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To effectively control the dust generated by coal mining operations, a new type of cyclonic pneumatic mist curtain dust control device was developed. Using CFD software, numerical simulations were conducted on the internal airflow velocity field, the exit velocity of the cyclonic pneumatic mist curtain, and the mist droplet particle field of the curtain. Experiments were carried out to measure the spray coverage, droplet size, and the dust control performance of the model device. The results indicate that when the water pump supply pressure is 8 MPa, the fan supply wind speed is 12 m/s, and the nozzle installation angle is 75 degrees, the cyclonic pneumatic mist curtain dust control device model operates under optimal conditions. The effective coverage of the cyclonic mist curtain is 380 × 3300 mm, fully suppressing dust generation on one side of the curtain. An optimal dust removal distance of about 90 cm was determined. After installing the cyclonic pneumatic mist curtain dust control device, the average dust reduction efficiency for respirable dust reached 91.07%, and the overall dust reduction efficiency achieved 93.34%.
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To improve the wettability of surfactants on bituminous coal and to explore its wettability and wettability mechanism on bituminous coal, taking the Sandaogou bituminous coal as an example, a single factor experiment was carried out first. Through contact angle and surface tension experiments, three surfactants with good wettability were selected from among the nine surfactants and mixed in equal proportions two by two to determine the optimal compounding method and compounding concentration. The experimental results show that the compounding of nonionic and anionic, nonionic and zwitterionic, anionic and zwitterionic surfactants can have synergistic effects and significantly improve the wettability of bituminous coal. Among them, the 0.5 wt% SDS + 0.5 wt% CAB-50 (R2) compound surfactant had the best wettability on bituminous coal, and the contact angle and surface tension were only 15.24° and 23.62 mN/m, respectively. The surface electrostatic potential values of each material molecule were calculated by Materials Studio software based on the quantum chemistry method, and correlation analysis was carried out with wettability. The results show that the surface electrostatic potentials of CDEA, SDS and CAB-50 were greater than those of water and bituminous coal, and the region of maximum negative electrostatic potential corresponded to oxygen atoms, which are easier to adsorb on bituminous coal and water molecules. Then, through molecular dynamics simulation, the interaction energy and the distribution of contributions along the Z-axis of the water/compound surfactant/bituminous coal system at equilibrium were investigated, and finally, a spray dust reduction test was carried out in the Sandaogou Coal Mine. The results showed that the 0.5 wt% SDS + 0.5 wt% CAB-50 compound solution can be used as a water molecule adsorption carrier, prompting more water molecules to be embedded into coal molecules, increasing the relative concentration of water molecules on the surface of bituminous coal, restricting the diffusion of water molecules, and greatly improving the wettability. After the addition of 0.5 wt% SDS + 0.5 wt% CAB-50 as a spray agent, the concentration of total dust at the driver's position decreased from 65.14 to 9.11 mg/m3, the concentration of exhaled dust decreased from 30.07 to 3.35 mg/m3, and the efficiency of total and exhaled dust reduction compared with that of pure water was 86.01% and 89.35%, respectively.
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In order to efficiently and accurately control coal dust pollution in coal mining faces, this study addresses the insufficient research on the dust generation mechanism during cutting. Firstly, a similar experimental platform for simulating coal wall cutting with a drum cutter was used to investigate the changes in coal wall fragmentation and dust generation at drum speeds of 35 r/min, 50 r/min, 65 r/min, and 80 r/min. The experimental results revealed that the degree of coal wall fragmentation and dust generation increased with the increase in rotational speed, leading to a wider range of particle size distribution and an increase in the generation of fine dust particles. A 1:1 scale discrete element simulation of coal wall cutting with a drum cutter was conducted based on the experiments. The results indicated that, under the four rotational speeds, the cracks generated during coal wall fracture were predominantly tensile cracks, accounting for over 76% of the total crack count. The total number of cracks increased from 10,600 to 11,200, the number of free single particles increased from 2555 to 2728, and the fragmentation volume increased from 0.021607 to 0.023024 m3. The range and degree of coal wall fragmentation increased with the increase in drum speed.
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Refined volatile organic compound (VOC) emission characteristics are crucial for accurate source apportionment in chemical industrial parks. The data from mobile monitoring platforms in chemical industrial parks contain pollution information that is not intuitively displayed, requiring further excavation. A novel approach was proposed to identify VOC emission characteristics using the class activation map (CAM) technology of convolutional neural network (CNN), which was applied on the mobile monitoring platform data (MD) derived from a typical fine chemical industrial park. It converts a large amount of monitoring data with high spatiotemporal complexity into simple and interpretable characteristic maps, effectively improving the identification effect of VOC emission characteristics, supporting more accurate source apportionment of VOC pollution around the park. Using this method, the VOC emission characteristics of eight key factories were identified. VOC source apportionment in the park was conducted for one day using a positive matrix factorization (PMF) model and seven combined factor profiles (CFPs) were calculated. Based on the identified VOC emission characteristics, the main pollution sources and their contributions to surrounding schools and residential areas were determined, revealing that one pesticide factory (named LKA) had the highest contribution ratio. The source apportionment results indicated that the impact of the chemical industrial park on the surrounding areas varied from morning to afternoon, which to some extent reflected the intermittent production methods employed for fine chemicals.
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At this stage, there are many dust-hazardous industries, and occupational pneumoconiosis has a high incidence for a long time. To solve the dust pollution problem in coal processing plant workshops, the dust particle field and liquid droplet particle field were numerically simulated using computational fluid dynamics (CFD), and the influences of the induced airflow and corridor wind speed on the internal airflow field of the workshop were investigated to derive the dust pollution mechanism in the coal plant workshop under the change in the wind flow field. In this study, it was shown that the wind flow rate in the coal processing plant workshop is mainly affected by the corridor wind speed, and the higher the corridor wind speed is, the higher the wind flow rate. The induced airflow mainly affected the direction of the wind flow field in the workshop. According to the conclusions obtained from the simulations, a spray dust reduction system was designed for the coal processing plant workshop and applied in the Huangyuchuan coal processing plant. On-site measurement revealed that the dust reduction effect inside the coal processing plant workshop is obvious, and the overall dust reduction efficiency in the workshop reaches more than 94%, which meets the requirements of environmentally sustainable development and clean production.
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Minas de Carbón , Neumoconiosis , Humanos , Polvo/análisis , Contaminación Ambiental , Carbón Mineral/análisisRESUMEN
The growing demand for pesticide manufacturing and increasing public awareness of sustainable development, have let to urgent requirements for a refined environmental management framework. It is imperative to conduct process-based life cycle assessments (LCAs) to promote clean and environment-friendly technologies. Herein, the cradle-to-gate LCA of glyphosate production was executed as an example to investigate crucial production factors (materials or energy) and multiple environmental impacts during the production processes. Results showed that methanol caused the highest environmental damage in terms of toxicity, with a normalized value of 85.7 × 10-8, followed by coal-fired electricity in 6.00 × 10-8. Furthermore, optimized schemes were proposed, including energy improvement (electricity generated by switching from coal-fired power to solar power) and wastewater targeted conversion. Regarding the normalization results before and after optimization, the latter showed more significant results with the normalized value decreasing by 21.10 × 10-8, while that of the former only decreased by 6.50 × 10-8. This study provides an integrated LCA framework for organophosphorus pesticides (OPs) from upstream control and offers an important supplement to managing the key pollution factors and control links of the OP industry. Moreover, it reveals the positive influence of optimized schemes in facilitating cleaner production technologies, thus ultimately promoting new methodologies for resource recycling.
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Plaguicidas , Animales , Compuestos Organofosforados , Carbón Mineral , Estadios del Ciclo de VidaRESUMEN
A numerical model of single-particle fog-dust collision coupling in a high-speed airflow based on three-phase flow theory. The effect of the fog-to-dust particle size ratio, relative velocity between the fog and dust particles, collision angle and contact angle at the wetting humidity function of dust particles is investigated. Different particle size ratios are determined for achieving the optimal wetting humidity for the interaction of high-velocity aerosols with dust particles of different sizes, for differ, that is, kPM2.5 = 2:1, kPM10 = 3.5:1 and kPM20 = 1.5:1. The optimal humidity increases with the relative velocity U between the fog and dust particles in the high-speed airflow. The larger the collision angle is, the lower the wetting rate is.The smaller the contact angle between the solid and liquid is, the better droplet wetting on dust is. The fine kinetic mechanism of single-particle fog-dust collision-coupling in a high-speed airflow is elucidated in this study.
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Polvo , Polvo/análisis , Tamaño de la Partícula , Simulación por Computador , Humedad , Aerosoles/análisisRESUMEN
The fine chemical industry is currently facing challenges in energy saving, material conservation, and pollution reduction due to the dual policy pressure of precise system management and collaborative pollution and carbon reduction. However, the interweaving of materials and energy input-output was not well understood due to the incomplete coverage and the lack of a generic framework. Therefore, a methodology based on the energy-material-pollution (E-M-P) coupling nexus was proposed to quantitatively assess multi-level coupling. According to the selected generic 32 coupling units, two representative glyphosate (PMG) production processes were taken as case studies. Quantification results showed that the solvent element and the material system had a higher priority. Moreover, Process 2 owned a greater optimization potential as the coupling relationship pairs were 2.55 compared to 2.32 for Process 1, and the correlation proportions of material systems reached 69.26 % and 56.92 %, respectively. In addition, assessment results indicated that Process 2 was more environmentally friendly because of the lower ecological indexes (9.7 GPt vs. 15.8 GPt) and weaker carbon footprint (CF) (1.16E+08 vs. 2.32E+08). Combined coupling nexus and environmental assessment organically, methanol had the most optimization potential and was beneficial for the measures such as solvent substitution. This work offered theory and practice guidance with demonstrative value to support the sustainable development of precise system management.
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Volatile organic compounds (VOCs) are the dominant pollutants in industrial parks. However, they are not generally considered as part of the air quality index (AQI) system, which leads to a biased assessment of pollution in industrial parks. In this study, a supplementary assessment system of AQI-V was established by analyzing VOCs characteristics with vehicle-mounted PTR-TOFMS instrument, correlation analysis and the standards analysis. Three hourly and daily scenarios were considered, and the hierarchical parameter setting was further optimized by field application. The hourly and daily assessments revealed the evaluation factors for the discriminability of different air quality levels, practiced value for regional air quality improvement, and the reservation of general dominant pollutants. Finally, the universality testing in ZPIP successfully recognized most of the peaks, with 54.76%, 38.39% and 6.85% for O3, VOCs and NO2 as the dominant pollutant, and reflected the daily ambient air quality condition, together with the dominant pollutant. The AQI-V system with VOCs sub-index is essential for air quality evaluation in industrial parks, which can further provide scientific support to control the pollution of VOCs and the secondary pollutant, therefore significantly improve the air quality in local industrial parks.
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Contaminantes Atmosféricos , Contaminación del Aire , Contaminantes Ambientales , Compuestos Orgánicos Volátiles , Contaminantes Atmosféricos/análisis , Contaminación del Aire/prevención & control , Contaminación del Aire/análisis , Contaminantes Ambientales/análisis , Industrias , Aire/análisis , Compuestos Orgánicos Volátiles/análisis , Monitoreo del Ambiente , China , Material Particulado/análisisRESUMEN
To solve the problem of excessive dust concentration in the belt transportation roadway of the mine. Numerical simulations were used to study the dust migration in the belt transportation roadway under 1.5 m/s ventilation conditions. The simulation results show the process of dust ejection from the inflow chute to contamination of the whole belt transportation roadway, and the spatial distribution of dust velocity. A comprehensive dust reduction scheme of "central suppression and bilateral splitting" was designed according to the dust distribution, with simultaneous control of the infeed chute and the roadway. In practical application, pneumatic spraying greatly reduces the amount of dust in the guide chute. The misting screen has a significant effect on dust collection and segregation. The solution effectively controls the dust in the space of 20 m on both sides of the transfer point, and the dust removal efficiency reaches more than 90%.
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Polvo , Transportes , Polvo/análisis , Simulación por Computador , VentilaciónRESUMEN
For the problem of coal dust pollution in the return air lane of the comprehensive mining working face of soft rock mines.Based on the principle of supersonic siphon pneumatic atomization dust control, mobile vehicle-mounted pneumatic spraying combined with full-section fog curtain dust control technology is proposed to address the coal dust pollution problem in the return air tunnel of the comprehensive mining working face of soft rock mines. This technology has a wider spraying range, stronger wind resistance and lower energy consumption.Using the k-ε turbulence module and the fluid flow particle tracking module of COMSOL simulation software, a three-dimensional numerical model of the return air tunnel was established. The effect of wind flow characteristics on the diffusion range of coal dust and fog droplets was analysed, and the dust transport pattern and dust control effect of the new technology were obtained for different cross-sectional return airways. The results show that the velocity of the wind flow is continuously decayed by the slope, and the dust of different particle sizes is distributed differently by the inertial force. Coal dust with particle sizes larger than 6.5 µm accumulates below the structure at a lower velocity, and coal dust with particle sizes smaller than 4.5 µm is mostly suspended above the structure at a higher velocity. The device effectively stops the transport of dust and covers the whole section of the roadway, and the dust removal efficiency reaches 96.53%~97.93%, which provides relevant theoretical support and treatment means for the control of dust pollution in the return airway of coal mines.
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Minas de Carbón , Polvo , Polvo/análisis , Estudios Transversales , Carbón Mineral/análisis , TecnologíaRESUMEN
In order to solve the problem of coal dust pollution at the transfer point, a three-dimensional numerical model of wind flow-coal dust at the loading point of underground rubber run was established by computational fluid dynamics (CFD) discrete particle model and finite element method and k-ε turbulence model, and the coal dust diffusion pollution phenomenon caused by the coal flow transfer under the intersection of wind flow in the cross tunnel was studied. Based on the simulation results of wind flow velocity contour, pressure contour and isochronous flow vector distribution, the influence mechanism of wind flow and coal dust characteristics on the distribution of wind flow and coal dust diffusion in the roadway is analysed, and a dust control and reduction system and treatment scheme with new pneumatic screw spray technology as the core is proposed to suppress coal dust pollution at the reloading point. The results of the study show that the wind flow distribution is mainly influenced by the intersection of tape traction and cross-roadway wind flow, showing a complex multi-layer distribution along the roadway and in the normal direction; the diffusion of coal dust of different particle sizes is influenced by the roadway wind flow, and coal dust with particle sizes in the range of 10µm~20µm is more easily diffused, and the dust with particle sizes in the range of 20µm~45µm is mainly collected and suspended near the vortex wind flow at the cross-roadway. The coal dust in the range of 20 µm~45 µm is more likely to gather in the vortex; the treatment system effectively controls the coal dust inside the dust cover, and the spiral-shaped transported droplet particle group formed by the pneumatic spiral spray combines with it efficiently, which verifies the dust control and reduction effect of the pneumatic spiral spray system at the transfer point, and the dust removal efficiency reaches 89.35%~93.06%, which provides relevant theoretical support for the treatment of dust pollution at the coal transfer point in underground coal mines It provides the theoretical support and means to control dust pollution at underground coal transfer points.
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Minas de Carbón , Carbón Mineral , Carbón Mineral/análisis , Minas de Carbón/métodos , Polvo/análisis , Minerales , Tamaño de la Partícula , TecnologíaRESUMEN
The structural characteristics of coal at the molecular level are important for its efficient use. Bituminous coal from the Baozigou Coal Mine is investigated, using elemental analysis, 13C nuclear magnetic resonance, X-ray photoelectron spectroscopy, and Fourier transform infrared. The molecular structure was determined. The aromatic compounds of bituminous coal molecules are primarily two- and three-ring structures, and the aliphatic structures are primarily in the form of methyl, ethyl side chains, and naphthenic hydrocarbons. The ratio of aromatic bridge carbon to peripheral carbon in the molecular structure is 0.279. Oxygen atoms in the form of carbonyl, phenolic hydroxyl and C-O, and nitrogen atoms in pyrroles. Thus, the average structure model of bituminous coal macromolecules was constructed; the molecular formula was C169H128O10N2S, and the molecular weight was 2378. The aromatic structural units in the macromolecular structure of coal include four naphthalenes, three anthracenes, two tetracenes, and heteroatoms in the form of three carbonyl groups, one phenolic hydroxyl group, one pyrrole, and one pyridine. The structure optimization and annealing kinetic simulation of a single macromolecular structure model were performed. Chemical bonds such as bridge bonds and aliphatic bonds were found to be twisted, and π-π interactions between the aromatic sheets in the molecule produced adjacent aromatic sheets. This arrangement tends to be approximately parallel, and the total energy decreases from 6713.401 to 2667.595 kJ/mol, among which the bond stretching energy and van der Waals energy dominate. We used 20 bituminous coal macromolecular models to construct aggregated structural models. After optimization by molecular dynamics simulation, the macromolecules were constrained by the surrounding molecules, and the sheet-like aromatic carbon structures that were originally approximately parallel were distorted. The macromolecular structure model of bituminous coal constructed in this study provides a theoretical model basis for the optimal surfactant.
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To improve the efficiency of coal dust removal by water spray technology, the addition of wetting agents in water becomes the main dust removal method. The influence of sodium dodecyl sulfate (SDS), sodium dodecyl sulfonate (SDDS), and sodium dodecylbenzene sulfonate (SDBS) on the wettability of coal dust is studied by experimental and molecular dynamics (MD) simulation. Measurement of the contact angle and surface tension was accomplished via relevant experiments for the three wetting agents, and their adhesion work, spreading work, and wetting work were also calculated. A preferred experimental method of conventional coal dust wetting agent is optimized. The wettability of the three wetting agents upon bituminous coal follows the trend: SDS > SDDS > SDBS. The simulation was performed based on MD to derive the intermolecular interaction energy, diffusion coefficient of water molecules, and water molecule count in the vicinity of the hydrophilic groups of the wetting agents. The wetting mechanism and performance of the wetting agent solution on bituminous coal were identified. The simulation results of the wetting performance of the wetting agents are consistent with the experimental results, which verifies the reliability of the simulation method. An easy, time-saving, and labor-saving MD simulation method is proposed, which provides a novel insight for choosing various wetting agents of coal dust.
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Volatile organic compound (VOC) emission control and source apportionment in small-scale industrial areas have become key topics of air pollution control in China. This study proposed a novel characteristic factor and pattern recognition (CF-PR) model for VOC source apportionment based on the similarity of characteristic factors between sources and receptors. A simulation was carried out in a typical industrial area with the CF-PR model involving simulated receptor samples. Refined and accurate source profiles were constructed through in situ sampling and analysis, covering rubber, chemicals, coating, electronics, plastics, printing, incubation and medical treatment industries. Characteristic factors of n-undecane, styrene, o-xylene and propane were identified. The source apportionment simulation results indicated that the predicted contribution rate was basically consistent with the real contribution rate. Compared to traditional receptor models, this method achieves notable advantages in terms of refinement and timeliness at similar accuracy, which is more suitable for VOC source identification and apportionment in small-scale industrial areas.
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Contaminantes Atmosféricos , Compuestos Orgánicos Volátiles , Contaminantes Atmosféricos/análisis , Monitoreo del Ambiente/métodos , Industrias , Tecnología , Compuestos Orgánicos Volátiles/análisisRESUMEN
[This corrects the article DOI: 10.1021/acsomega.1c05422.].
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To solve the problem of the inability of traditional spray dust removal technology to efficiently restrain dust diffusion at the heading face, a multilayer spiral fog curtain dust control method based on spirally arranged pneumatic nozzles is proposed. In this paper, the k-É turbulence model and K-H droplet breakage model are used. First, different airflow fields are analyzed by simulating the simultaneous injection of different numbers of nozzles, and the motion law of airflow interaction is obtained. Taking the two-layer fog curtain as an example, a multiphysical field coupling numerical simulation of the two-layer spiral fog curtain applied in the field is carried out, and the variation law of its velocity field distribution and particle motion characteristics is analyzed. A similar experimental platform is established to verify the effectiveness of the simulation results and the feasibility of the dust removal scheme. The simulation results show that the double helix arrangement will form a rotating airflow with the cutting arm as the axis to cover the whole roadway section and produce a double-layer spiral fog curtain. The water mist is fragmented into smaller fog droplets under the action of rotating airflow, which improves the dust catching effect of the fog curtain. Experiments show that the dust removal rate and efficiency of multilayer spiral fog curtains are obviously stronger than those of natural dust reduction and traditional spray. After 3 minutes, a dust concentration of approximately 470 mg/m3 can be reduced to less than 4 mg/m3. The average dust removal rates of total dust and exhaled dust were 2.600 mg/(m3.s) and 0.189 mg/(m3.s), respectively, and the dust removal efficiencies were 97.01% and 94.32%.
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Polvo , Agua , Simulación por Computador , DifusiónRESUMEN
To effectively solve the problem of dust pollution caused by the parallel double-belt transportation of coal in a coal preparation plant, taking the Huangyuchuan coal preparation plant as an example, a numerical model of the air flow-dust distribution was established by means of simulation. The flow lines between the strips of tape and the tail of the tape machine will gather, and there will be backflow on the right side of the 3001 tape and left side of the 3002 tape. Under the action of wind current, most of the dust particles larger than 10 µm are distributed in the range of 0-5 m on both sides of the tape; dust particles smaller than 10 µm spread to the entire preparation workshop. Combined with field test verification, dust pollution is mainly concentrated at the guide trough, the feed inlet, the rear of the machine, and the joint of the belt corridor. Based on this, a targeted spray dust reduction treatment plan is proposed. By measuring the dust concentration before and after the treatment of dust-polluted areas, it is proven that the dust reduction efficiency of this plan can reach more than 90%.
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Minas de Carbón , Polvo , Carbón Mineral/análisis , Polvo/análisis , Tecnología , TransportesRESUMEN
To solve the problem of poor dust wettability during coal mine dust treatment, sodium dodecyl sulfate (SDS) and alkyl glycoside (APG1214) were selected for compounding. An efficient, environmentally friendly, economical wetting agent was prepared. First, through molecular dynamics simulation studies, it was determined that the tail group C of SDS and APG1214 was adsorbed on the surface of bituminous coal, and the head groups S and O were adsorbed on the surface of water. The simulation result is found to be consistent with the surfactant solution dust removal theory, which proves the confidence of simulation. Then, by comparing the interaction of water-SDS and APG1214-bituminous coal and water-bituminous coal systems and the number of hydrogen bonds, the wetting mechanism of the SDS and APG1214 solution on bituminous coal was revealed. Finally, the surface tension, contact angle, and wetting time of different SDS and APG1214 solutions were determined by experiments and they decreased with decreasing mass fraction of SDS at the same concentration. The surface tension of the SDS and APG1214 solution and the number of micelles affected the wettability of bituminous coal. The optimal concentration of the SDS and APG1214 solution was 0.7%, and the optimal ratio was SDS/APG1214 = 1:3.
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The distribution of multiscale pores and fractures in coal and rock is an important basis for reflecting the capacity of fluid flow in coal seam seepage passages. Accurate extraction and qualitative and quantitative analysis of pore-fracture structures are helpful in revealing the flow characteristics of fluid in seepage channels. The relationship between pore and fracture connectivity can provide a scientific reference for optimizing coal seam water injection parameters. Therefore, to analyse the change in permeability caused by the variability in the coal pore-fracture network structure, a CT scanning technique was used to scan coal samples from the Leijia District, Fuxin. A total of 720 sets of original images were collected, a median filter was used to filter out the noise in the obtained images, and to form the basis of a model, the reconstruction and analysis of the three-dimensional pore-fracture morphology of coal samples were carried out. A pore-fracture network model of the coal body was extracted at different scales. Using the maximum sphere algorithm combined with the coordination number, the effect of different quantitative relationships between pore size and pore throat channel permeability was studied. Avizo software was used to simulate the flow path of fluid in the seepage channels. The change trend of the fluid velocity between different seepage channels was discussed. The results of the pore-fracture network models at different scales show that the pore-fracture structure is nonuniform and vertically connected, and the pores are connected at connecting points. The pore size distribution ranges from 104 µm to 9425 µm. The pore throat channel length distribution ranges from 4206 µm to 48073 µm. The size of the coordination number determines the connectivity and thus the porosity of the coal seam. The more connected pore channels there are, the larger the pore diameters and the stronger the percolation ability. During flow in the seepage channels of the coal, the velocity range is divided into a low-speed region, medium-speed region and high-speed region. The fluid seepage in the coal seam is driven by the following factors: pore connectivity > pore and pore throat dimensions > pore and pore throat structure distribution. Ultimately, the pore radius and pore connectivity directly affect the permeability of the coal seam.