1.
J Org Chem
; 89(11): 8178-8184, 2024 Jun 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38803054
RESUMEN
A red-light-activated phthalocyanine ruthenium complex has been designed as a catalyst for the bifunctionalization of styrene derivatives. The combination of a trifluoromethylation agent resistant to nucleophiles and various nucleophiles facilitates the concurrent incorporation of a trifluoromethyl group and various functional groups onto the double bond of the substrate. This reaction demonstrates the utility of mild, low-energy, and highly transmissive long-wavelength light for intricate molecular transformations in a one-pot procedure.