RESUMEN
Employing porous structures is essential in high-performance electrochemical energy devices. However, obtaining uniform functional coatings on high-tortuosity structures can be challenging, even with specialized processes such as atomic layer deposition (ALD). Herein, a novel method for achieving a porous composite electrode for solid oxide fuel cells by coating La0.6 Sr0.4 Co0.2 Fe0.8 O3 -δ (LSCF) powders with ZrO2 using a powder ALD process is presented. Unlike conventional ALD, powder ALD can be used to fabricate extremely uniform coatings on porous electrodes with a thickness of tens of micrometers. The powder ALD ZrO2 coating is found to effectively suppress chemical degradation of the LSCF electrodes. The cell with the powder ALD coated cathode shows a 2.2 times higher maximum power density and 60% lower thermal degradation in activation resistance than the bare LSCF cathode cell at 700-750 °C. The result demonstrated in this study is expected to have significant implications for high-performance and durable electrodes in energy conversion/storage devices.
RESUMEN
Particle swarm optimization is implemented for the complete inverse design of multilayered optical filters. To achieve this, a model is designed to optimize the thickness and material of each layer, as well as the total number of layers, simultaneously. The performance of the model is evaluated by repeating the optimization process, enabling clarification of the effects of model parameters on the final output. The designed model is also demonstrated for the optimization of various optical filters, including bandstop filters, bandpass filters, and anti-reflection coatings. The results confirm that particle swarm optimization is capable of designing arbitrary optical filters that cannot be designed using conventional design theories.