Quantification of radionuclide distribution and migration during Cu-(Fe)-sulphide mineral processing by alpha particle autoradiography.

Understanding the movement of radionuclides (RNs) between different mineral hosts during processing of base metal ores is critical for accurate modelling of RN deportment and optimisation of processes designed to reduce or eliminate RNs. Here, we demonstrate that spatially resolving quantitative alpha particle autoradiography combined with backscatter electron imaging and energy dispersive X-ray spectroscopy (EDS) can establish the correlation between alpha-emitting RNs (notably 226Ra and 210Po, daughters of the abundant 238U decay series) and certain minerals, in different stages of processing. This is achieved by locating the RNs to a specific mineral grain, the species of which can subsequently be identified using EDS. The mineralogy of RN-associated grains can then be compared with the mineral suite and relative abundances of the species within the sample, by relating how often each mineral is associated with alpha decay-events. In the processing of uranium-bearing copper ores, migration of alpha-emitting RN daughters of the 238U series were observed, and these RNs were demonstrated to correlate strongly with barite, bornite and covellite over other coexisting minerals.

Alpha particle autoradiography for high spatial resolution mapping of radionuclides.

An autoradiographic technique capable of determining the spatial location of radioactive isotopes within materials on the scale of micrometers is demonstrated in low-activity mineral samples, where the concentrations of radionuclides with short half lives is small and below the detection limits of current measurement techniques. The location of certain radionuclide species within samples with complex structures on the micron scale can yield valuable information, however current methods do not have the spatial resolution required for this purpose. We demonstrate the use of an autoradiographic emulsion to directly image alpha particle events in samples with low radionuclide concentrations, allowing spatial resolution of radionuclide locations on the order of several microns. Exposure over a long time period allows sufficient integration of decay events enabling analysis of samples with low activity but large area, (less than 1×10-4 Bq/mm2). The use of polarising filters to increase contrast between the alpha particle tracks and the substrate during imaging demonstrates the viability of the technique on samples with a complex structure.