RESUMEN
In this study, we synthesized various dimensionalities of ZnO nanowires using the Ti grid-assisted chemical vapor deposition process. Energy dispersive X-ray spectroscopic mapping technique accompanied with a lattice diffusion model was used to characterize the growth mechanism. A diffusion ratio γ, defined by short-circuit and lattice diffusion activation energies, was obtained to describe the growth mechanism of ZnO nanowires. The tunable dimensionalities of ZnO nanowires allow us to modify the morphology of ZnO nanocrystals by developing well-controlled potential applications.
RESUMEN
In this work, we succeeded in preparing in-plane zinc oxide nanowires using a Ti-grid assisted by the chemical vapor deposition method. Optical spatial mapping of the Confocal Raman spectra was used to investigate the phonon and geometric properties of a single ZnO nanowire. The local optical results reveal a red shift in the non-polar E2 high frequency mode and width broadening along the growth direction, reflecting quantum-confinement in the radial direction.