1.
Angew Chem Int Ed Engl
; 45(23): 3811-3, 2006 Jun 02.
Artículo
en Inglés
| MEDLINE
| ID: mdl-16671141
Asunto(s)
Cetonas/química , Acetofenonas/química , Metanol/química , Modelos Químicos , Estructura Molecular
2.
Org Lett
; 6(23): 4375-7, 2004 Nov 11.
Artículo
en Inglés
| MEDLINE
| ID: mdl-15524487
RESUMEN
Two new, crystalline solid, storable, and highly enantioselective reagents for aldehyde crotylation have been developed. Both (cis and trans) crotylsilane reagents are easily prepared in bulk, require trivial reaction conditions, and provide the homoallylic alcohol products with near diastereo- and enantiospecificity in many cases.