Bio-inspired wrinkle microstructures for random lasing governed by surface roughness.

A method for fabricating bio-inspired scattering substrates based on polydimethylsiloxane (PDMS) for spatially incoherent random lasing is presented. The leaves of monstera and piper sarmentosum plants are used to mold PDMS polymer to form wrinkle-like scattering substrates, which are then used with a liquid gain medium for random lasing. Scattering is attributed to the surface roughness (Sa) of the samples. The rougher sample with 5.2 µm Sa shows a two-mode stable lasing with a 2 nm linewidth and a lower threshold fluence of 0.2mJ/cm2 compared to the sample with smaller Sa (3.6 µm) with a linewidth of 5 nm and a threshold fluence of 0.5mJ/cm2. The waveguide theory substantiates the results of incoherent random lasing through a relation between the microstructure feature size and the mean free path. Power Fourier transform analysis is used to deduce the resonant cavity length of 180 µm in the rougher sample, and the observed variations in cavity length with Sa validate the optical feedback. PDMS being hydrophobic, the scattering substrate can be reused by wiping off the gain medium. This Letter paves the way for facile fabrication methods of bio-inspired random lasers for sensing and imaging applications.

Stokes mode Raman random lasing in a fully biocompatible medium.

We demonstrate for the first time, to the best of our knowledge, Raman random lasing in a continuous-wave (CW) excited, completely biocompatible and biodegradable carrot medium naturally composed of fibrous cellulose scattering medium and rich carotene Raman gain medium. The CW-laser-induced photoluminescence threshold and linewidth analysis at the Stokes modes of carotene show a characteristic lasing action with a threshold of 130 W/cm2 and linewidth narrowing with mode Q factor up to 1300. Polarization study of output modes reveals that lasing mode mostly retains the source polarization state. A neat and interesting linear temperature dependence of emission intensity is also discussed. Easy availability, biocompatibility, excitation-dependent emission wavelength selectivity, and temperature sensitivity are hallmarks of this elegant Raman laser medium with strong potential as an optical source for applications in bio-sensing, imaging, and spectroscopy.

Femtosecond laser-pumped plasmonically enhanced near-infrared random laser based on engineered scatterers.

In this Letter, we report on the design, fabrication, and implementation of a novel plasmon-mode-driven low-threshold near-infrared (NIR) random laser (RL) in the 850-900 nm range based on plasmonic ZnS@Au core-shell scatterers. Plasmon modes in the NIR region are used for nanoscale scatterer engineering of ZnS@Au core-shell particles to enhance scattering, as against pristine ZnS. This plasmonic scattering enhancement coupled with femtosecond (fs) laser pumping is shown to cause a three-fold lasing threshold reduction from 325 µJ/cm2 to 100 µJ/cm2 and a mode Q-factor enhancement from 200 to 540 for ZnS@Au-based RL, as compared to pristine ZnS-based RL. Local field enhancement due to plasmonic ZnS@Au scatterers, as evidenced in the finite-difference time-domain simulation, further adds to this enhancement. This work demonstrates a novel scheme of plasmonic mode coupling in the NIR region and fs excitation in a random laser photonic system, overcoming the inherent deficiencies of weak absorption of gain media and poor scattering cross sections of dielectric scatterers for random lasing in the NIR spectrum.