RESUMEN
Giant power conversion efficiency is achieved by using bifunction ZrO2 : Er3+ /Yb3+ assisted co-sensitised dye-sensitized solar cells. The evolution of the crystalline structure and its microstructure are examined by X-ray diffraction, scanning electron microscopy studies. The bi-functional behaviour of ZrO2 : Er3+ /Yb3+ as upconversion, light scattering is confirmed by emission and diffused reflectance studies. The bi-function ZrO2 : Er3+ /Yb3+ (pH=3) assisted photoanode is co-sensitized by use of N719 dye, squaraine SPSQ2 dye and is sandwiched with Platinum based counter electrode. The fabricated DSSC exhibited a giant power conversion efficiency of 12.35 % with VOC of 0.71â V, JSC of 27.06â mA/cm2 , FF of 0.63. The results, which motivated the development of a small DSSC module, gave 6.21 % and is used to drive a tiny electronic motor in indoor and outdoor lighting conditions. Small-area DSSCs connected in series have found that a VOC of 4.52â V is sufficient to power up Internet of Things (IoT) devices.
RESUMEN
High-performance bilayer counter electrodes (BCEs) for dye-sensitized solar cell (DSSC) applications are gaining considerable attention. In this study, MoS2 /single-walled carbon nanohorn (SWCNHs) BCEs were fabricated by ultrasonic-spray-assisted electrochemical deposition. The BCEs exhibited superior electrocatalytic activity, confirmed through CV, Tafel plots, and electrochemical impedance spectroscopic studies. The fabricated MoS2 /SWCNH-based DSSCs exhibited an impressive photovoltaic power conversion efficiency of 9.48 %, which is higher than the performance of cells with Pt-containing CEs (8.64 %). The simple and reliable growth strategy for bilayer film CEs provides a new route for the preparation of cost-effective and high-performance catalytic BCEs for renewable energy applications involving Pt-free DSSCs.
