Astrobiological stoichiometry.

Chemical composition affects virtually all aspects of astrobiology, from stellar astrophysics to molecular biology. We present a synopsis of the research results presented at the "Stellar Stoichiometry" Workshop Without Walls hosted at Arizona State University April 11-12, 2013, under the auspices of the NASA Astrobiology Institute. The results focus on the measurement of chemical abundances and the effects of composition on processes from stellar to planetary scales. Of particular interest were the scientific connections between processes in these normally disparate fields. Measuring the abundances of elements in stars and giant and terrestrial planets poses substantial difficulties in technique and interpretation. One of the motivations for this conference was the fact that determinations of the abundance of a given element in a single star by different groups can differ by more than their quoted errors. The problems affecting the reliability of abundance estimations and their inherent limitations are discussed. When these problems are taken into consideration, self-consistent surveys of stellar abundances show that there is still substantial variation (factors of ∼ 2) in the ratios of common elements (e.g., C, O, Na, Al, Mg, Si, Ca) important in rock-forming minerals, atmospheres, and biology. We consider how abundance variations arise through injection of supernova nucleosynthesis products into star-forming material and through photoevaporation of protoplanetary disks. The effects of composition on stellar evolution are substantial, and coupled with planetary atmosphere models can result in predicted habitable zone extents that vary by many tens of percent. Variations in the bulk composition of planets can affect rates of radiogenic heating and substantially change the mineralogy of planetary interiors, affecting properties such as convection and energy transport.

Remote life-detection criteria, habitable zone boundaries, and the frequency of Earth-like planets around M and late K stars.

The habitable zone (HZ) around a star is typically defined as the region where a rocky planet can maintain liquid water on its surface. That definition is appropriate, because this allows for the possibility that carbon-based, photosynthetic life exists on the planet in sufficient abundance to modify the planet's atmosphere in a way that might be remotely detected. Exactly what conditions are needed, however, to maintain liquid water remains a topic for debate. In the past, modelers have restricted themselves to water-rich planets with CO2 and H2O as the only important greenhouse gases. More recently, some researchers have suggested broadening the definition to include arid, "Dune" planets on the inner edge and planets with captured H2 atmospheres on the outer edge, thereby greatly increasing the HZ width. Such planets could exist, but we demonstrate that an inner edge limit of 0.59 AU or less is physically unrealistic. We further argue that conservative HZ definitions should be used for designing future space-based telescopes, but that optimistic definitions may be useful in interpreting the data from such missions. In terms of effective solar flux, S(eff), the recently recalculated HZ boundaries are: recent Venus--1.78; runaway greenhouse--1.04; moist greenhouse--1.01; maximum greenhouse--0.35; and early Mars--0.32. Based on a combination of different HZ definitions, the frequency of potentially Earth-like planets around late K and M stars observed by Kepler is in the range of 0.4-0.5.