1.
Dalton Trans
; 50(31): 10696-10700, 2021 Aug 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-34318832
RESUMEN
The hydroboration of aldehydes, ketones and CO2 is demonstrated using a cheap and air stable [Fe(salen)]2-µ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)2]-µ-oxo pre-catalyst shows good efficacy at reducing "wet" CO2 with HBpin at room temperature.