Production of a bio-magnetic adsorbent via co-pyrolysis of pine wood waste and red mud.

The efficient reduction of accumulated waste biomass and red mud by converting them into a value-added magnetic adsorbent is both difficult and tempting in terms of sustainability. This study focused on investigating the reaction mechanism of co-pyrolysis of different biomasses, including pine wood, cellulose, and lignin, with red mud at 500, 650, and 800 °C, and the comprehensive characterizations of the produced bio-magnetic particles. The performance of biomass and red mud based magnetic adsorbents is also evaluated, and their primary adsorption mechanisms for organic pollutants are revealed by using different organic model compounds. The samples produced at 800 °C showed the best performance. For example, the sample prepared using red mud and pine wood at 800 °C showed the highest adsorption capacity of ibuprofen, which was 21.01 mg/g at ∼pH 4.5, indicating strong π stacking interactions as the dominant adsorption mechanism. When compared to lignin-rich biomass, adsorbents composed of cellulose-rich biomass showed greater adsorption efficacy. The findings show that co-pyrolysis of biomass with red mud can reduce waste while also producing a flexible adsorbent that is magnetically separable and effective at absorbing different organic contaminants from water.

Biodiesel synthesis from swine manure.

This study demonstrates that the biodiesel (BD) from swine manure (SM) could be a promising way for large scale generation of biofuel. Also, the economic and environmental benefits of SM derived BD were evaluated. Transesterification of lipid contents extracted from the collected SM had low BD yield (14.2 wt%) using H2SO4 catalyst due to high acid value and impurities. However, thermo-chemical non-catalytic transesterification with a porous material showed 94.7 wt% yield of BD from the lipid in SM. Considering the current population of swine, the annual production of BD from SM was estimated. The SM derived BD could cover 19.7 and 46.8 wt% of BD currently produced in both Korea and the USA with the economic benefits of up to $96 million and $2.1 billion, respectively. The proposed approach also can save vast arable lands needed to cultivate oil-bearing feedstocks for BD production.

Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions.

A low-cost poly(ethyleneimine)-cobalt (PEI-Co) complex solution with high O2 absorption capacity (as high as 1.5 L O2 (STP)/L solution) was developed and used in a bio-mimetic system to produce high-purity O2 from air. An oxygen concentration greater than 99.6% was demonstrated.