Enhanced Properties of 3-MHz Sliver-Mode Vibrators for Cardiac Probes With Alternating Current Poling for Pb(Mg1/3Nb2/3)O3-PbTiO3 Single Crystals.

We investigated the effects of alternating current poling (ACP) on the piezoelectric and dielectric properties of 3-MHz sliver mode (L13 mm × W0.10-0.25 mm × T0.48 mm) vibrators fashioned from Pb(Mg1/3Nb2/3)O3-0.30PbTiO3 (PMN-0.30PT) single crystal (SC) plate manufactured using the continuous-feeding Bridgman (CF-BM) method for cardiac probes. The ACP SC plate (L13 mm × W24 mm × T0.48 mm) exhibited ultrahigh dielectric permittivity ( εT33/ε0 ) and piezoelectric coefficient ( d33 ) of 9690 and 2920 pC/N, respectively. After array dicing, the SC slivers with widths of 0.10, 0.15, 0.20, and 0.25 mm were obtained, and their average εT33/ε0 values decreased from the SC plate εT33/ε0 by 45% (5330), 29% (6880), 19% (7840), and 15% (8240), respectively, possibly because of heat and mechanical damage during the dicing. A combination of the ACP and a postdicing direct current poling (ACP-DCP) recovered their εT33/ε0 values to 6050, 7080, 8140, and 8540, respectively. The sliver mode electromechanical coupling factors ( k'33 ) were confirmed to exceed 93% after the ACP-DCP process, which were more than 4% higher than those of DCP-DCP SC slivers. The measured impedance spectra indicated that the SC slivers with 0.10-0.20 mm in width showed no spurious mode vibration near the fundamental k'33 mode. We conclude that the ACP-DCP SC slivers maintained more enhanced piezoelectric and dielectric properties than the DCP-DCP samples. These results will have important implications for the commercial application of ACP technology to medical imaging ultrasound probes.

A Review on Alternating Current Poling for Perovskite Relaxor-PbTiO3 Single Crystals.

With the great success on verifying its effectiveness on relaxor-PbTiO3 (PT) single crystals (SCs), alternating current poling (ACP) has been taking a center as a new domain engineering method in the last few years. Compared with the conventional direct current poling (DCP), ACP enables enhanced piezoelectric and dielectric properties. In this article, research progress in ACP and perspectives are introduced. Initially, optimized conditions of ACP for relaxor-PT SCs and unsolved issues on polycrystalline ceramics and spurious modes are reviewed. Second, the ferroelectric domain size dependence of piezoelectricity associated with ACP is discussed. We hypothesize that a tradeoff between domain and domain wall contributions exists for high piezoelectricity, suggesting an optimum 109° domain wall size, which is presumably dependent on compositions, crystallographic symmetries, and domain configurations. Finally, crystals synthesized by a solid-state crystal growth (SSCG) method are briefly introduced due to their unprecedented piezoelectricity obtained by ACP ( d33  âˆ¼ 5500 pC/N). We hope that this work helps to grasp the current status of ACP and to guide future tasks to be studied.

A Review of Lead Perovskite Piezoelectric Single Crystals and Their Medical Transducers Application.

Piezoelectric materials have been developed since early 1900s and many research had been conducted on the composition and process to obtain higher piezoelectric constants ( d33 ). Within composition research, lead perovskite relaxor piezoelectric single crystals (SCs) of Pb(Mg1/3Nb2/3)O3-lead titanate PbTiO3 type have been actively studied since 1990s because of their outstanding pC/N compared with those of the conventional Pb(Zr,Ti)O3 ceramics. A major driving force of these SC research has been promoted by mass production of ultrasound transducers and array probes for medical diagnostic systems since early 2000s. However, higher d33 material and process research for these ultrasound devices are almost saturated. In this review article, we present a brief overview of the history, current situation, and future perspective of piezoelectric SCs. The authors believe that the main research in the next century is high d33 SCs with a high composition uniformity and low-energy SC growth methods, such as solid-state SC growth, low-loss SC transducer manufacturing technique, and improved poling process. This is a big technical challenge for all the scientists; however, the relatively large market of medical ultrasound has been expanded year by year, and we hope that the community is motivated to solve such technical problems in the near future.

Single-Beam Acoustic Tweezer Prepared by Lead-Free KNN-Based Textured Ceramics.

Acoustic tweezers for microparticle non-contact manipulation have attracted attention in the biomedical engineering field. The key components of acoustic tweezers are piezoelectric materials, which convert electrical energy to mechanical energy. The most widely used piezoelectric materials are lead-based materials. Because of the requirement of environmental protection, lead-free piezoelectric materials have been widely researched in past years. In our previous work, textured lead-free (K, Na)NbO3 (KNN)-based piezoelectric ceramics with high piezoelectric performance were prepared. In addition, the acoustic impedance of the KNN-based ceramics is lower than that of lead-based materials. The low acoustic impedance could improve the transmission efficiency of the mechanical energy between acoustic tweezers and water. In this work, acoustic tweezers were prepared to fill the gap between lead-free piezoelectric materials research and applications. The tweezers achieved 13 MHz center frequency and 89% -6 dB bandwidth. The -6 dB lateral and axial resolution of the tweezers were 195 µm and 114 µm, respectively. Furthermore, the map of acoustic pressure measurement and acoustic radiation calculation for the tweezers supported the trapping behavior for 100 µm diameter polystyrene microspheres. Moreover, the trapping and manipulation of the microspheres was achieved. These results suggest that the KNN-based acoustic tweezers have a great potential for further applications.

Lead-Free KNN-Based Textured Ceramics for High-Frequency Ultrasonic Transducer Application.

Environment-friendly lead-free piezoelectric materials with excellent piezoelectric properties are needed for high-frequency ultrasonic transducer applications. Recently, lead-free 0.915(K0.45Na0.5Li0.05)NbO3-0.075BaZrO 3-0.01(Bi0.5Na0.5)TiO3 (KNLN-BZ-BNT) textured piezo- electric ceramics have high piezoelectric response, superior thermal stability, and excellent fatigue resistance, which are promising for devices applications. In this work, the KNLN-BZ-BNT textured ceramics were prepared by the tape-casting method. Microstructural morphology, phase transition, and electrical properties of KNLN-BZ-BNT textured ceramics were investigated. High-frequency needle-type ultrasonic transducers were designed and fabricated with these textured ceramics. The tightly focused transducers have a center frequency higher than 80 MHz and a -6-dB fractional bandwidth of 52%. Such transducers were built for an f -number close to 1, and the desired focal depth was achieved by press-focusing technology associated with a set of customer design fixture. Its lateral resolution was better than [Formula: see text] by scanning a 15- [Formula: see text] tungsten wire target. These promising results demonstrate that the lead-free KNLN-BZ-BNT textured ceramic is a good candidate for high-frequency ultrasonic transducer applications.

Large Piezoelectric Strain with Superior Thermal Stability and Excellent Fatigue Resistance of Lead-Free Potassium Sodium Niobate-Based Grain Orientation-Controlled Ceramics.

Environment-friendly lead-free piezoelectric materials with high piezoelectric response and high stability in a wide temperature range are urgently needed for various applications. In this work, grain orientation-controlled (with a 90% ⟨001⟩c-oriented texture) (K,Na)NbO3-based ceramics with a large piezoelectric response ( d33*) = 505 pm V-1 and a high Curie temperature ( TC) of 247 °C have been developed. Such a high d33* value varies by less than 5% from 30 to 180 °C, showing a superior thermal stability. Furthermore, the high piezoelectricity exhibits an excellent fatigue resistance with the d33* value decreasing within only by 6% at a field of 20 kV cm-1 up to 107 cycles. These exceptional properties can be attributed to the vertical morphotropic phase boundary and the highly ⟨001⟩c-oriented textured ceramic microstructure. These results open a pathway to promote lead-free piezoelectric ceramics as a viable alternative to lead-based piezoceramics for various practical applications, such as actuators, transducers, sensors, and acoustic devices, in a wide temperature range.

Study on luminescence properties of Eu2+ in BaAl12O19 matrix.

Eu(2+)-doped BaAl12O19 phosphors were prepared using the sol-gel method, and their structure and luminescence properties were characterized by X-ray diffraction (XRD) analysis and fluorescence spectrometry. The results showed that a single hexagonal BaAl12O19 crystal structure was synthesized and the emission spectrum of BaAl12O19:Eu exhibited a broad asymmetric band from 375 to 600 nm, which was composed of three emission peaks at 438, 462, and 511 nm. The effects of crystallization temperature, Eu2+ concentration, and Al3+ content on the occupation of Eu2+ in three crystallographic positions were investigated. The emission intensity of 438 nm increased with increasing crystallization temperature, while the emission intensity of 462 and 511 nm increased with the increase of Eu2+ concentration and Al3+ content.

A gradational system for ferroelectric nanosized (Pb(0.7)Sr(0.3))TiO(3) particles.

Synchrotron radiation x-ray diffraction measurement was performed to investigate the size effect in ferroelectric nanosized (Pb(0.7)Sr(0.3))TiO(3) particles with various sizes ranging from 10 to 200 nm. The 200 and 002 Bragg reflections were separated using low energy synchrotron radiation x-rays. The peak profiles of the 002 reflections show a large broadening and asymmetry for all particle sizes compared with those of the 200 reflections. These anomalously wide and asymmetric peak profiles become marked for peaks with a large l. The aspect ratio of the lattice constants c/a and the atomic distance between the anions and cations decrease gradually in the vicinity of the surface of the particles, indicating that the asymmetrical profiles can be attributed to the formation of a gradational system.