Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 25
Filtrar
Más filtros










Intervalo de año de publicación
1.
ACS Omega ; 8(50): 47821-47834, 2023 Dec 19.
Artículo en Inglés | MEDLINE | ID: mdl-38144128

RESUMEN

The discharge of synthetic dyes from different industrial sources has become a global issue of concern. Enormous amounts are released into wastewater each year, causing concerns due to the high toxic consequences. Photocatalytic semiconductors appear as a green and sustainable form of remediation. Among them, graphitic carbon nitride (g-C3N4) has been widely studied due to its low cost and ease of fabrication. In this work, the synthesis, characterization, and photocatalytic study over methylene blue of undoped, B/S-doped, and exfoliated heterojunctions of g-C3N4 are presented. The evaluation of the photocatalytic performance showed that exfoliated undoped/S-doped heterojunctions with 25, 50, and 75 mass % of S-doped (g-C3N4) present enhanced activity with an apparent reaction rate constant (kapp) of 1.92 × 10-2 min-1 for the 75% sample. These results are supported by photoluminescence (PL) experiments showing that this heterojunction presents the less probable electron-hole recombination. UV-vis diffuse reflectance and valence band-X-ray photoelectron spectroscopy (VB-XPS) allowed the calculation of the band-gap and the valence band positions, suggesting a band structure diagram describing a type I heterojunction. The photocatalytic activities calculated demonstrate that this property is related to the surface area and porosity of the samples, the semiconductor nature of the g-C3N4 structure, and, in this case, the heterojunction that modifies the band structure. These results are of great importance considering that scarce reports are found concerning exfoliated B/S-doped heterojunctions.

2.
Enferm. nefrol ; 26(4): 316-324, oct. - dic. 2023. ilus, tab
Artículo en Español | IBECS | ID: ibc-229055

RESUMEN

Introducción:La enfermedad infecciosa producida por el virus SARS-CoV2 provocó un grave problema de salud pública en la población en general; y para las personas con insuficiencia re-nal, se observó un mayor riesgo de desarrollar complicaciones severas y muerte.Objetivo: Identificar la evidencia científica relacionada con la mortalidad por SARS-CoV2 -19 de las personas con insuficien-cia renal crónica.Metodología: Se llevó a cabo una revisión integrativa, mediante búsqueda en las bases de datos Scopus, EBSCO, Pubmed (con-tiene además la base Medline), Science Direct, Scielo, Lilacs, y Embase.Resultados: Se obtuvieron y revisaron un total de 14 artículos. Estos, estaban escritos en idioma inglés y español, publicados en Europa (6), en Asia (5), en Norteamérica (1) y Latinoamérica (2). Las variables sociodemógraficas que mostraron influencia en la mortalidad fueron género masculino, edad avanzada, fra-gilidad de los pacientes en diálisis, presencia de comorbilidades como el síndrome cardiorrenal, cardiopatía isquémica, sobrepe-so, obesidad, multimorbilidad, diabetes, hipertensión arterial, antecedentes de ictus y demencia. Conclusiones: Se observó que la mortalidad por SARS-CoV2 grave fue mayor en pacientes con insuficiencia renal crónica que en la población en general, asociado con cambios en los marcadores bioquímicos como elevación de la troponina, pro-teína C reactiva, enzimas hepáticas, marcadores inflamatorios, disminución de linfocitos, albúmina sérica, así mismo, las com-plicaciones desarrolladas y que se asociaban con la mortalidad fueron síndrome de dificultad respiratoria aguda, coagulación intravascular diseminada, shock séptico, hipotensión y neumo-nía (AU)


ortality due to SARS-CoV-2 in individuals with chronic kidney disease: an integrative reviewIntroduction: The infectious disease caused by the SARS-CoV-2 virus has posed a serious public health problem in the general population. For individuals with chronic kidney disease, a higher risk of developing severe complications and mortality has been observedObjective: To identify scientific evidence related to mor-tality from SARS-CoV-2 in individuals with chronic kidney disease.Methodology: An integrative review was conducted by searching the Scopus, EBSCO, PubMed (which also includes the Medline database), Science Direct, Scielo, Lilacs, and Embase databases. Results: A total of 14 articles were obtained and reviewed. These articles were written in English and Spanish and were published in Europe (6), Asia (5), North America (1), and Latin America (2). Sociodemographic variables that showed influence on mortality included male gender, advanced age, frailty of dialysis patients, presence of comorbidities such as cardio-renal syndrome, ischemic heart disease, overweight, obesity, multimorbidity, diabetes, hypertension, a history of stroke, and dementia.Conclusions: Severe mortality from SARS-CoV-2 was observed to be higher in patients with chronic kidney disease than in the general population. This was associated with changes in biochemical markers such as elevated troponin, C-reactive protein, liver enzymes, inflammatory markers, decreased lymphocytes, and serum albumin. Additionally, complications associated with mortality included acute respiratory distress syndrome, disseminated intravascular coagulation, septic shock, hypotension, and pneumonia (AU)


Asunto(s)
Insuficiencia Renal Crónica , Diálisis , Mortalidad
3.
Sci Rep ; 13(1): 6752, 2023 Apr 25.
Artículo en Inglés | MEDLINE | ID: mdl-37185779

RESUMEN

We report on the synthesis and characterization of V2O5 nanoparticles grown using a sol-gel method at different calcination temperatures. We observed a surprising reduction in the optical band gap from 2.20 to 1.18 eV with increasing calcination temperature from 400 to 500 °C. Raman and X-Ray diffraction measurements indicated slight changes in the lattice parameters induced by the growth process. However, density functional theory calculations of the Rietveld-refined and pristine structures revealed that the observed optical gap reduction could not be explained by structural changes alone. By introducing oxygen vacancies to the refined structures, we could reproduce the reduction of the band gap. Our calculations also showed that the inclusion of oxygen vacancies at the vanadyl position creates a spin-polarized interband state that reduces the electronic band gap and promotes a magnetic response due to unpaired electrons. This prediction was confirmed by our magnetometry measurements, which exhibited a ferromagnetic-like behavior. Our findings suggest that oxygen vacancies play a crucial role in band gap reduction and the promotion of a ferromagnetic-like response in an otherwise paramagnetic material. This provides a promising route to engineer novel devices.

4.
Cult. cuid ; 27(66): 17-34, Juli 25, 2023. tab, graf
Artículo en Español | IBECS | ID: ibc-224019

RESUMEN

Communicative health plays an important role in the wellbeing of a person with or without a disability. The aim of the article is to describe the communicative interaction that occurs between a group of caregivers and the people which they take care to identify their perceptions focuson their communicative health. This is descriptive research. 12 informal caregivers participated andthey completed a survey based on the communication strategies used in interactions with the peoplewho they take care. The results show that the interaction between the caregiver and the person whothey take care. This is characterized by the presence of different communicative intentions, the useof verbal and non-verbal code, the passive role of the person with disabilities, and the active role ofthe caregiver. In the discussion the authors introduce the criteria to take into account when someoneis talking about communicative health in people with disabilities. The study shows the signs thataccount for communicative health evidenced in the caregiver-person dyad who is cared for.(AU)


La salud comunicativa es una parte importante en el bienestar de una persona con o sindiscapacidad. El objetivo del artículo es describir la interacción comunicativa que se da entre ungrupo de cuidadores y las personas a quienes cuidan para identificar sus percepciones frente a susalud comunicativa. En la investigación de tipo descriptivo participaron 12 cuidadores informales quienes diligenciaron una encuesta sobre las estrategias comunicativas empleadas en las interacciones con las personas a quienes cuidan. Los resultados mostraron que la interacción entre el cuidadory la persona a quien se cuida se caracteriza por la presencia de diferentes intenciones comunicativas, por el uso del código verbal oral y no verbal, por el rol pasivo de la persona con discapacidad,y por el rol activo del cuidador. Los autores reflexionan en torno a los criterios a tener en cuenta alhablar de la salud comunicativa en personas con discapacidad. El estudio concluye con los signosque dan cuenta de la salud comunicativa evidenciados en la diada cuidador-persona a la que secuida.(AU)


A saúde comunicativa é uma parte importante do bemestar de uma pessoa com ou semdeficiência. O objetivo do artigo é descrever a interação comunicativa que ocorre entre um grupo decuidadores e as pessoas de quem cuidam, a fim de identificar suas percepções sobre sua saúde comunicativa. Na pesquisa descritiva, participaram 12 cuidadores informais que responderam a umquestionário sobre as estratégias de comunicação utilizadas nas interações com as pessoas de quemcuidam. Os resultados mostram que a interação entre o cuidador e o ser cuidado é caracterizadapela presença de diferentes intenções comunicativas, pelo uso do código verbal oral e não verbal,pelo papel passivo da pessoa com deficiência, e pelo papel ativo de cuidador. Os autores refletemsobre os critérios a serem levados em consideração quando se fala em saúde comunicativa em pessoas com deficiência. O estudo se conclui com os indícios que explicam a saúde comunicativa evidenciados na díade cuidador-pessoa cuidada.(AU)


Asunto(s)
Humanos , Masculino , Femenino , Adulto Joven , Adulto , Persona de Mediana Edad , Cuidadores , Atención de Enfermería , Personas con Discapacidad , Comunicación , Relaciones Interpersonales , Relaciones Enfermero-Paciente , Epidemiología Descriptiva , Encuestas y Cuestionarios
5.
Rev. chil. fonoaudiol. (En línea) ; 21(1): 1-10, 2022. tab, graf
Artículo en Español | LILACS | ID: biblio-1437268

RESUMEN

El objetivo de este artículo es analizar el panorama investigativo disciplinar desde la producción académica nacional, para identificar poblaciones, áreas, enfoques de investigación, de esta manera reconocer necesidades y retos para la investigación formativa de la fonoaudiología en Colombia. Se analizó información proveniente de proyectos de investigación de pregrado y posgrado de 13 programas de formación en Fonoaudiología del país, entre 2010 y 2019, reportados por las instituciones de educación superior. Se recolectó información de informes y documentos de investigación (N=638). En primer lugar, se observa un incremento en la producción investigativa entre 2010 (4,9%) y 2019 (18,3%). El 85% de la investigación se identificó en pregrado y el 15% en postgrado. El enfoque predominante fue cualitativo (55,3%), el que, junto con el alcance descriptivo (77,8%) que representan la mayoría de productos de investigación. El escenario relacionado con el ámbito de salud clínico asistencial lidera la investigación (52,9%). Las áreas predominantes en este escenario investigativo son Lenguaje (29,1%) y Audición (27,4%) en poblaciones de adultos (56,7%) e infantil (28,52%). Se concluye que la producción investigativa desde la academia, específicamente desde los programas de formación de fonoaudiólogos en Colombia, evidencian la necesidad de fomentar la investigación de tipo experimental y analítica, con poblaciones de neonatos y lactantes, en áreas relacionadas con la función oralfaríngea y en escenarios inéditos. Además, es necesario incluir el uso de tecnologías y nuevos enfoques de intervención para aportar al abordaje basado en la evidencia. Futuras investigaciones deben permitir comparar la investigación antes y después de la pandemia, dada la virtualización y la inclusión de la fonoaudiología en escenarios como las unidades de cuidado crítico y cuidado paliativo.


The objective of this article is to analyze the disciplinary research landscape from the national academic production, to identify populations, areas, research approaches, in this way identify needs and challenges for formative research of speech therapy in Colombia. Information from undergraduate and graduate research projects of 13 training programs in Speech Therapy in the country, between 2010 and 2019, reported by higher education institutions, was analyzed. Information was collected from reports and research papers (N=638). First, there was an increase in research production between 2010 (4.9%) and 2019 (18.3%). 85% of the researchwas identified in undergraduate and 15% in postgraduate. The predominant approach was qualitative (55.3%), which, together with the descriptive scope (77.8%) that represent the majority of research products. The scenario related to the field of clinical health care leads the research (52.9%). The predominant areas in this research scenario are Language (29.1%) and Hearing (27.4%)in adult (56.7%) and child (28.52%) populations. It is concluded that the research production from the academy, specifically from the trainingprograms of speech therapists in Colombia, evidences the need to promote experimental and analytical research, with populations of neonates and infants, in areas related to oral function and in unprecedented scenarios. Besides, it is necessary to include the use oftechnologies and new intervention approaches to contribute to the evidence-based approach. Future research should allow comparison of research before and after the pandemic, given the virtualization and the inclusion of speech therapy in settings such as critical careand palliative care units.


Asunto(s)
Proyectos de Investigación/tendencias , Proyectos de Investigación/estadística & datos numéricos , Fonoaudiología/tendencias , Colombia
6.
Sci Rep ; 10(1): 3376, 2020 02 25.
Artículo en Inglés | MEDLINE | ID: mdl-32099058

RESUMEN

Dye-sensitized solar cells (DSSCs) have been highlighted as the promising alternative to generate clean energy based on low pay-back time materials. These devices have been designed to mimic solar energy conversion processes from photosynthetic organisms (the most efficient energy transduction phenomenon observed in nature) with the aid of low-cost materials. Recently, light-harvesting complexes (LHC) have been proposed as potential dyes in DSSCs based on their higher light-absorption efficiencies as compared to synthetic dyes. In this work, photo-electrochemical hybrid devices were rationally designed by adding for the first time Leu and Lys tags to heterologously expressed light-harvesting proteins from Chlamydomonas reinhardtii, thus allowing their proper orientation and immobilization on graphene electrodes. The light-harvesting complex 4 from C. reinhardtii (LHC4) was initially expressed in Escherichia coli, purified via affinity chromatography and subsequently immobilized on plasma-treated thin-film graphene electrodes. A photocurrent density of 40.30 ± 9.26 µA/cm2 was measured on devices using liquid electrolytes supplemented with a phosphonated viologen to facilitate charge transfer. Our results suggest that a new family of graphene-based thin-film photovoltaic devices can be manufactured from rationally tagged LHC proteins and opens the possibility to further explore fundamental processes of energy transfer for biological components interfaced with synthetic materials.


Asunto(s)
Proteínas Algáceas/metabolismo , Chlamydomonas reinhardtii/metabolismo , Técnicas Electroquímicas/métodos , Grafito/química , Complejos de Proteína Captadores de Luz/metabolismo , Proteínas Algáceas/genética , Colorantes/química , Técnicas Electroquímicas/instrumentación , Electrodos , Proteínas Inmovilizadas/química , Proteínas Inmovilizadas/metabolismo , Complejos de Proteína Captadores de Luz/genética , Proteínas Recombinantes/biosíntesis , Proteínas Recombinantes/química , Proteínas Recombinantes/aislamiento & purificación , Energía Solar
7.
Rev. logop. foniatr. audiol. (Ed. impr.) ; 39(4): 192-200, oct.-dic. 2019.
Artículo en Español | IBECS | ID: ibc-191302

RESUMEN

En Fonoaudiología el uso de las TIC ha generado un campo relacionado con Telerrehabilitación y Telepráctica y ha requerido el desarrollo de la competencia digital. El presente artículo tiene como objetivo reflexionar en torno a los conocimientos y a las habilidades asociadas al uso de las TIC en Fonoaudiología. Así se presentan recursos tecnológicos para el abordaje de diversos problemas (lenguaje, habla, voz, comunicación, deglución). También se hace una reflexión sobre las implicaciones del uso de las TIC en la formación de los fonoaudiólogos, y las estrategias que se pueden usar para el desarrollo de las competencias requeridas


In Phonoaudiology, the use of ICT has created a field known as Telerehabilitation and Telepractice and has required the development of the digital literacy. The following article aims to reflect on the knowledge and the skills associated with the use of ICT in Phonoaudiology. The paper introduces technological resources used to treat different problems (language, speech, voice, communication, swallowing). Besides there is a reflection on the implications of technological resources uses in future professionals' training programs, and the strategies that can be used for the development of the required competencies


Asunto(s)
Humanos , Fonoaudiología/tendencias , Consulta Remota/métodos , Telerrehabilitación/métodos , Telediagnóstico , Teleterapia , Competencia Profesional , Tecnología de la Información/tendencias
8.
Rev. colomb. rehabil ; 15(1): 12-21, 2016. ilus, graf
Artículo en Español | LILACS, COLNAL | ID: biblio-912756

RESUMEN

Un número de investigaciones han estudiado la relación entre la lecto-escritura y el desempeño de los estudiantes. Este artículo describe las características del proceso lecto-escrito y analiza la correlación entre este proceso y el desempeño escolar. En este estudio la muestra fue de 327 estudiantes de los grados quinto y sexto quienes fueron evaluados a través de diferentes tareas. En este estudio descriptivo se aplicaron pruebas de comprensión de lectura y de producción de textos. El análisis de la información mostró un desempeño más alto en los estudiantes de grado sexto en comprensión de lectura y en las conciencias fonológica, morfológica y sintáctica. El análisis identificó una correlación entre el desempeño en matemáticas y las habilidades psicolin-güísticas, además una correlación entre el desempeño en ciencias sociales y habilidades metalin-güísticas, ciencias naturales y habilidades metalingüísticas y artes y habilidades metacognitivas. Los hallazgos brindan luces sobre la importancia de la lecto-escritura en el desempeño escolar y como las diferentes habilidades facilitan el desarrollo de la lecto-escritura. En este sentido, es importante plantear nuevas investigaciones centradas en la promoción de habilidades metalin-güísticas, metacognitivas y psicolingüísticas para el desempeño escolar de los estudiantes.


A number of researches have studied the relationship between reading and writing skills and the students school performance. This paper describes the characteristics of reading and writing skills and analyzes the correlation between this process and the academic performance. For this study a total of 327 students from fifth and sixth grade were evaluated through different tasks. In this descriptive study the sample was assessed through reading comprehension and writing production tests. Data analyses showed higher performances in sixth grade students in reading comprehension, and in phonological, morphological and syntactic awareness. The analysis iden-tified correlation between Mathematics performance and Psycholinguistic skills; as well as be-tween Social Science performance and metalinguistic skills, Natural Science performance and metalinguistic skills and Arts performance and metacognitive skills. The findings highlight the importance of reading and writing skills for student's academic performance and how the diffe-rent skills facilitate literacy's development. In this sense, it is important to plan new researches focused on promoting metalinguistic, metacognitive and psycholinguistic skills in the student's academic performance


Asunto(s)
Humanos , Psicolingüística , Preescolar , Lectura , Escritura
9.
Nat Chem ; 6(2): 126-32, 2014 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-24451588

RESUMEN

The properties of graphene nanoribbons (GNRs) make them good candidates for next-generation electronic materials. Whereas 'top-down' methods, such as the lithographical patterning of graphene and the unzipping of carbon nanotubes, give mixtures of different GNRs, structurally well-defined GNRs can be made using a 'bottom-up' organic synthesis approach through solution-mediated or surface-assisted cyclodehydrogenation reactions. Specifically, non-planar polyphenylene precursors were first 'built up' from small molecules, and then 'graphitized' and 'planarized' to yield GNRs. However, fabrication of processable and longitudinally well-extended GNRs has remained a major challenge. Here we report a bottom-up solution synthesis of long (>200 nm) liquid-phase-processable GNRs with a well-defined structure and a large optical bandgap of 1.88 eV. Self-assembled monolayers of GNRs can be observed by scanning probe microscopy, and non-contact time-resolved terahertz conductivity measurements reveal excellent charge-carrier mobility within individual GNRs. Such structurally well-defined GNRs may prove useful for fundamental studies of graphene nanostructures, as well as the development of GNR-based nanoelectronics.


Asunto(s)
Grafito/química , Nanotubos de Carbono/química , Reacción de Cicloadición , Electrones , Microscopía de Fuerza Atómica , Nanotubos de Carbono/ultraestructura , Polimerizacion , Polímeros/química , Teoría Cuántica
10.
ACS Nano ; 7(4): 3598-606, 2013 Apr 23.
Artículo en Inglés | MEDLINE | ID: mdl-23531157

RESUMEN

Solution-processable thin layer graphene is an intriguing nanomaterial with tremendous potential for electronic applications. In this work, we demonstrate that electrochemical exfoliation of graphite furnishes graphene sheets of high quality. The electrochemically exfoliated graphene (EG) contains a high yield (>80%) of one- to three-layer graphene flakes with high C/O ratio of 12.3 and low sheet resistance (4.8 kΩ/□ for a single EG sheet). Due to the solution processability of EG, a vacuum filtration method in association with dry transfer is introduced to produce large-area and highly conductive graphene films on various substrates. Moreover, we demonstrate that the patterned EG can serve as high-performance source/drain electrodes for organic field-effect transistors.


Asunto(s)
Electrodos , Galvanoplastia/métodos , Grafito/química , Membranas Artificiales , Nanoestructuras/química , Nanoestructuras/ultraestructura , Transistores Electrónicos , Conductividad Eléctrica , Diseño de Equipo , Análisis de Falla de Equipo , Tamaño de la Partícula , Soluciones/química
11.
J Am Chem Soc ; 134(44): 18169-72, 2012 Nov 07.
Artículo en Inglés | MEDLINE | ID: mdl-23082776

RESUMEN

Oxidative cyclodehydrogenation of laterally extended polyphenylene precursor allowed bottom-up synthesis of structurally defined graphene nanoribbons (GNRs) with unprecedented width. The efficiency of the cyclodehydrogenation was validated by means of MALDI-TOF MS, FT-IR, Raman, and UV-vis absorption spectroscopies as well as investigation of a representative model system. The produced GNRs demonstrated broad absorption extended to near-infrared region with the optical band gap of as low as 1.12 eV.

12.
ACS Nano ; 6(11): 9541-50, 2012 Nov 27.
Artículo en Inglés | MEDLINE | ID: mdl-23050839

RESUMEN

The high cost of platinum-based electrocatalysts for the oxygen reduction reaction (ORR) has hindered the practical application of fuel cells. Thanks to its unique chemical and structural properties, nitrogen-doped graphene (NG) is among the most promising metal-free catalysts for replacing platinum. In this work, we have developed a cost-effective synthesis of NG by using cyanamide as a nitrogen source and graphene oxide as a precursor, which led to high and controllable nitrogen contents (4.0% to 12.0%) after pyrolysis. NG thermally treated at 900 °C shows a stable methanol crossover effect, high current density (6.67 mA cm(-2)), and durability (∼87% after 10,000 cycles) when catalyzing ORR in alkaline solution. Further, iron (Fe) nanoparticles could be incorporated into NG with the aid of Fe(III) chloride in the synthetic process. This allows one to examine the influence of non-noble metals on the electrocatalytic performance. Remarkably, we found that NG supported with 5 wt % Fe nanoparticles displayed an excellent methanol crossover effect and high current density (8.20 mA cm(-2)) in an alkaline solution. Moreover, Fe-incorporated NG showed almost four-electron transfer processes and superior stability in both alkaline (∼94%) and acidic (∼85%) solutions, which outperformed the platinum and NG-based catalysts.


Asunto(s)
Electroquímica/métodos , Grafito/química , Hierro/química , Nanoestructuras/química , Nitrógeno/química , Oxígeno/química , Catálisis , Ensayo de Materiales , Oxidación-Reducción
13.
Angew Chem Int Ed Engl ; 51(31): 7640-54, 2012 Jul 27.
Artículo en Inglés | MEDLINE | ID: mdl-22777811

RESUMEN

Graphene, an individual two-dimensional, atomically thick sheet of graphite composed of a hexagonal network of sp(2) carbon atoms, has been intensively investigated since its first isolation in 2004, which was based on repeated peeling of highly oriented pyrolyzed graphite (HOPG). The extraordinary electronic, thermal, and mechanical properties of graphene make it a promising candidate for practical applications in electronics, sensing, catalysis, energy storage, conversion, etc. Both the theoretical and experimental studies proved that the properties of graphene are mainly dependent on their geometric structures. Precise control over graphene synthesis is therefore crucial for probing their fundamental physical properties and introduction in promising applications. In this Minireview, we highlight the recent progress that has led to the successful chemical synthesis of graphene with a range of different sizes and chemical compositions based on both top-down and bottom-up strategies.

14.
J Am Chem Soc ; 134(29): 12168-79, 2012 Jul 25.
Artículo en Inglés | MEDLINE | ID: mdl-22716095

RESUMEN

We have studied the exfoliation and dispersion of hexabenzocoronene (HBC) in 28 different solvents. We see a wide range of dispersed concentrations and aggregation states, all of which can be related to the solvent properties. To a first approximation, the dispersed concentration is maximized for solvents with Hildebrand solubility parameter close to 21 MPa(1/2), similar to graphitic materials such as nanotubes and graphene. We have also studied the concentration dependence of the absorbance and photoluminescence of HBC for both a good solvent, cyclohexyl pyrrolidone (CHP), and a poor solvent, tetrahydrofuran (THF). In both cases, we observe features that can be associated with either individual molecules or aggregates, allowing us to establish metrics both for aggregate and individual molecule content. While the aggregate content always increases with concentration, good solvents disperse individual molecules at relatively high concentrations while poor solvents display aggregation even at low concentrations. Using these metrics, we determine that large populations of individual molecules are present at low concentrations in certain solvents with Hildebrand solubility parameters close to 21 MPa(1/2). However, the aggregation state of HBC is considerably more sensitive to solvent Hildebrand parameter for halogenated solvents than for amide solvents. We find a combination of high overall concentrations and large populations of individual molecules in four solvents: cyclohexyl pyrrolidone, 1-chloronaphthalene, 1-bromonaphthalene, and 1,2,4-trichlorobenzene. Scanning tunnelling microscopy (STM) measurements show the formation of self-assembled monolayers at the interface between a HBC-solvent dispersion and a highly oriented pyrolytic graphite (HOPG) substrate. Similar structures were observed on ultrathin supports by aberration-corrected transmission electron microscopy (TEM). Also observed were graphitic objects of size ~1 nm consistent with monomers or aggregated stacks of very few monomers. We believe this is strong evidence of the presence of individual molecules in dispersions prepared with appropriate solvents.

15.
Sci Rep ; 2: 427, 2012.
Artículo en Inglés | MEDLINE | ID: mdl-22645643

RESUMEN

A well-designed nanostructure of transition metal oxides has been regarded as a key to solve their problems of large volume changes during lithium insertion-desertion processes which are associated with pulverization of the electrodes and rapid capacity decay. Here we report an effective approach for the fabrication of porous iron oxide ribbons by controlling the nucleation and growth of iron precursor onto the graphene surface and followed by an annealing treatment. The resultant iron oxide ribbons possess large aspect ratio, porous structure, thin feature and enhanced open-edges. These characteristics are favorable for the fast diffusion of lithium ions and electrons, and meanwhile can effectively accommodate the volume change of iron oxides during the cycling processes. As a consequence, the graphene-induced porous iron oxide ribbons exhibit a high reversible capacity and excellent cycle stability for lithium storage.


Asunto(s)
Compuestos Férricos/química , Grafito/química , Litio/química , Nanoestructuras/química , Espectroscopía Dieléctrica , Conductividad Eléctrica , Suministros de Energía Eléctrica , Electrodos , Electrólitos/química , Microscopía Electrónica de Rastreo , Microscopía Electrónica de Transmisión , Nanoestructuras/ultraestructura , Nanotecnología/métodos , Porosidad , Propiedades de Superficie , Temperatura
16.
ACS Nano ; 6(6): 5539-48, 2012 Jun 26.
Artículo en Inglés | MEDLINE | ID: mdl-22631451

RESUMEN

Graphene nanoribbons (GNRs) are strips of graphene cut along a specific direction that feature peculiar electronic and optical properties owing to lateral confinement effects. We show here by means of (time-dependent) density functional theory calculations that GNRs with properly designed edge structures fulfill the requirements in terms of electronic level alignment with common acceptors (namely, C(60)), solar light harvesting, and singlet-triplet exchange energy to be used as low band gap semiconductors for organic photovoltaics.


Asunto(s)
Suministros de Energía Eléctrica , Electrodos , Grafito/química , Modelos Químicos , Nanopartículas/química , Nanopartículas/ultraestructura , Energía Solar , Simulación por Computador , Diseño Asistido por Computadora , Transporte de Electrón , Diseño de Equipo , Análisis de Falla de Equipo , Teoría Cuántica
18.
Rev. colomb. rehabil ; 10(1): 94-105, 2011. ilus, graf
Artículo en Español | LILACS, COLNAL | ID: biblio-909073

RESUMEN

El objetivo de este artículo fue identificar las tendencias investigativas mundiales de los estu-dios de la Lengua de Señas entre el año 2000 y el 2011 (primer bimestre) a partir de la revisión de 20 revistas indexadas que se encuentran en las bases de datos electrónicas Scielo, Pubmed, y PROQUEST. Los artículos están escritos en diferentes lenguas como Español, Inglés y Por-tugués. Para este propósito cinco variables fueron registradas: a) el nombre de las revistas; b) la producción investigativa por año, c) el porcentaje de autores por artículo, d) los autores más destacados, y e) los temas trabajados. Los resultados muestran 196 artículos de investiga-ción en términos de frecuencia y porcentajes. También hay siete temas: el 25,7% de estos artí-culos se refiere a las características de la lengua de señas; el 24,5% estudia la lengua de señas y la educación; el 22,7% se centra en las variaciones sociolingüísticas de la Lengua de Señas; el 7% se refiere a la comunicación bimodal; el 6% se centra en el proceso lecto-escrito; el 4% estudia el procesamiento psicolingüístico, y el 3% revisa las bases neurológicas de la lengua de señas. Teniendo en cuenta lo anterior, se determinan los siete temas expuestos como las tendencias investigativas en cuanto a la Lengua de Señas. Al finalizar hay algunas propuestas de investigación que pueden ser desarrolladas con el fin de apoyar la comprensión de esta lengua.


The objective of this article was to identify the research world tendencies in Sign Langua-ge studies between 2000 and 2011 (first two months) from the review of 20 indexed journals which are on electronic databases Scielo, Pubmed, and PROQUEST. The articles are written in different languages such as Spanish, English and Portuguese. For this purpose five varia-bles were registered: a) journals' name; b) research production by year; c) authors' percentage by article; d) authors and higher productivity; and e) worked themes. The results show 196 research articles that were analyzed in terms of frequency and percentage. Also there are seven themes: 25,7% of these articles refers to the sign language characteristics; 24,5% studies the sign language and education; 22,7% is focused in sign language and its socio-cultural variables; 7% refers to bimodal communication; 6% is focused in reading-writing process; 4% studies the psycholinguistics processing; and 3% reviews the sign language ́s neurological bases. Given the above, the seven themes were identified as research tendency about Sing Language. At the end, there are some research purposes that can be developed in order to support the understanding of this language.


Asunto(s)
Humanos , Lenguaje , Procesamiento de Lenguaje Natural , Investigación , Fonoaudiología
20.
Langmuir ; 26(5): 3208-13, 2010 Mar 02.
Artículo en Inglés | MEDLINE | ID: mdl-19883090

RESUMEN

We have measured the dispersibility of graphene in 40 solvents, with 28 of them previously unreported. We have shown that good solvents for graphene are characterized by a Hildebrand solubility parameter of delta(T) approximately 23 MPa(1/2) and Hansen solubility parameters of delta(D) approximately 18 MPa(1/2), delta(P) approximately 9.3 MPa(1/2), and delta(H) approximately 7.7 MPa(1/2). The dispersibility is smaller for solvents with Hansen parameters further from these values. We have used transmission electron microscopy (TEM) analysis to show that the graphene is well exfoliated in all cases. Even in relatively poor solvents, >63% of observed flakes have <5 layers.

SELECCIÓN DE REFERENCIAS
DETALLE DE LA BÚSQUEDA
...