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1.
Phys Chem Chem Phys ; 8(36): 4182-8, 2006 Sep 28.
Artículo en Inglés | MEDLINE | ID: mdl-16971986

RESUMEN

The dependence of the individual mean square displacement of rare gases in binary mixtures is studied by a combined experimental and theoretical approach. We show that the diffusion constant can be varied in a considerable range by changing the molar fractions of the mixtures. On the experimental side, NMR diffusion measurements are done on hyperpolarized 3He and 129Xe, mixed with several inert buffer gases, in the presence of a magnetic field gradient. The results are compared to diffusion coefficients obtained from atomistic molecular dynamics simulations based on Lennard-Jones type potentials of the corresponding gas mixtures, and to appropriate analytical expressions, yielding very good mutual agreement. This study is the first quantitative validation of the effects of the mutual interactions between gas particles on the individual diffusion properties. It is shown that the dependency of gas phase diffusion properties on the local chemical environment may not be neglected, e.g. in diffusion-controlled chemical reactions.


Asunto(s)
Mezclas Complejas/química , Gases/análisis , Gases/química , Espectroscopía de Resonancia Magnética/métodos , Modelos Químicos , Modelos Moleculares , Mezclas Complejas/análisis , Simulación por Computador , Difusión , Peso Molecular , Tamaño de la Partícula , Electricidad Estática
2.
Med Tr Prom Ekol ; (10): 36-40, 2005.
Artículo en Ruso | MEDLINE | ID: mdl-16315589

RESUMEN

First series of studies covered analysis of lecture with registering number of words and movements complementary to them. The series 2 determined occupational activities of college teacher, according to contemporary hygienic classification, as highly intensive work requiring physiologic and managerial correction.


Asunto(s)
Adaptación Fisiológica/fisiología , Salud Laboral , Enseñanza , Carga de Trabajo , Adulto , Fatiga/fisiopatología , Fatiga/psicología , Femenino , Humanos , Persona de Mediana Edad , Enfermedades Profesionales/fisiopatología , Enfermedades Profesionales/psicología , Estrés Psicológico/fisiopatología , Estrés Psicológico/psicología
3.
Med Tr Prom Ekol ; (10): 13-7, 2004.
Artículo en Ruso | MEDLINE | ID: mdl-15581084

RESUMEN

Experimental study covered females of three age groups and revealed variation differences in time of arbitrary rhythmichand movements (tapping-test) and of movents with fixed rhythm of response to light. Their difference is represented as additional time for associations between cortical centers in regulation of hand movements.


Asunto(s)
Mano/fisiología , Movimiento/fisiología , Periodicidad , Desempeño Psicomotor/fisiología , Adulto , Femenino , Humanos , Persona de Mediana Edad
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