RESUMEN
In this work, a photo-polymerization route was used to obtain potassium acrylate-co-acrylamide hydrogels with enhanced mechanical properties, well-defined microstructures in the dry state, and unique meso- and macrostructures in the hydrated state. The properties of the hydrogels depended on the concentration of the crosslinking agent. Mechanical properties, swelling capacity, and morphology were analyzed, showing a well-defined transition at a critical concentration of the crosslinker. In terms of morphology, shape-evolving surface patterns appeared at different scales during swelling. These surface structures had a noticeable influence on the mechanical properties. Hydrogels with structures exhibited better mechanical properties compared to unstructured hydrogels. The critical crosslinking concentration reported in this work (using glycerol diacrylate) is a reference point for the future preparation of multistructured acrylic hydrogel with enhanced properties.
RESUMEN
Global environmental pollution issues caused by synthetic materials and the lack of practical utilization of the local industrial lignocellulosic waste, force Mexican researchers to produce new biobased sustainable materials that use industrial waste as a source of components. Herein, we show the preparation and characterization of environmentally friendly starch-based nanocomposites reinforced with cellulose nanofibrils (CNF) extracted from Agave tequilana Weber. Tensile, bending and impact mechanical properties of dried and hydrated nanocomposites were studied. Moreover, the water absorption capacity of the nanocomposites were measured and evaluated. The mechanical properties improved because of the presence of a small amount of CNF (1 wt%). This work demonstrates the importance of the addition of a natural biomodifier in a starch matrix to achieve better mechanical properties. Most importantly, this study highlights that lignocellulosic waste from the tequila industry can have a practical application, which is being a source of natural nanoreinforcements for preparation of all-biobased sustainable materials.