A Review of Plant-Mediated ZnO Nanoparticles for Photodegradation and Antibacterial Applications.

This review focuses on the synthesis of plant-mediated zinc oxide nanoparticles (ZnO NPs) and their applications for antibacterial and photocatalytic degradation of dyes, thereby addressing the need for sustainable and eco-friendly methods for the preparation of NPs. Driven by the significant rise in antibiotic resistance and environmental pollution from dye pollution, there is a need for more effective antibacterial agents and photocatalysts. Therefore, this review explores the synthesis of plant-mediated ZnO NPs, and the influence of reaction parameters such as pH, annealing temperature, plant extract concentration, etc. Additionally, it also looks at the application of plant-mediated ZnO NPs for antibacterial and photodegradation of dyes, focusing on the influence of the properties of the plant-mediated ZnO NPs such as size, shape, and bandgap on the antibacterial and photocatalytic activity. The findings suggest that properties such as shape and size are influenced by reaction parameters and these properties also influence the antibacterial and photocatalytic activity of plant-mediated ZnO NPs. This review concludes that plant-mediated ZnO NPs have the potential to advance green and sustainable materials in antibacterial and photocatalysis applications.

Lutetium-Induced Ultrafine PtRu Nanoclusters with a High Electrochemical Surface Area for Direct Methanol Fuel Cells at Alleviated Temperatures.

PtRu alloys have been recognized as the state-of-the-art catalysts for the methanol oxidation reaction (MOR) in direct methanol fuel cells (DMFCs). However, their applications in DMFCs are still less efficient in terms of both catalytic activity and durability. Rare earth (RE) metals have been recognized as attractive elements to tune the catalytic activity, while it is still a world-class challenge to synthesize well-dispersed Pt-RE alloys. Herein, we developed a novel hydrogen-assisted magnesiothermic reduction strategy to prepare a highly dispersed carbon-supported lutetium-doped PtRu catalyst with ultrafine nanoclusters and atomically dispersed Ru sites. The PtRuLu catalyst shows an outstanding high electrochemical surface area (ECSA) of 239.0 m2 gPt-1 and delivers an optimized MOR mass activity and specific activity of 632.5 mA mgPt-1 and 26 A cmPt-2 at 0.4 V vs saturated calomel electrode (SCE), which are 3.6 and 3.5 times of commercial PtRu-JM and an order higher than PtLu, respectively. These novel catalysts have been demonstrated in a high-temperature direct methanol fuel cell running in a temperature range of 180-240 °C, achieving a maximum power density of 314.3 mW cm-2. The AC-STEM imaging, in situ ATR-IR spectroscopy, and DFT calculations disclose that the high performance is resulted from the highly dispersed PtRuLu nanoclusters and the synergistic effect of the atomically dispersed Ru sites with PtRuLu nanoclusters, which significantly reduces the CO* intermediates coverage due to the promoted water activation to form the OH* to facilitate the CO* removal.

Catalytic Properties of Biochar as Support Material Potential for Direct Methanol Fuel Cell: A Review.

With the evolution and emergence of compounding environmental problems and issues, renewable energy promises to be a sustainable future technology. One technology considered is the fuel cell, which thrives on the primary function of electrocatalytic activities. Thus this review article envisages and presents a comprehensive summary of the applications of activated carbonaceous material as supports for electrocatalysts in fuel cells. The different techniques utilized to produce these carbon materials are discussed in detail. The overview architecture and the principle of the operation of fuel cells are also addressed. Additionally, electrocatalysts and the importance of support materials, their characteristics, and the role they play in the performance of the electrocatalyst will be reviewed. Unfortunately, the carbon-support-based electrocatalyst suffers long-term instability due to corrosion. Previously, carbon black has been used as a carbon support in various fuel cells. In recent years, there has been progress in the incorporation of nanostructured carbon supports in electrocatalysts in various fuel cells; however, there is still a great deal of distance to cover for nanostructured carbon-supported electrocatalysts in fuel cells to realize full commercialization and large-scale industrial purposes due to shortcomings in electrocatalysts, which are low-cost and highly efficient. This review therefore discusses the progress of incorporation of biochar extracted from sugar cane bagasse as carbon support in electrocatalysts for direct methanol fuel cells with the intention to provide insight into the quest of producing highly efficient and low cost fuel cells.

Green synthesis of silica and silicon from agricultural residue sugarcane bagasse ash - a mini review.

Silicon dioxide (SiO2), also known as silica, has received attention in recent years due to wide range of capable applications including biomedical/pharmaceutical, energy, food, and personal care products. This has accelerated research in the extraction of materials from various agricultural wastes; this review investigates the extraction of silica and silicon nanoparticles from sugarcane bagasse ash with potential applications in electronic devices. Specific properties of silica have attracted the interest of researchers, which include surface area, size, biocompatibility, and high functionality. The production of silica from industrial agricultural waste exhibits sustainability and potential reduction in waste production. Bagasse is sustainable and environmentally friendly; though considered waste, it could be a helpful component for sustainable progress and further technological advancement. The chemical, biogenic and green synthesis are discussed in detail for the production of silica. In green synthesis, notable attempts have been made to replace toxic counterparts and decrease energy usage with the same quantity and quality of silica obtained. Methods of reducing silica to silicon are also discussed with the potential application-specific properties in electronic devices, and modern technological applications, such as batteries, supercapacitors, and solar cells.

Antibacterial and Photodegradation of Organic Dyes Using Lamiaceae-Mediated ZnO Nanoparticles: A Review.

The green synthesis of zinc oxide nanoparticles (ZnO NPs) using plant extracts has been receiving tremendous attention as an alternative to conventional physical and chemical methods. The Lamiaceae plant family is one of the largest herbal families in the world and is famous for its aromatic and polyphenolic biomolecules that can be utilised as reducing and stabilising agents during the synthesis of ZnO NPs. This review will go over the synthesis and how synthesis parameters affect the Lamiaceae-derived ZnO NPs. The Lamiaceae-mediated ZnO NPs have been utilised in a variety of applications, including photocatalysis, antimicrobial, anticancer, antioxidant, solar cells, and so on. Owing to their optical properties, ZnO NPs have emerged as potential catalysts for the photodegradation of organic dyes from wastewater. Furthermore, the low toxicity, biocompatibility, and antibacterial activity of ZnO against various bacteria have led to the application of ZnO NPs as antibacterial agents. Thus, this review will focus on the application of Lamiaceae-mediated ZnO NPs for the photodegradation of organic dyes and antibacterial applications.

A Review of the Green Synthesis of ZnO Nanoparticles Utilising Southern African Indigenous Medicinal Plants.

Metal oxide nanoparticles (NPs), such as zinc oxide (ZnO), have been researched extensively for applications in biotechnology, photovoltaics, photocatalysis, sensors, cosmetics, and pharmaceuticals due to their unique properties at the nanoscale. ZnO NPs have been fabricated using conventional physical and chemical processes, but these techniques are limited due to the use of hazardous chemicals that are bad for the environment and high energy consumption. Plant-mediated synthesis of ZnO NPs has piqued the interest of researchers owing to secondary metabolites found in plants that can reduce Zn precursors and stabilise ZnO NPs. Thus, plant-mediated synthesis of ZnO NPs has become one of the alternative green synthesis routes for the fabrication of ZnO NPs. This is attributable to its environmental friendliness, simplicity, and the potential for industrial-scale expansion. Southern Africa is home to a large and diverse indigenous medicinal plant population. However, the use of these indigenous medicinal plants for the preparation of ZnO NPs is understudied. This review looks at the indigenous medicinal plants of southern Africa that have been used to synthesise ZnO NPs for a variety of applications. In conclusion, there is a need for more exploration of southern African indigenous plants for green synthesis of ZnO NPs.

Electro-Design of Bimetallic PdTe Electrocatalyst for Ethanol Oxidation: Combined Experimental Approach and Ab Initio Density Functional Theory (DFT)-Based Study.

An alternative electrosynthesis of PdTe, using the electrochemical atomic layer deposition (E-ALD) method, is reported. The cyclic voltammetry technique was used to analyze Au substrate in copper (Cu2+), and a tellurous (Te4+) solution was used to identify UPDs and set the E-ALD cycle program. Results obtained using atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques reveal the nanometer-sized flat morphology of the systems, indicating the epitaxial characteristics of Pd and PdTe nanofilms. The effect of the Pd:Te ratio on the crystalline structure, electronic properties, and magnetic properties was investigated using a combination of density functional theory (DFT) and X-ray diffraction techniques. Te-containing electrocatalysts showed improved peak current response and negative onset potential toward ethanol oxidation (5 mA; -0.49 V) than Pd (2.0 mA; -0.3 V). Moreover, DFT ab initio calculation results obtained when the effect of Te content on oxygen adsorption was studied revealed that the d-band center shifted relative to the Fermi level: -1.83 eV, -1.98 eV, and -2.14 eV for Pd, Pd3Te, and Pd3Te2, respectively. The results signify the weakening of the CO-like species and the improvement in the PdTe catalytic activity. Thus, the electronic and geometric effects are the descriptors of Pd3Te2 activity. The results suggest that Pd2Te2 is a potential candidate electrocatalyst that can be used for the fabrication of ethanol fuel cells.

Solar Energy Materials-Evolution and Niche Applications: A Literature Review.

The demand for energy has been a global concern over the years due to the ever increasing population which still generate electricity from non-renewable energy sources. Presently, energy produced worldwide is mostly from fossil fuels, which are non-renewable sources and release harmful by-products that are greenhouses gases. The sun is considered a source of clean, renewable energy, and the most abundant. With silicon being the element most used for the direct conversion of solar energy into electrical energy, solar cells are the technology corresponding to the solution of the problem of energy on our planet. Solar cell fabrication has undergone extensive study over the past several decades and improvement from one generation to another. The first solar cells were studied and grown on silicon wafers, in particular single crystals that formed silicon-based solar cells. With the further development in thin films, dye-sensitized solar cells and organic solar cells have significantly enhanced the efficiency of the cell. The manufacturing cost and efficiency hindered further development of the cell, although consumers still have confidence in the crystalline silicon material, which enjoys a fair share in the market for photovoltaics. This present review work provides niche and prominent features including the benefits and prospects of the first (mono-poly-crystalline silicon), second (amorphous silicon and thin films), and third generation (quantum dots, dye synthesized, polymer, and perovskite) of materials evolution in photovoltaics.

Green Synthesis of Crystalline Silica from Sugarcane Bagasse Ash: Physico-Chemical Properties.

Sugarcane bagasse South Africa is an agricultural waste that poses many environmental and human health problems. Sugarcane bagasse dumps attract many insects that harm the health of the population and cause many diseases. Sugarcane ash is a naturally renewable source of silica. This study presents for the first time the extraction of nanosilica from sugar cane bagasse ash using L-cysteine hydrochloride monohydrate acid and Tetrapropylammonium Hydroxide. The structural, morphological, and chemical properties of the extracted silica nanoparticles was cross examined using XRD, FTIR, SEM, and TGA. SEM analysis presents agglomerates of irregular sizes. It is possible to observe the structure of nanosilica formed by the presence of agglomerates of irregular shapes, as well as the presence of some spherical particles distributed in the structure. XRD analysis has revealed 2θ angles at 20, 26, 36, 39, 50, and 59 which shows that each peak on the xrd pattern is indicative of certain crystalline cubic phases of nanosilica, similar to results reported in the literature by Jagadesh et al. in 2015. The crystallite size estimated by the Scherrer equation based on the aforementioned peaks for ca-silica and L-cys-silica for the extracted particles had an average diameter of 26 nm and 29 nm, respectively. Furthermore, it showed a specific surface area of 21.6511 m2/g and 116.005 m2/g for ca-silica and L-cys silica, respectively. The Infrared (IR) spectra showed peaks at 461.231 cm-1, 787.381 cm-1 and 1045.99 cm-1 which corresponds to the Si~O~Si bending vibration, the Si~O~Si stretch vibration, and the Si~O~Si stretching vibration, respectively. This confirms the successful extraction of nanosilica from sugar cane bagasse ash. TGA analysis has revealed that the as received sugarcane bagasse has high loss on ignition (LOI) of 18%, corresponding to the presence of the unburnt or partial burnt particles, similar to results reported by Yadav et al. This study has shown that sugar cane bagasse ash is a natural resource of silica which should be harnessed for industrial purposes in south Africa.

Pt-based (Zn, Cu) nanodendrites with enhanced catalytic efficiency and durability toward methanol electro-oxidation via trace Ir-doping engineering.

Pt-based alloy nanomaterials with nanodendrites (NDs) structures are efficient electrocatalysts for methanol oxidation reaction (MOR), however their durability is greatly limited by the issue of transition metals dissolution. In this work, a facile trace Ir-doping strategy was proposed to fabricate Ir-PtZn and Ir-PtCu alloy NDs catalysts in aqueous medium, which significantly improved the electrocatalytic activity and durability for MOR. The as-prepared Ir-PtZn/Cu NDs catalysts showed distinct dendrites structures with the averaged diameter of 4.1 nm, and trace Ir doping subsequently improved the utilization of Pt atoms and promoted the oxidation efficiency of methanol. The electrochemical characterizations further demonstrated that the obtained Ir-PtZn/Cu NDs possessed enhanced mass activities of nearly 1.23 and 1.28-fold higher than those of undoped PtZn and PtCu, and approximately 2.35 and 2.67-fold higher than that of Pt/C in acid medium. More excitingly, after long-term durability test, the proposed Ir-PtZn and Ir-PtCu NDs still retained about 88.9% and 91.6% of its initial mass activities, which further highlights the key role of Ir-doping in determining catalyst performance. This work suggests that trace Ir-doping engineering could be a promising way to develop advanced electrocatalysts toward MOR for direct methanol fuel cell (DMFC) applications.

Fabrication of polyoxometalate-modified palladium-nickel/reduced graphene oxide alloy catalysts for enhanced oxygen reduction reaction activity.

Designing advanced nanocatalysts for effectively catalyzing the oxygen reduction reaction (ORR) is of great importance for practical applications of direct methanol fuel cells (DMFCs). In this work, the reduced graphene oxide (rGO)-supported palladium-nickel (Pd-Ni/rGO) alloy modified by the novel polyoxometalate (POM) with Keggin structure (Pd-Ni/rGO-POM) is efficiently fabricated via an impregnation technique. The physical characterizations such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, inductively coupled plasma optical emission spectroscopy (ICP-OES), field emission scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (FESEM-EDX), and transmission electron microscopy (TEM) are utilized to confirm the structure, morphology, and chemical composition of the fabricated samples. The XRD results verify the formation of the POM-modified Pd8Ni2/rGO alloy electro-catalyst with the face-centered-cubic (fcc) structure and average crystallite size of 5.54 nm. The electro-catalytic activities of the nanocatalysts towards ORR in alkaline conditions are evaluated by cyclic voltammetry (CV), rotating disk electrode (RDE), and chronoamperometry (CA) analyses. The synthesized Pd8Ni2/rGO-POM nanomaterial shows remarkably greater ORR catalytic activity and better methanol resistance compared with the Pd8Ni2/rGO and Pd/rGO electro-catalysts. The promoted ORR activity of the Pd8Ni2/rGO-POM sample is attributed to the alloying of Pd and Ni components, the uniform scattering of Pd-Ni nanoparticles on rGO, and the alloyed catalyst being modified with POM. Moreover, these findings demonstrate that the resultant Pd8Ni2/rGO-POM material is attractive as a suitable and cost-effective cathodic catalyst for DMFCs, in which the decorated POMs play a vital role for the enhancement in the catalytic abilities of the nanocatalyst.

Experimental Demonstration of Dynamic Temperature-Dependent Behavior of UiO-66 Metal-Organic Framework: Compaction of Hydroxylated and Dehydroxylated Forms of UiO-66 for High-Pressure Hydrogen Storage.

High-pressure (700 MPa or ∼100 000 psi) compaction of dehydroxylated and hydroxylated UiO-66 for H2 storage applications is reported. The dehydroxylation reaction was found to occur between 150 and 300 °C. The H2 uptake capacity of powdered hydroxylated UiO-66 reaches 4.6 wt % at 77 K and 100 bar, which is 21% higher than that of dehydroxylated UiO-66 (3.8 wt %). On compaction, the H2 uptake capacity of dehydroxylated UiO-66 pellets reduces by 66% from 3.8 to 1.3 wt %, while for hydroxylated UiO-66 the pellets show only a 9% reduction in capacity from 4.6 to 4.2 wt %. This implies that the H2 uptake capacity of compacted hydroxylated UiO-66 is at least three times higher than that of dehydroxylated UiO-66, and therefore, hydroxylated UiO-66 is more promising for hydrogen storage applications. The H2 uptake capacity is closely related to compaction-induced changes in the porosity of UiO-66. The effect of compaction is greatest in partially dehydroxylated UiO-66 samples that are thermally treated at 200 and 290 °C. These compacted samples exhibit XRD patterns indicative of an amorphous material, low porosity (surface area reduces from between 700 and 1300 m2/g to ca. 200 m2/g and pore volume from between 0.4 and 0.6 cm3/g to 0.1 and 0.15 cm3/g), and very low hydrogen uptake (0.7-0.9 wt % at 77 K and 100 bar). The observed activation-temperature-induced dynamic behavior of UiO-66 is unusual for metal-organic frameworks (MOFs) and has previously only been reported in computational studies. After compaction at 700 MPa, the structural properties and H2 uptake of hydroxylated UiO-66 remain relatively unchanged but are extremely compromised upon compaction of dehydroxylated UiO-66. Therefore, UiO-66 responds in a dynamic manner to changes in activation temperature within the range in which it has hitherto been considered stable.