1.
J Am Chem Soc
; 131(29): 9896-7, 2009 Jul 29.
Artículo
en Inglés
| MEDLINE
| ID: mdl-19580274
RESUMEN
The new cation [Sb(7)S(8)Br(2)](3+) has a double-cubane structure and forms as the [AlCl(4)](-) salt from the ionic liquid EMIMBr-AlCl(3) (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.