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Talanta ; 161: 713-720, 2016 Dec 01.
Artículo en Inglés | MEDLINE | ID: mdl-27769471

RESUMEN

In this work, we report a novel Au-Pt bimetallic nanoparticles (Au-PtNPs) decorated on the surface of nitrogen-doped graphene (NG) functionalized with 1, 3, 6, 8-pyrene tetra sulfonic acid sodium salt (PyTS) by direct electrodeposition method. The results of scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and electrochemical impendence spectrum (EIS) reveal that the Au-PtNPs were successfully anchored on the surface of NG sheets with a diameter of 20-40nm. Further, the prepared Au-PtNPs/PyTS-NG nanocomposite exhibits superior catalytic activity for the oxidation of nitrite. Under optimal experimental conditions, an amperometric sensor with a linear range of 0.5-1621µM and a detection limit of 0.19µM (S/N=3) for the detection of nitrite was set up and applied to real samples.

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