Sustainability in Membrane Technology: Membrane Recycling and Fabrication Using Recycled Waste.

Membrane technology has shown a promising role in combating water scarcity, a globally faced challenge. However, the disposal of end-of-life membrane modules is problematic as the current practices include incineration and landfills as their final fate. In addition, the increase in population and lifestyle advancement have significantly enhanced waste generation, thus overwhelming landfills and exacerbating environmental repercussions and resource scarcity. These practices are neither economically nor environmentally sustainable. Recycling membranes and utilizing recycled material for their manufacturing is seen as a potential approach to address the aforementioned challenges. Depending on physiochemical conditions, the end-of-life membrane could be reutilized for similar, upgraded, and downgraded operations, thus extending the membrane lifespan while mitigating the environmental impact that occurred due to their disposal and new membrane preparation for similar purposes. Likewise, using recycled waste such as polystyrene, polyethylene terephthalate, polyvinyl chloride, tire rubber, keratin, and cellulose and their derivates for fabricating the membranes can significantly enhance environmental sustainability. This study advocates for and supports the integration of sustainability concepts into membrane technology by presenting the research carried out in this area and rigorously assessing the achieved progress. The membranes' recycling and their fabrication utilizing recycled waste materials are of special interest in this work. Furthermore, this study offers guidance for future research endeavors aimed at promoting environmental sustainability.

Polyvinylidene fluoride (PVDF)-α-zirconium phosphate (α-ZrP) nanoparticles based mixed matrix membranes for removal of heavy metal ions.

The removal of heavy metal ions from industrial wastewater is essential as they pose serious threats to human health and the environment. In this study, novel poly(vinylidene fluoride) (PVDF)-alpha-zirconium phosphate (PVDF-α-ZrP) mixed matrix membranes (MMM) were prepared via the phase inversion method. Membranes with different α-ZrP nanoparticles (NPs) loadings (0.25, 0.50, 0.75, or 1.00 wt%) were fabricated. The impacts of α-ZrP NP loading on the membrane's morphology, functionality, surface charge, and hydrophilicity were evaluated. Fourier-transform infrared and the energy-dispersive X-ray spectroscopy were performed to verify the presence of α-ZrP NPs in the fabricated membranes. The PVDF membranes became more hydrophilic after incorporating the α-ZrP NPs. The thermal and mechanical stability and porosity of the PVDF-α-ZrP MMM were higher than those of the pristine PVDF membrane. The increased hydrophilicity, pore size and porosity and reduced surface roughness of the PVDF-α-ZrP membrane led to significant flux increase and reduced fouling propensity. The PVDF-α-ZrP membrane containing 1.00 wt% α-ZrP was capable of removing 42.8% (Cd2+), 93.1% (Cu2+), 44.4% (Ni2+), 91.2% (Pb2+), and 44.2% (Zn2+) from an aqueous solution at neutral pH during filtration.

Detection and quantification of SARS-CoV-2 RNA in wastewater and treated effluents: Surveillance of COVID-19 epidemic in the United Arab Emirates.

Testing SARS-CoV-2 viral loads in wastewater has recently emerged as a method of tracking the prevalence of the virus and an early-warning tool for predicting outbreaks in the future. This study reports SARS-CoV-2 viral load in wastewater influents and treated effluents of 11 wastewater treatment plants (WWTPs), as well as untreated wastewater from 38 various locations, in the United Arab Emirates (UAE) in May and June 2020. Composite samples collected over twenty-four hours were thermally deactivated for safety, followed by viral concentration using ultrafiltration, RNA extraction using commercially available kits, and viral quantification using RT-qPCR. Furthermore, estimates of the prevalence of SARS-CoV-2 infection in different regions were simulated using Monte Carlo. Results showed that the viral load in wastewater influents from these WWTPs ranged from 7.50E+02 to over 3.40E+04 viral gene copies/L with some plants having no detectable viral RNA by RT-qPCR. The virus was also detected in 85% of untreated wastewater samples taken from different locations across the country, with viral loads in positive samples ranging between 2.86E+02 and over 2.90E+04 gene copies/L. It was also observed that the precautionary measures implemented by the UAE government correlated with a drop in the measured viral load in wastewater samples, which were in line with the reduction of COVID-19 cases reported in the population. Importantly, none of the 11 WWTPs' effluents tested positive during the entire sampling period, indicating that the treatment technologies used in the UAE are efficient in degrading SARS-CoV-2, and confirming the safety of treated re-used water in the country. SARS-CoV-2 wastewater testing has the potential to aid in monitoring or predicting an outbreak location and can shed light on the extent viral spread at the community level.

Synthesis of super hydrophilic cellulose-alpha zirconium phosphate ion exchange membrane via surface coating for the removal of heavy metals from wastewater.

In this study, commercial cellulose membranes were surface coated with alpha­zirconium phosphate nanoparticles (α-ZrP-n) to study their impact on the overall removal efficiency of heavy metals from synthetic metal mixture wastewater solution. A total of four homogeneous solutions (0.25, 0.50, 0.75, and 1.00 wt%) of α-ZrP-n were prepared by sonicating the nanoparticles in deionized water. These solutions were used to surface coat the commercial cellulose membranes. The Scanning Electron Microscopy (SEM) along with Energy Dispersive Spectroscopy (EDS) were used to confirm the attachment of α-ZrP-n on the cellulose membrane surface. Furthermore, the structural characteristics of the α-ZrP-n modified cellulose membranes were also studied. The water contact angle results showed that all coated membranes remained super-hydrophilic. The porosity of the membranes decreased to 48% with the addition of 1.00 wt% α-ZrP-n compared to 65% for the pristine membrane. The mechanical strength has improved from 3.4 MPa for the pristine membrane to about 4 MPa for the 1.00 wt% α-ZrP-n membrane. Similarly, the thermal stability was found to be slightly enhanced as evidenced by the increase in decomposition temperature to 280 and 285 °C in the 0.75 and 1.00 wt% α-ZrP-n membranes, respectively. Furthermore, a removal efficiency of 97.0 ±â€¯0.6, 98.0 ±â€¯0.5, 99.5 ±â€¯0.2, and 91.5 ±â€¯2.0% for Cu (II), Zn (II), Ni (II), and Pb (II), respectively, was observed with the 0.50 wt% α-ZrP-n membrane. This removal was achieved at a flux of 41.85 ±â€¯0.87 × 103 LMH. Increasing the α-ZrP-n concentration further did not show any improvement in the overall removal efficiency. However, it led to 46% flux reduction in the 1.00 wt% α-ZrP-n membrane. The mechanism of removal of the heavy metal ions was postulated to be a combination of ion exchange and electrostatic attraction of the strong negatively charged α-ZrP-n membranes and the free metal ions in the wastewater solution.