1.
Chem Commun (Camb)
; 57(67): 8280-8283, 2021 Aug 28.
Artículo
en Inglés
| MEDLINE
| ID: mdl-34319322
RESUMEN
A rhodium-catalysed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent is reported. The developed catalytic system is further utilised for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments are conducted to elucidate the reaction mechanism.