An Atmospheric Water-Harvester with Ultrahigh Uptake-Release Efficiency at Low Humidity.

Atmospheric water harvesting is a practical strategy that is achieved by removing materials from air moisture to relieve global water scarcity. Here we design a water-harvester (i.e., MOF-303/thiolated polymer composite (MTC)) by using a metal-organic framework (MOF-303) and thiolated chitosan (TC) skeleton. Intermolecular hydrogen bonding between TC and MOF-303 facilitates porous structures with enlarged air-polymer interfaces for long cycling life and high capacity at low relative humidity. Benefiting from synergetic effects on porosity and anchorage for accelerating the uptake-release of moisture, MTC exhibits a rapid water uptake capacity of 0.135 g/g in 60 min under 12.5 RH% and ultrafast water desorption kinetics of 0.003 g/g/min at 8.5 RH%, which is superior to the as-reported MOF-303 based adsorbents. At low heat (∼40 °C), the water desorption and collection rate, respectively, are 0.0195 and 0.0168 g/g/min within 210 min, showing ultrahigh harvesting efficiency. These results highlight the enormous potential as promising materials for solving the world's water scarcity crisis. This study offers an insight into the design of AWH materials, which can be extended into applications in some realms, e.g., freshwater development for industry in arid areas, water engineering-related devices and systems, etc.

Gradient-Janus Wires for Simultaneous Fogwater Harvesting and Electricity Generation.

A Gradient-Janus wire (GJW) with a diameter of 0.3 mm has been fabricated on a large scale through liquid confined modification, enabling the opposite conical wetting phenomenon along the same orientation of the GJW, characterized by an increasing superhydrophilic region and a decreasing hydrophobic region. This property allows the GJW to exhibit controllable water hovering, transport, and pinning during fog harvesting, i.e., at a large tilting angle α of 60° (mass increased with decreased α), the GJW can hover 0.6 mg of harvested fogwater in 30 s, can transport 3 mg of fogwater along the gradient in 30 s at α = 4° (with maximal mass reaching up to 4.3 mg at α = -10°), and finally, pin the water droplet at the end of the GJW. Such ability generates an effective torque that serves as the driving force for rotation. We designed a GJWs-wheel by radially arranging 60 GJWs together, resulting in an extremely lightweight structure weighing only 1.9 g. The cumulative torque generated during fog harvesting activates the rotation of the GJWs-wheel. When loaded with a coil within a magnetic field, electricity is generated as output power peaks at around 0.25 µW while maintaining a high water harvesting efficiency averaging approximately 38 ± 2.12 mg/min. This finding is significant as it provides valuable insights into designing materials capable of efficiently harnessing both energy and water resources.

Robust Photothermal Icephobic Surface with Mechanical Durability of Multi-Bioinspired Structures.

Photothermal superhydrophobic surfaces are potential to become ideal anti-/deicing surfaces due to their rapid water removal, icing delay, and photothermal deicing performance. Here, a robust photothermal icephobic surface with mechanical durability is shown that is integrated with a microspine array inspired by honeycomb and cactus thorn (i.e., MAHC), which is developed by a laser-layered microfabrication strategy. The maximum stress on the microspine of the MAHC is reduced by ≈2/3, due to the protection of the bionic honeycomb structure. Even after 200 linear abrasions by a steel blade, the MAHC remains superior water repellency with a water contact angle of 150.7° and roll-off angles of 10.3°, stable icing delay time (578.2 s), and rapidly photothermal deicing capabilities (401 s). As the MAHC is fabricated on a curvature surface such as a copper alloy transmission line for an overhead high-speed rail, a stable photothermal anti-/deicing in a low-temperature environment still can be achieved effectively. The freezing rain covering the functional transmission line completely slides off within 758 s under one sun illumination. This studying offers insight into the design of novel materials with stable anti-icing/icephobic structures, which would be extended into some applied realms, for example, transportation fields or power systems in cold or low-temperature climates.

Highly Efficient Photothermal Icephobic/de-Icing MOF-Based Micro and Nanostructured Surface.

Photothermal materials have gained considerable attention in the field of anti-/de-icing due to its environmental friendliness and energy saving. However, it is always significantly challenging to obtain solar thermal materials with hierarchical structure and simultaneously demonstrate both the ultra-long icing delay ability and the superior photothermal de-icing ability. Here, a photothermal icephobic MOF-based micro and nanostructure surface (MOF-MNS) is presented, which consists of micron groove structure and fluorinated MOF nanowhiskers. The optimal MOF-M250 NS can achieve solar absorption of over 98% and produce a high temperature increment of 65.5 °C under 1-sun illumination. Such superior photothermal-conversion mechanism of MOF-M250 NS is elucidated in depth. In addition, the MOF-M250 NS generates an ultra-long icing delay time of ≈3960 s at -18 °C without solar illumination, achieving the longest delay time, which isn't reported before. Due to its excellent solar-to-heat conversation ability, accumulated ice and frost on MOF-M250 NS can be rapidly melted within 720 s under 1-sun illumination and it also holds a high de-icing rate of 5.8 kg m-2 h-1 . MOF-M250 NS possesses the versatility of mechanical robustness, chemical stability, and low temperature self-cleaning, which can synergistically reinforce the usage of icephobic surfaces in harsh conditions.

Dynamic Anti-Icing Performance of Flexible Hybrid Superhydropohobic Surfaces.

Normal superhydrophobic surfaces with a rough topography provide pocketed air at the solid-liquid interface, which guides the droplet to easily detach from the surface at room temperature. However, at low temperatures, this function attenuates obviously. In this research, a flexible hybrid topography with submillimeter (sub-mm) and microcone arrays is designed to adjust the impacting behavior of the droplet. The sub-mm cone could provide rigid support to limit deformation, leading to reduced energy consumption during impact processes. However, the microcone could maintain surface superhydrophobicity under different conditions, preventing droplet breakage and the change of the droplet contact state during impact processes by providing multiple contact points. Under the synergistic effect, such a hybrid structure could provide much more pocket air at the solid-liquid interface to limit the spreading of liquid droplets and reduce the energy loss during the impact process. At a low temperature (-5 °C), even if the impact height is reduced to 1 cm, the droplets still could be bound off, and the hybrid superhydrophobic surface presents excellent dynamic anti-icing ability. The special flexible hybrid superhydropohobic surface has potential application in fast self-cleaning and anti-icing fields.

A UV-Resistant Heterogeneous Wettability-Patterned Surface.

Preparing UV-resistant heterogeneous wettability patterns is critical for the practical application of surfaces with heterogeneous wettability. However, combining UV-resistant superhydrophobic and superhydrophilic materials on heterogeneous surfaces is challenging. Inspired by the structure of cell membranes, a UV-resistant heterogeneous wettability-patterned surface (UPS) is designed via laser ablation of the coating of multilayer structures. UV-resistant superhydrophobic silica patterns can be created in situ on surfaces covered with superhydrophilic TiO2 nanoparticles. The UV resistance time of the UPS with a TiO2 -based surface is more than two orders of magnitude higher than that obtained with other surface molecular modification methods that require a mask. The cell-membrane-like structure of the UPS regulates the migration of internal siloxane chain segments in the hydrophilic and hydrophobic regions of the surface. The UPS enables efficient patterning of functional materials under UV irradiation, controlling the wetting behavior of liquids in open-air systems. Furthermore, its heterogeneous wettability remains stable even after 50 h of intense UV irradiation (365 nm, 500 mW cm-2 ). These UV-resistant heterogeneous wettability patterned surfaces will likely be applied in microfluidics, cell culture, energy conversion, and water collection in the future.

Efficient Atmospheric Water Harvesting of Superhydrophilic Photothermic Nanocapsule.

Drought and water scarcity are two of the world's major problems. Solar-powered sorption-based atmospheric water harvesting technology is a promising solution in this category. The main challenge is to design materials with high water harvesting performance while achieving fast water vapor adsorption/desorption rates. Here, a superhydrophilic photothermic hollow nanocapsule (SPHN) is represented that achieves efficient atmospheric water harvesting in outdoor climates. In SPHN, the hollow mesoporous silica (HMS) is grafted with polypyrrole (PPy) and also loaded with lithium chloride (LiCl). The hollow structure is used to store water while preventing leakage. The hydrophilic spherical nanocapsule and the trapped water produce more free and weakly adsorbed water. Significantly lower the heat of desorption compared to pure LiCl solution. Such SPHN significantly improves the adsorption/desorption kinetics, e.g., absorbs 0.78-2.01 g of water per gram of SPHN at 25 °C, relative humidity (RH) 30-80% within 3 h. In particular, SPHN has excellent photothermal properties to achieve rapid water release under natural sunlight conditions, i.e., 80-90% of water is released in 1 h at 0.7-1.0 kW m-2 solar irradiation, and 50% of water is released even at solar irradiation as low as 0.4 kW m-2 . The water collection capacity can reach 1.2 g g-1 per cycle by using the self-made atmospheric water harvesting (AWH) device. This finding provides a way to design novel materials for efficient water harvesting tasks, e.g., water engineering, freshwater generator, etc.

Enhanced Fog Harvesting through Capillary-Assisted Rapid Transport of Droplet Confined in the Given Microchannel.

A novel integrated bioinspired surface is fabricated by using an innovative capillarity-induced selective oxidation method, to achieve the combination of the fog-collecting characteristics of a variety of creatures, i.e., the micronanostructures of spider silk, the wettable patterns of desert beetle, the conical structure of cactus spine, and the hierarchical microchannel of Sarracenia trichome. The fog is captured effectively via multistructures on the cone tips, and captured droplet is collected and confined in the microchannel to realize rapid transport via the formation of wettable pattern on the surface and the introduction of wettable gradient in the microchannel. Consequently, the fog harvest efficiency reaches 2.48 g/h, increasing to nearly 320% compared to the normal surface. More interestingly, similar to Sarracenia trichome, the surface also presents two transport modes, namely, Mode I (water transport along dry microchannel) and Mode II (succeeding water slippage on the water film). In Mode II, the velocity of 34.10 mm/s is about three times faster than that on the Sarracenia trichome. Such a design of integrated bioinspired surface may present potential applications in high-efficiency water collection systems, microfluidic devices, and others.

Elastic Microstaggered Porous Superhydrophilic Framework as a Robust Fogwater Harvester.

A robust fogwater harvester with an elastic microstaggered porous superhydrophilic framework (EMSF) has been designed. The EMSF can be fabricated by using polydimethylsiloxane and polyvinyl alcohol (PVA) via an etching method of sugar crystals pile-up cube as a template. The EMSF possesses a high porosity of 76%, of which the saturated fogwater-capturing capacity is 4 times higher than its weight, achieving a high fogwater harvesting rate (ε) of 62.7 g/cm3·h. It is attributed to the strong hydrogen bond (H-bond) interaction between hydroxyl groups (-OH) in PVA and water molecules for rapidly harvesting water and storing water in a staggered porous structure by means of a capillary force. The elasticity of EMSF allows to achieve a higher fogwater harvesting rate (ε) of 73.2 g/cm3·h via releasing the as-stored water in the EMSF under periodic external pressing. In addition, a durable corrosion resistance is demonstrated on the EMSF. This study offers a way to design novel materials that would further be extended into applications, for example, fog engineering in industry, agriculture, forest, and so forth.

Bioinspired Nanofibril-Humped Fibers with Strong Capillary Channels for Fog Capture.

Bioinspired nanofibril-humped fibers (BNFs) are fabricated by using thermoplastic polyester elastomer and chitosan, via combining the electrospinning technique and fluid coating method to achieve periodic humps composed of interlaced random nanofibrils and a joint composed of aligned nanofibrils, which are highly similar to the micro/nanostructures of wetted spider silk. Especially, nanofibrils can increase the specific area of the hump to capture fog droplets effectively and transport water in channels between the nanofibrils under humid conditions, and thus the fog droplets can coalesce and be highly efficiently transported toward humps for water collection directionally. Such an ability of highly efficient fog capture is attributed to cooperation of an efficient transportation inside the outer shell of BNFs and outside transportation. Inside transportation is induced by anisotropic capillary channels between nanofibrils. When BNFs are wetted, the inside transportation mode is dominated for water collection, induced by anisotropic capillary channels between nanofibrils. BNF web is also used to investigate the droplet transportation in different cross-fiber contact modes in the process of fog capture on a large scale. This study offers an insight into the design of novel materials, which is expected to be developed for some realms of applications, such as fog harvesting engineering, filtration, and others.

Fog Collection on a Bio-inspired Topological Alloy Net with Micro-/Nanostructures.

Because of the scarcity of freshwater resources, fog collection as one of the effective methods to solve this issue has attracted widespread concern. Inspired by several natural creatures with the capability to collect water from fog, the bio-inspired water-harvesting materials have aroused considerable attention and been widely developed. Inspired by the directional water droplets transportation to the apex on both shorebirds beaks and wheat awns, the bio-inspired topological alloy net with a V-shaped asymmetric geometry in its mesh was designed for fog collecting. Then, micro-/nano-hierarchical structures were modified on the surface of the netting wire via the cathodic electrodeposition method. Thus, the bio-inspired topological alloy net with micro/nanostructures was fabricated successfully. Through the integration of topological geometry and surface microstructure, not only the water-collection rate is improved by efficient drainage along the designated pathways, but also the issue of mesh clogging is resolved. In addition, a theoretical model was constructed to reveal the mechanism, especially the resultant force arising from the V-shaped structure. This work provides insight into the development of novel fog-collecting materials, which has potential applications in other fields, such as liquid transportation, microfluidics, and interface science.

Water Harvesting of Bioinspired Microfibers with Rough Spindle-Knots from Microfluidics.

Heterostructure rough spindle-knot microfibers (HRSFs) are fabricated via a flexible parallel-nozzle microfluidic method. In this method, the bioinspired HRSF with a roughness gradient between spindle-knots and joints, can be manufactured in large-scale, and with which the size of the spindle-knots and joints can be precisely adjusted by regulating flow rates. The HRSFs, fabricated with chitosan and calcium alginate, have strong mechanical properties and corrosion resistance in acid environment (pH = 5) and alkaline environment (pH = 9), respectively. More attractively, under controlled treatment conditions, the morphology of the spindle-knots on the HRSFs can be effectively managed by changing the composite content of calcium chloride in the fluid. During the water collection process, tiny droplets of moisture can be captured on the surface of the HRSFs, subsequently, the droplets can coalesce and be transported from joint to spindle-knot sections. It is demonstrated that the surface morphology of spindle-knots directly influences the water collection efficiency, where a higher roughness gradient generates higher water collection efficiency. This parallel-nozzle microfluidic technology provides a low-cost and flexible method to manufacture high biocompatibility bioinspired rough spindle-knot microfibers, which has many potential applications in large-scale water collection, sustained drug release, and directional water collection.

Integrative Bioinspired Surface with Wettable Patterns and Gradient for Enhancement of Fog Collection.

A novel integrative bioinspired surface with wettable patterns and gradient (WPGS) is proposed for fog collection via a novel anodic oxidation strategy. We study the water collection behaviors on WPGS with different parameters. Quantitative force analysis is presented, providing evidence for the underlying mechanism leading to the directional motion of the droplet, which is consistent with the experimental results. Such a surface can not only improve the fog droplet capture performance effectively owing to wettable patterns but also accelerate surface regeneration by taking full advantage of the cooperation of multidriving forces, leading to a further fog collection enhancement.

Unidirectional Droplet Transport on the Biofabricated Butterfly Wing.

Water droplet unidirectional transport on the asymmetric superhydrophobic surface has attracted much interest in theory analysis and applications, such as self-cleaning, antifogging, anti-icing, heat transfer, and so on. Different from the symmetrical performance on the uniform topographies, the droplets acting on the asymmetric surface exhibit an anisotropic state and easily roll off the surface along the special direction. This phenomenon is indicated by natural butterfly wings. The flexible asymmetrically arranged microstep induces the droplet to release along the outside radial (RO) direction and to pin against the RO direction. Here, inspired by butterfly wings, a kind of surface for superhydrophobic and unidirectional droplet transport is achieved by integrating the methods of soft lithography and enhanced crystal growth. The water droplet shows the anisotropic state on the biofabricated surface, and it rolls off easily along the step direction. The droplet is unidirectionally driven off the surface by the asymmetric surface tension force generated by the microstep topography. This experiment is significant for designing self-cleaning surfaces.

Controlled droplet transport to target on a high adhesion surface with multi-gradients.

We introduce multi-gradients including Laplace pressure gradient, wettable gradient and wettable different gradient on a high adhesion surface via special wedge-pattern and improved anodic oxidation method. As a result of the cooperative effect mentioned above, controlled directional motion of a droplet on a high adhesion surface is realized, even when the surface is turned upside down. The droplet motion can be predicted and the movement distances can be controlled by simply adjusting the wedge angle and droplet volume. More interestingly, when Laplace pressure gradient is introduced on a V-shaped wettable gradient surface, two droplets can move toward one another as designed.

Long time and distance self-propelling of a PVC sphere on a water surface with an embedded ZnO micro-/nano-structured hollow sphere.

In this research, a zinc oxide micro-/nano-structured hollow sphere (MNHS) with a large specific surface area is applied as energy storage material to encapsulate poly(vinyl chloride) solution and control the fuel release. The sustained release effect of MNHS not only makes the motion more controllable, but enhances the motion time and distance.

Controlled Smart Anisotropic Unidirectional Spreading of Droplet on a Fibrous Surface.

Smart anisotropic-unidirectional spreading is displayed on a wettable-gradient-aligned fibrous surface due to a synergetic directing effect from the aligned structure and the ratio of hydrophilic components.

Dynamic Magnetic Responsive Wall Array with Droplet Shedding-off Properties.

Directional control of droplets on a surface is an important issue for tasks of long-range liquid-transport, self-cleaning and water repellency. However, it is still challenging to control the structure motions in orientations so as to control the shedding-off of droplets. Herein, we report a novel dynamic magnetic responsive wall (DMRW) array on PDMS (polydimethylsiloxane)-based surface. The walls can easily tilt through the effect of the external magnet because of the magnetic material in the DMRW. The droplets can be shed off directionally on the surface. Particularly, with the shape recovery and flexible properties, it achieves simultaneous control of the tilt angles (0-60°) of DMRW for shedding-off of droplets with different volumes (1-15 µL) under magnetic action on DMRW. The mechanism of droplet shedding-off on DMRW is elucidated by theory of interfaces. It offers an insight into design of dynamic interface for water repellency. This strategy realizes the preparation of multifunctional, tunable and directional drive functions.

Radial wettable gradient of hot surface to control droplets movement in directions.

A radial wettable gradient was fabricated on the surface of graphite plate by a simple one-step anodic oxidation process. It was found that the direction and value of the wettable gradient could be easily controlled by adjusting current and oxidation time gradient. With the increase of surface temperature, droplets on surface not only exhibited the transition of boiling mode, but also showed the controlled radial spreading, evaporation and movement behaviors. These phenomena could be attributed to the cooperation of wettability force, hysteresis force and vapor pressure (Leidenfrost effect). Especially, the controlled radial convergence or divergence of droplets with high velocity were realized on the surfaces with either inside or outside radial gradient, which would have crucial applications in the design of microfluidic devices and the exploration of the biotechnology.

Controlled droplet transport on a gradient adhesion surface.

A surface with continuously changed adhesion from ultrahigh to ultralow is fabricated by an integrated method of anodic oxidation combined with octafluorocyclobutane (C4F8) plasma. The control of droplet transport along the direction of the adhesion gradient in length is achieved, as the surface is submitted to either tilted angle or vibration frequency.