Phosphorus recycling from waste activated sludge using the hydrothermal platform: Recovery, solubility and phytoavailability.

To address the grand challenge of increasing the sustainability of wastewater treatment plants, hydrothermal carbonization was studied as a nutrient recovery platform, transforming sludge into a valuable hydrochar. Carbonization was achieved at different temperatures (200-300 °C) and durations (30-120 min). The highest mass recovery (73%) was observed in the lowest temperature, while the lowest (49%) was obsereved at the highest temperature. Under all reaction conditions, phosphorus recovery values exceeded 80%, with the dominated fraction of inorganic-P in the hydrochar being HCl-extractable. Although HCl-extractable P is considered a moderately labile P fraction, P phytoavailability assays indicate that sewage sludge hydrochar is an excellent source for P, surpassing soluble P, likely due to its slow-release nature. We postulate that polyphosphates constitute a significant portion of this P pool. Overall, we emphasize the benefits of using HTC as a circular economy approach to convert sludge into a valuable hydrochar.

Subcritical water extraction as a circular economy approach to recover energy and agrochemicals from sewage sludge.

Global population growth is creating severe pressure on wastewater treatment plants, and specifically on sludge management. Meanwhile, the global challenge of achieving food-security requires the development of green pest control practices that maximize crop productivity. The hydrothermal technology, using subcritical water as the conversion media has been intensively studied, mostly for energy recovery purposes. Here, we focused on the aqueous phase by-product of this process and studied the subcritical water extraction of sewage sludge to recover valuable agrochemicals, with high potential of pre-emergent herbicidal activity. Full characterization of hydrothermal extracts from different reaction temperatures (200-300 °C) and times (30-120 min) highlighted the formation of pyrazine derivatives. Seed germination bioassays with three different species suggested a positive correlation between reaction temperature and extract herbicidal activity. Moreover, differences in seed viability and final root elongation between the tested crop (Trriticum aestivum) and weeds (Lapidium sativum and Amaranthus palmeri) may indicate the competitive abilities that can play a key role in weed management. Our results suggest that subcritical water can be applied as a green solvent for extracting a valuable agrochemical from sewage sludge and improving the circular economy for wastewater treatment.