

4.
Materials (Basel) ; 15(12)2022 Jun 16.
Artículo en Inglés | MEDLINE | ID: mdl-35744338

RESUMEN

The construction industry relies heavily on concrete as a building material. The coarse aggregate makes up a substantial portion of the volume of concrete. However, the continued exploitation of granite rock for coarse aggregate results in an increase in the future generations' demand for natural resources. In this investigation, coconut shell was used in the place of conventional aggregate to produce coconut shell lightweight concrete. Class F fly ash was used as a partial substitute for cement to reduce the high cement content of lightweight concrete. The impact of steel fiber addition on the compressive strength and flexural features of sustainable concrete was investigated. A 10% weight replacement of class F fly ash was used in the place of cement. Steel fiber was added at 0.25, 0.5, 0.75, and 1.0% of the concrete volume. The results revealed that the addition of steel fibers enhanced the compressive strength by up to 39%. The addition of steel fiber to reinforced coconut shell concrete beams increased the ultimate moment capacity by 5-14%. Flexural toughness was increased by up to 45%. The span/deflection ratio of all fiber-reinforced coconut shell concrete beams met the IS456 and BS 8110 requirements. Branson's and the finite element models developed in this study agreed well with the experimental results. As a result, coconut shell concrete with steel fiber could be considered as a viable and environmentally-friendly construction material.

5.
Materials (Basel) ; 15(9)2022 Apr 25.
Artículo en Inglés | MEDLINE | ID: mdl-35591435

RESUMEN

Generally, the concrete with higher strength appears to produce brittle failure more easily. However, the use of mineral admixture can help in enhancing the ductility, energy dissipation, and seismic energy in the designed concrete. This paper presents energy absorption capacity, stiffness degradation, and ductility of the copper slag (CS) admixed reinforced concrete with fly ash (FA) beams subjected to forward cyclic load. The forward cyclic load was applied with the help of servo-hydraulic universal testing machines with 250 kN capacity. Twenty-four beams with a size of 100 mm × 150 mm × 1700 mm made with CS replaced for natural sand from 0% to 100% at an increment of 20%, and FA was replaced for cement from 0% to 30% with an increment of 10% were cast. Beams are designed for the grade of M30 concrete. Based on the preliminary investigation results, compressive strength of the concrete greatly increased when adding these two materials in the concrete. Normally, Grade of concrete can change the behaviour of the beam from a brittle manner to be more ductile manner. So, in this work, flexural behaviour of RC beams are studied with varying compressive strength of concrete. Experimental results showed that the RC beam made with 20% FA and 80% CS (FA20CS80) possesses higher ultimate load-carrying capacity than the control concrete beam. It withstands up to 18 cycles of loading with an ultimate deflection of 60 mm. The CS and FA admixed reinforced concrete composite beams have excellent ultimate load carrying capacity, stiffness, energy absorption capacity, and ductility indices compared to the control concrete beam.

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