Layered Double Hydroxides for Regulating Phosphate in Water to Achieve Long-Term Nutritional Management.

Hunger and undernourishment are increasing global challenges as the world's population continuously grows. Consequently, boosting productivity must be implemented to reach the global population's food demand and avoid deforestation. The current promising agricultural practice without herbicides and pesticides is fertilizer management, particularly that of phosphorus fertilizers. Layered double hydroxides (LDHs) have recently emerged as favorable materials in phosphate removal, with practical application possibilities in nanofertilizers. This review discusses the fundamental aspects of phosphate removal/recycling mechanisms and highlights the current endeavors on the development of phosphate-selective sorbents using LDH-based materials. Specific emphasis is provided on the progress in designing LDHs as the slow release of phosphate fertilizers reveals their relevance in making agro-practices more ecologically sound. Relevant pioneering efforts have been briefly reviewed, along with a discussion of perspectives on the potential of LDHs as green nanomaterials to improve food productivity with low eco-impacts.

Improvements in the Performance of a Visible-NIR Photodetector Using Horizontally Aligned TiS3 Nanoribbons.

We report the fabrication and characterization of visible and near-infrared-resistive photodetector using horizontally aligned titanium tri sulfide (TiS3) nanoribbons. The fabrication process employed micro-electromechanical system, photolithography and dielectrophoretic (DEP) methods. The interdigitated electrodes (IDE) fingers were fabricated using photolithography and thin-film metallization techniques onto the Si/SiO2 substrate, and then TiS3 nanoribbons were horizontally aligned in between IDE using DEP. The fabricated device was first characterized in absence of light and then, the photodetector-based characteristics were obtained by illuminating it with fiber-coupled laser beam. These characteristics were optimized by varying wavelength and power density of the laser beam. The present photodetector shows a maximum responsivity of 5.22 × 102 A/W, quantum efficiency of 6.08 × 102, and detectivity of 1.69 × 109 Jones. The switching times, i.e., response and recovery times were found to be 1.53 and 0.74 s, respectively, with 1064 nm wavelength and 3.4 mW/mm2 power density of the laser beam. Also, the effect of O2 adsorption on nanoribbons has been studied and it is found that adsorbed O2 acts as electron acceptor and decreases the conductivity of the photodetector. Experimentally, it is found that the photoresponse of the horizontally aligned TiS3 nanoribbons is better than that of a randomly oriented TiS3 nanoribbon-based photodetector. Finally, the performance of the present photodetector was compared to that of the previous ones that were found to outperform the reported ones. The additional advantages of the photodetector include excellent stability and portability from which it may be concluded that TiS3 nanoribbons can be a promising candidate for application in nanoscale electronic and optoelectronic devices.