RESUMEN
Materials dictate carbon neutral industrial chemical processes. Visible-light photoelectrocatalysts from abundant resources will play a key role in exploiting solar irradiation. Anionic doping via pre-organization of precursors and further co-polymerization creates tuneable semiconductors. Triazole derivative-purpald, an unexplored precursor with sulfur (S) container, combined in different initial ratios with melamine during one solid-state polycondensation with two thermal steps yields hybrid S-doped carbon nitrides (C3 N4 ). The series of S-doped/C3 N4 -based materials show enhanced optical, electronic, structural, textural, and morphological properties and exhibit higher performance in organic benzylamine photooxidation, oxygen evolution, and similar energy storage (capacitor brief investigation). 50M-50P exhibits the highest photooxidation conversion (84 ± 3%) of benzylamine to imine at 535 nm - green light for 48 h, due to a discrete shoulder (≈700) nm, high sulfur content, preservation of crystal size, new intraband energy states, structural defects by layer distortion, and 10-16 nm pores with arbitrary depth. This work innovates by studying the concomitant relationships between: 1) the precursor decomposition while C3 N4 is formed, 2) the insertion of S impurities, 3) the S-doped C3 N4 property-activity relationships, and 4) combinatorial surface, bulk, structural, optical, and electronic characterization analysis. This work contributes to the development of disordered long-visible-light photocatalysts for solar energy conversion and storage.
RESUMEN
Heteroatom doping of carbon networks may introduce active functional groups on the surface of the material, induce electron density changes that alter the polarity of the carbon surface, promote the formation of binding sites for molecules or ions, or make the surface catalytically active for different reactions, among many other alterations. Thus, it is no surprise that heteroatom doping has become a well-established strategy to enhance the performance of carbon-based materials for applications ranging from water remediation and gas sorption to energy storage and conversion. Although oxygen functionalization is sometimes inevitable (i.e., many carbon precursors contain oxygen functionalities), its participation in carbon materials performance is often overlooked on behalf of other heteroatoms (mainly nitrogen). In this Mini-review, we summarize recent and relevant publications on the effect that oxygen functionalization has on carbonaceous materials performance in different electrochemical applications and some strategies to introduce such functionalization purposely. Our aim is to revert the current tendency to overlook it and raise the attention of the materials science community on the benefits of using oxygen functionalization in many state-of-the-art applications.