Functional impacts of polyaniline in composite matrix of photocatalysts: an instrumental overview.

The challenges associated with photocatalysts including their agglomeration, electron-hole recombination and limited optoelectronic reactivity to visible light during the photocatalysis of dye-laden effluent make it necessary to fabricate versatile polymeric composite photocatalysts, and in this case the incredibly reactive conducting polyaniline can be employed. The selection of polyaniline among the conducting polymers is based on its proficient functional impacts in composite blends and proficient synergism with other nanomaterials, especially semiconductor catalysts, resulting in a high photocatalytic performance for the degradation of dyes. However, the impacts of PANI in the composite matrix, which result in the desired photocatalytic activities, can only be assessed using multiple characterization techniques, involving both microscopic and spectroscopic assessment. The characterization results play a significant role in the detection of possible points of agglomeration, surface tunability and improved reactivity during the fabrication of composites, which are necessary to improve their performance in the photocatalysis of dyes. Accordingly, studies revealed the functional impacts of polyaniline in composites including morphological transformation, improved surface functionality, reduction in agglomeration and lowered bandgap potential employing different characterization techniques. In this review, we present the most proficient fabrication techniques based on the in situ approach to achieve improved functional and reactive features and efficiencies of 93, 95, 96, 98.6 and 99% for composites in dye photocatalysis.

Investigation of functional performance of treatment systems for textile wastewater in selected textile industries in Tanzania.

Textile industrialization is an integral part of the economic growth in Tanzania. However, the corresponding wastewater from textile treatment processes consists of dyes and auxiliaries associated with acute toxicological impacts. This necessitates an investigation of the functional performance of the industrial treatment systems used before effluent discharge. The study primarily accesses the catalog of industrial dyes and the functionality of the treatment system at Arusha, Morogoro and Dar es Salaam vis-à-vis the effluent physicochemical properties. The analytical study reveals disperse (42%), vat (34%) and reactive (26%) as the most used industrial dyes. The physicochemical properties of the quantified wastewater reveal a significant amount of and phosphorus which was consequent to the high turbidity, biochemical oxygen demand (BOD) and chemical oxygen demand (COD) apart from the color at the different sampling points. Although the treatability of the wastewater was 90% efficient using an activated carbon system (237.33 ± 0.67 mg/L). Similarly, the use of aerated constructed wetlands shows efficiency in the remediation of the recalcitrant having a value of 12.13 ± 0.89b mg/L (90%) and 13.22 ± 0.15a mg/L (94%). Thereafter, needful recommendations were suggested based on the physicochemical properties of the textile wastewater and to improve the functionality of the treatment systems in the respective industries.

Two-stage banana leaves wastes utilization towards mushroom growth and biogas production.

Banana leaves wastes (BL) were subjected to fungal treatment using Pleurotus ostreatus to produce edible mushrooms and biogas in the anaerobic digestion process. Effects of fungal treatment on mushrooms production, lignin degradation, trace elements compositions and biogas yield during the anaerobic digestion process were evaluated. Treatment with P.ostreatus for 36 d resulted in the production of 181 ± 19 g of edible mushrooms per 2 kg of BL with biological efficiency of 37 ± 4%. Lignin concentration in fungal treated BL decreased by 10% indicating an improvement on its digestibility. Important trace elements (Fe, Mn, Mo, Co and Ni) necessary for the improvement of the anaerobic digestion process were also significantly reduced (P < 0.05) during the fungal treatment process. The biogas yield for the fungal treated BL was 282 mL g-1 VS-1 of which this study suggests that could be improved through trace element supplementation during the anaerobic digestion process.

Alternative tanning technologies and their suitability in curbing environmental pollution from the leather industry: A comprehensive review.

Chrome tanning remains the most favourite technology in the leather industry worldwide due to its ability to produce leather with attributes desirable for high-quality leather such as excellent hydrothermal stability, better dyeing characteristics and softness. Nevertheless, the technology has been censured globally for its severe environmental detriments and adverse effects on human health and other organisms. Developing alternative eco-friendly tanning technologies capable of producing leather of high quality has remained a challenging scientific inquiry. This review article provides an assessment of various eco-friendly tanning attempts geared towards improving or replacing the chrome technology without compromising the quality of the produced leather. The reviewed publications have ascertained that, these attempts have been centred on recycling of spent liquors; chromium exhaustion enhancement and total replacement of chromium salts. The research gaps and levels of key environmental pollutants from the reviewed technologies are presented, and the qualities of the leather produced from these technologies are highlighted. Of all the examined alternative technologies, total replacement of chromium salts sounds ideal to elude adverse effects associated with chrome tanning. Combination tanning, which implies blending two tanning agents that individually cannot impart desired properties to the leather, is anticipated to be an alternative technology to chrome tanning. Apart from being an eco-friendly technology, combination tanning produces leather with similar features to those produced by chrome tanning. In this regard, blending vegetable tannins with aluminium sulphate provides a promising chrome-free tanning technology. However, further studies to optimize combination tanning technologies to suit industrial applications are highly recommended.

Antimicrobial dependence of silver nanoparticles on surface plasmon resonance bands against Escherichia coli.

This study presents a simple and trouble-free method for determining the antimicrobial properties of silver nanoparticles (AgNPs) based on the surface plasmon resonance (SPR) bands. AgNPs were prepared by chemical reduction method using silver nitrates as a metallic precursor and formaldehyde (HCHO) as a reducing agent and capped by polyethylene glycol. Effects of several processing variables on the size and shape of AgNPs were monitored using an ultraviolet-visible spectrophotometer based on their SPR bands. The formed particles showing various particle shapes and full width at half maximum (FWHM) were tested against Escherichia coli by surface spreading using agar plates containing equal amounts of selected AgNPs samples. The NPs exhibited higher antimicrobial properties; however, monodispersed spherical NPs with narrow FWHM were more effective against E. coli growth. The NPs prepared are promising candidates in diverse applications such as antimicrobial agents in the food and biomedical industries.

Transformation of food packaging from passive to innovative via nanotechnology: concepts and critiques.

In recent decades, there is a global advancement in manufacturing industry due to increased applications of nanotechnology. Food industry also has been tremendously changing from passive packaging to innovative packaging, to cope with global trends, technological advancements, and consumer preferences. Active research is taking place in food industry and other scientific fields to develop innovative packages including smart, intelligent and active food packaging for more effective and efficient packaging materials with balanced environmental issues. However, in food industry the features behind smart packaging are narrowly defined to be distinguished from intelligent packaging as in other scientific fields, where smart materials are under critical investigations. This review presents some scientific concepts and features pertaining innovative food packaging. The review opens new research window in innovative food packaging to cover the existing disparities for further precise research and development of food packaging industry.

Human food safety and environmental hazards associated with the use of methyltestosterone and other steroids in production of all-male tilapia.

In recent years, all-male cultures of Nile tilapia (Oreochromis niloticus) have been the most preferred mode of production in aquaculture industry. All-male individuals achieve higher somatic growth rate and shut high energy losses associated with gonadal development and reproduction. The economic advantages of culturing all-male tilapia have led to the development of procedures for producing unisex cultures, using 17α-methyltestosterone (MT). Despite widespread use of the MT in tilapia farming, the implications of hormone treatment in relation to human health and the environment have raised a number of concerns in the scientific community. In this review, the hormonal application processes, economic and ecological significance of MT, food safety and residual MT, comparative uses of steroids in aquaculture, animal husbandry, and medicine have been briefly reviewed for regulatory guidelines, and finally, future research perspectives have been addressed. The review can be used as policy-making guidelines in aquaculture framework development as can be emphasized in African continent, among others. The most important conclusion to draw is that the quantity of MT used in conventional practice is large compared to the actual dose required for sex reversal, fish produced are safe for human consumptions, and the environmental hazards should be further emphasized.

Effects of spray-drying on w/o/w multiple emulsions prepared from a stearic acid matrix.

The goal of this study was to explore the effects of spray-drying on w/o/w double emulsions of methyltestosterone (MT) loaded in a stearic acid matrix. MT-loaded nanoparticles were formulated by a water-in-oil-in-water emulsion technique using 50, 75, and 100 mg of stearic acid, 2% and 3% w/v polyvinyl alcohol, 5% w/v lactose, and 0.2% w/v chitosan. The emulsions were immediately spray-dried based on an optimized model of inlet temperature and pump rate, and characterized for optimized responses with regard to particle size, polydispersity index, and zeta potential, for both emulsion and powder samples. Dynamic light scattering analysis shown that the nanoparticles increased in size with increasing concentrations of polyvinyl alcohol and stearic acid. Scanning electron microscopy indicated that the MT-loaded nanoparticles were spherical in shape, had a smooth surface, and were in an amorphous state, which was confirmed by differential scanning calorimetry. These MT-loaded nanoparticles are a promising candidate carrier for the delivery of MT; however, further studies are needed in order to establish the stability of the system and the cargo release profile under normal conditions of use.

Recovery of high surface area mesoporous silica from waste hexafluorosilicic acid (H2SiF6) of fertilizer industry.

In this article we report recovery of mesoporous silica from the waste material (hexafluorosilicic acid) of phosphate fertilizer industry. The process involves the reaction of hexafluorosilicic acid (50 ml, 24 wt% H(2)SiF(6)) and 100ml, 0.297 M Na(2)CO(3) to generate the alkaline aqueous slurry. Silica was separated from the slurry by filtration and the sodium fluoride was extracted from the aqueous solution by evaporation method. The obtained mesoporous silica was characterized by N(2) absorption/desorption (BET), thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscope (SEM), and EDS. The results confirm that the separation of silica and NaF was successful and the final products have high purity. The silica product was found to have an average pore diameter of 4.14 nm and a high surface area (up to 800 m(2)/g). The process reported in this study may significantly reduce the release of hazardous materials into the environment and it might confer economic benefits to the responsible industries.