1.
Org Lett
; 25(11): 1868-1871, 2023 Mar 24.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36913953
RESUMEN
Herein, an efficient, scalable, and concise approach to an advanced pyrroloiminoquinone synthetic intermediate (6b) by way of a Larock indole synthesis is reported. The synthetic utility of this intermediate is demonstrated by its ready conversion to makaluvamines A (1) and K (4).
2.
Org Lett
; 23(4): 1243-1246, 2021 02 19.
Artículo
en Inglés
| MEDLINE
| ID: mdl-33517659
RESUMEN
An enantioselective total synthesis of plagiochianin B is described that employs (+)-3-carene as its point of departure and delivers the enantiomer of the natural product. Key features of the synthesis include a palladium-mediated regioselective oxidative cleavage of an olefin residing on a pyridine derived from a 6π-azatriene electrocyclization.