RESUMEN
Soft actuators generate motion in response to external stimuli and are indispensable for soft robots, particularly future miniature robots with complex structure and motion. Similarly to conventional hard robots, electricity is suitable for the stimulation. However, previous electrochemical soft actuators require a tethered connection to a power supply, limiting their size, structure, and motion. Here, wireless electrochemical soft actuators composed of hydrogels and driven by bipolar electrochemistry are reported. Viologen, which dimerizes by one-electron reduction and dissociates by one-electron oxidation, is incorporated in the side chains of the gel networks and works as a reversible cross-link. Wireless and reversible electrochemical actuation of the hydrogels, i.e., muscle-like shrinking and swelling, is demonstrated at microscopic and even macroscopic scales.
RESUMEN
Molecular photoswitches have been widely used as molecular machines in various fields due to the small structures and simple motions generated in reversible isomerization. However, common photoswitches, as represented by azobenzene (AB), cannot combine both large motions and high thermal stability, which are critically important for some practical applications in addition to high photoisomerization yields. Here, we focus on a promising photoswitch, stiff stilbene (SS), and its derivative, sterically hindered SS (HSS). The detailed investigation of their performance with a comparison to AB demonstrated that HSS is an outstanding photoswitch offering larger motions than AB and SS, ca. 90% photoisomerization in both E-to-Z and Z-to-E directions, and significantly high thermal stability with a half-life of ca. 1000 years at room temperature. The superior performance of HSS promises its use in various applications, even where previous photoswitches have troubles and are unavailable.
