1.
Org Lett
; 16(23): 6152-5, 2014 Dec 05.
Artículo
en Inglés
| MEDLINE
| ID: mdl-25398049
RESUMEN
An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom- and step-economic efficiency.
Asunto(s)
Compuestos Organofosforados/síntesis química , Catálisis , Técnicas Químicas Combinatorias , Estructura Molecular , Compuestos Organofosforados/química , Oxidación-Reducción , Estereoisomerismo
2.
Org Biomol Chem
; 12(23): 3802-7, 2014 Jun 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-24788750
RESUMEN
An efficient metal-free aerobic oxidative C-N bond cleavage of tertiary amines has been developed to construct N-heterocycles using molecular oxygen as the sole oxidant with high atom efficiency, in which all of the three alkyl groups in tertiary amines can be utilized and transformed into N-heterocycles.