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1.
Int J Biol Macromol ; 279(Pt 2): 134866, 2024 Sep 02.
Artículo en Inglés | MEDLINE | ID: mdl-39233159

RESUMEN

In this study, the PVA/starch blend films were prepared by dry melting method. The microstructure showed that the starch existed in the continuous PVA matrix in granular structure. When the amount of starch was 30 wt%, the tensile strength increased from 12.8 to 14.7 MPa, and the elastic modulus increased from 15.4 to 20.5 MPa, and the water absorption increased by about 2 %. The addition of starch increased the Tmax by 8.1-29.64 °C compared to pure PVA. Considering the mechanical, hydrophilic and optical properties of the blend films, PVA/starch at 7:3 was the most promising packaging material. Notably, the blend films exhibit great reusability and renewability. Overall, these findings highlight the potential of PVA/starch blend films as environmentally friendly materials with enhanced properties.

2.
Int J Biol Macromol ; 253(Pt 1): 126536, 2023 Dec 31.
Artículo en Inglés | MEDLINE | ID: mdl-37634775

RESUMEN

The adverse effects of heavy metal pollutants in wastewater have threatened human health in recent decades. Therefore, the development of absorbents for such pollutants is essential to overcome these problems. Electrospun nanofibers are often used for wastewater treatment owing to their high porosity and high specific surface area. Zein from plants and collagen from animals are vulnerable to moisture, which limits its broad application in practice. However fully biodegradable polyvinyl alcohol (PVA), which is soluble in water, can be mixed with protein individually to overcome the limitation. In this work, the two proteins described above and PVA were combined to prepare protein nanofibers by electrospinning technology, which could achieve adsorption of Cu2+. As the protein content increased, the adsorption properties of the obtained nanofibers for Cu2+ showed a rising and then decreasing trend, with the highest point at 50 % of protein content, especially the collagen nanofibers, which reached 24.62 mg/g. Both protein nanofibers reached adsorption equilibrium after 15 h, but overall, collagen nanofibers showed a superior adsorption performance for Cu2+ than that by zein nanofibers. In the process of Cu2+ adsorption by protein nanofibers, both physical and chemical effect existed, and the physical effect played the leading role.


Asunto(s)
Contaminantes Ambientales , Metales Pesados , Nanofibras , Contaminantes Químicos del Agua , Zeína , Humanos , Alcohol Polivinílico/química , Nanofibras/química , Adsorción , Iones , Colágeno , Contaminantes Químicos del Agua/química
3.
Materials (Basel) ; 16(12)2023 Jun 16.
Artículo en Inglés | MEDLINE | ID: mdl-37374623

RESUMEN

Intrinsic self-healing polymers via dynamic covalent bonds have been attracting extensive attention because of their repeatable self-healing property. Herein, a novel self-healing epoxy resin was synthesized with disulfide-containing curing agent via the condensation of dimethyl 3,3'-dithiodipropionate (DTPA) and polyether amine (PEA). Therefore, in the structure of cured resin, flexible molecular chains and disulfide bonds were imported into the cross-linked polymer networks for triggering self-healing performance. The self-healing reaction of cracked samples was realized under a mild condition (60 °C for 6 h). The distribution of flexible polymer segments, disulfide bonds and hydrogen bonds in cross-linked networks plays a great role in the self-healing process of prepared resins. The molar ratio of PEA and DTPA strongly affects the mechanical performance and self-healing property. Especially when that molar ratio of PEA to DTPA is 2, the cured self-healing resin sample showed great ultimate elongation (795%) and excellent healing efficiency (98%). The products can be used as an organic coating, in which the crack could self-repair during a limited time. The corrosion resistance of a typical cure coating sample has been testified by an immersion experiment and electrochemistry impedance spectrum (EIS). This work provided a simple and low-cost route to prepare a self-healing coating for prolonging the service life of conventional epoxy coatings.

4.
Food Chem ; 418: 135851, 2023 Aug 30.
Artículo en Inglés | MEDLINE | ID: mdl-36944306

RESUMEN

To extend the shelf life of sweet cherries (Prunus avium L.) and considering the environmental problems caused by traditional packaging materials, novel Zein/Gelatin-proanthocyanidins-zinc oxide nanoparticles (ZE/GE-PC-ZnO) and Zein/Gelatin-gallic acid-zinc oxide nanoparticles (ZE/GE-GA-ZnO) protein-based composite nanofiber films were prepared by electrospinning. According to the results, ZE/GE-PC-ZnO and ZE/GE-GA-ZnO films' contact angles were higher than those of Zein/Gelatin film by 28.91% and 21.27%, and their antioxidant activities were 5 and 9 times higher, respectively. Moreover, ZE/GE-PC-ZnO film showed good inhibitory activity against B. cinerea. On the eleventh day of the cherry packaging test, compared to unwrapped cherries, the losses of weight and firmness of wrapped fruit were reduced by more than 20% and 60%, respectively. Respiration time was delayed by 5 days, and the peak of ethylene release was decreased by nearly half. In conclusion, these two nanofiber films were viable packaging materials that fulfilled global strategies for green development.


Asunto(s)
Nanofibras , Zeína , Óxido de Zinc , Biopolímeros , Embalaje de Alimentos/métodos , Frutas , Gelatina , Óxido de Zinc/farmacología , Nanopartículas del Metal
5.
Food Chem ; 405(Pt B): 134991, 2023 Mar 30.
Artículo en Inglés | MEDLINE | ID: mdl-36435113

RESUMEN

In order to overcome the environmental problems posed by traditional packaging materials and taking into account the degradation factors, a natural polypeptides-based nanofiber rich in different polyphenols was prepared by electrospinning technique and has been explored as an active food packaging material. The results showed that the introduction of polyphenols improved the hydrophobicity and oxidation resistance of the natural polypeptides based nanofabric. The antioxidant value was 82.5% after incorporation of 15% gallic acid, which was ten times more than that of the natural polypeptides-based nanofabrics without polyphenols. Through the packaging test of wrapped cherries, it was found that the nanofabric films greatly improved the preservation performance of cherries. Water loss, hardness and gas release were significantly enhanced when compared with those of unwrapped cherries. In this work, the zein/gelatin film with 15% gallic acid or 10% procyanidins polyphenols exhibited the best fresh-keeping performance and remarkable effect thus leading to potential application aspect.


Asunto(s)
Antioxidantes , Polifenoles , Conservación de Alimentos , Péptidos , Ácido Gálico
6.
Int J Biol Macromol ; 120(Pt A): 475-490, 2018 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-30145158

RESUMEN

The environmental crisis caused by the use of petroleum-based nondegradable polymers and the impending petroleum finite resources have directly threatened human being's sustainable development. Therefore, ecofriendly polymers based on natural renewable resources are attracting more and more attention. As the byproducts of soy oil industries, soy protein, is regarded as a viable alternative for petroleum-based polymeric products. In order to improve the physical properties, especially the mechanical properties and water resistance that limit their extensive applications, different modifications were adopted. Among these efforts, incorporating nanoparticles and blending with other polymers are proved to be effective ways. The properties of the resulting materials are highly dependent on the processing methods, nature of the components, dispersion status and the compatibility. This review intends to provide a clear overview on preparation, properties, and applications of soy-protein-based materials. These biodegradable materials will find more and more potential applications in biodegradable foams, edible films, packaging materials, biomedical materials, etc.


Asunto(s)
Embalaje de Alimentos , Polímeros/química , Energía Renovable , Proteínas de Soja/química , Materiales Biocompatibles/química , Humanos , Nanopartículas/química , Proteínas de Soja/metabolismo , Proteínas de Soja/ultraestructura
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