Strategy and Metrological Support for Indoor Radon Measurements Using Popular Low-Cost Active Monitors with High and Low Sensitivity.

Traditionally, for indoor radon testing, predominantly passive measurements have been used, typically applying the solid-state alpha track-etch method for long-term and the charcoal method for short-term measurements. However, increasingly, affordable consumer-grade active monitors have become available in the last few years, which can generate a concentration time series of an almost arbitrary duration. Firstly, we argue that consumer-grade monitors can well be used for quality-assured indoor radon assessment and consequent reliable decisions. Secondly, we discuss the requirements of quality assurance, which actually allow for reliable decision-making. In particular, as part of a rational strategy, we discuss how to interpret measurement results from low-cost active monitors with high and low sensitivity with respect to deciding on conformity with reference levels that are the annual average concentration of indoor radon. Rigorous analysis shows that temporal variations in radon are a major component of the uncertainty in decision-making, the reliability of which is practically independent of monitor sensitivity. Manufacturers of low-cost radon monitors already provide sufficient reliability and quality of calibration for their devices, which can be used by both professional inspectors and the general public. Therefore, within the suggested measurement strategy and metrologically assured criteria, we only propose to clarify the set and values of the key metrological characteristics of radon monitors as well as to upgrade user-friendly online tools. By implementing clear metrological requirements as well as the rational measurement strategy for the reliable conformity assessment of a room (building) with radon safety requirements, we anticipate significant reductions in testing costs, increased accessibility, and enhanced quality assurance and control (QA/QC) in indoor radon measurements.

Degradation of RC Columns under Combined Exposure to Axial Loading, Stray Currents, and Chloride Ingress.

Coastal regions, home to a significant portion of the world's population, confront a formidable challenge: the corrosive impact of chloride-rich environments on vital infrastructure. These areas often host essential transportation systems, such as trains and metros, reliant on pre-existing electrical infrastructure. Unfortunately, complete isolation of this infrastructure is rarely feasible, resulting in the emergence of stray currents and electrical potentials that expedite corrosion processes. When coupled with conducive mediums facilitating chemical electrocell formation, the corrosion of reinforced concrete elements accelerates significantly. To combat this issue, international standards have been established, primarily focusing on augmenting the thickness of reinforcement bar covers and restricting stray voltage between rails and the ground. Nevertheless, these measures only provide partial solutions. When subjected to service loads, these elements develop cracks, especially when exposed to stray currents and chlorides, dramatically increasing corrosion rates. Corrosion products, which expand in volume compared to steel, exert internal forces that widen cracks, hastening the deterioration of structural elements. The study deals with the degradation of reinforced concrete columns under the combined action of loads, chloride-rich environments, and electrical voltage-simulating stray currents. In these conditions, degradation and reduction of load-bearing capacity accelerate compared to unloaded conditions, significantly amplifying the corrosion rate. Astonishingly, even in the absence of mechanical loads, stray currents alone induce tensile stresses in elements due to corrosion product formation, leading to longitudinal cracks parallel to the reinforcement bars.

Metrology for Indoor Radon Measurements and Requirements for Different Types of Devices.

Indoor radon measurements have been conducted in many countries worldwide for several decades. However, to date, there is a lack of a globally harmonized measurement standard. Furthermore, measurement protocols in the US (short-term tests for 2-7 days) and European Union countries (long-term tests for at least 2 months) differ significantly, and their metrological support is underdeveloped, as clear mathematical algorithms (criteria) and QA/QC procedures considering fundamental ISO/IEC concepts such as "measurement uncertainty" and "conformity assessment" are still absent. In this context, for many years, the authors have been advancing and refining the theory of metrological support for standardizing indoor radon measurements based on a rational criterion for conformity assessment within the ISO/IEC concepts. The rational criterion takes into account the main uncertainties arising from temporal variations in indoor radon and instrumental errors, enabling the utilization of both short- and long-term measurements while ensuring specified reliability in decision making (typically no less than 95%). The paper presents improved mathematical algorithms for determining both temporal and instrumental uncertainties. Additionally, within the framework of the rational criterion, unified metrological requirements are formulated for various methods and devices employed in indoor radon measurements.

A challenging path to rational and harmonised international regulation of indoor radon.

The main trends of indoor radon regulation in Europe are expressed through the standard ISO 11665-8. This standard, however, ignores the short-term tests (2-7 days in practice)-the main tests in the USA, and instead requires conducting long-term tests only (2-12 months)-without any justification. Moreover, the temporal (key) uncertainty of indoor radon is ignored altogether, a fact that does not allow the assessment of a room's conformity with a normative at a given reliability (usually 95%). Thus, the current international regulation is neither harmonised nor rational. This paper reports the interim results of storming discussions within the ISO 11665-8 Focus Group, in charge of revising the aforementioned standard. Proposed are the rational criterion for conformity assessment of a room with a normative for both short- and long-term measurements, as well as the indicative values and the algorithm for determining indoor radon temporal uncertainty depending on the measurement duration.

Short- versus long-term tests of indoor radon for risk assessment by Monte-Carlo method towards effective measurement strategy.

There now exists a broad consensus among the European radon community members that long-term measurements are the best practice in managing the risk of indoor radon exposure. This, not with standing the fact that <1% of buildings have been tested in Europe so far. At the same time, US' experience over the years shows more effective regulation has been accomplished through tests that are short-term. This study quantifies the uncertainty of collective risks obtained independently through short- and long-term measurements under the same conditions using the Monte Carlo method that takes into account the number of measurements, as well as the diversity of the spatial distribution of radon concentrations in representative samples of buildings. Simulation results have shown that contrary to the erroneous practice of the European radon community, the accuracy of the assessment of the collective risk due to radon exposure does not in fact depend on the duration of the indoor test at all. The main problem remains ensuring the existance of a representative sample of buildings, especially given limited number of tests. In this regard, recommended is a revision of the regulatory documents of IAEA, ICRP, WHO, and ISO focusing on (i) the principle of the effective measurement strategy based on rational ISO/IEC concepts, (ii) the mass measurements via short-term tests, and (iii) the societal engagement in measurements.

Temporal uncertainty versus coefficient of variation for rational regulation of indoor radon.

Significant temporal variations of radon and other air pollutants can be observed in any room, even one with permanently closed windows and doors. Therefore, a question arises: how can one assess the conformity of a room with a normative and make a reliable decision if the test lasts <1 year (days or months)? The measurement protocol fundamentally differs between Europe with its long-term testing tradition lasting several months, and the US where short-term tests of several days are more common. Neither the European nor the American protocols considers the temporal uncertainty of indoor radon, a factor that usually exceeds the instrumental uncertainty (including in long-term tests) and is 2-3 times higher the coefficient of variation (COV) commonly used to estimate temporal variations. This problem significantly complicates the creation of a rational and harmonized ISO standard. At the same time, strict adhering to the fundamental ISO/IEC rules within such concepts as "measurement uncertainty" and "conformity assessment" allows to control the coverage probability or reliability of decision making. Within ISO/IEC, proposed are a criterion of conformity assessment of a room with a normative for both short- and long-term measurements, as well as a statistical algorithm for determining the temporal uncertainty considering mode and measurements duration.

Acoustic Emission Monitoring of High-Strength Concrete Columns Subjected to Compressive Axial Loading.

Acoustic Emission (AE) nondestructive tests have attracted great interest for their use in the determination of structural properties and behavior of reinforced concrete (RC) elements. One of the applications this method can contribute to is in high-strength concrete (HSC) columns. These elements have a great advantage in the lower stories of high-rise buildings. However, the premature failure of the concrete cover and the brittleness nature of the failure is of a concern for engineers. This paper presents a study on the AE monitoring of HSC columns subjected to compressive axial loading. The study consists of four large-scale reinforced HSC columns with different confinement reinforcement and height. It is shown that the AE distributions in the columns are categorized by three stages. Moreover, the levels of loads reached at the first AE macro event are similar to the lower range levels of the nominal axial compressive strengths of the tested specimens, while the majority of macro AE events are located at the concrete cover. Based on the results of this study, AE monitoring can provide indications for the damage and load levels attained by reinforced high-strength concrete columns subjected to compressive axial loading.

Indoor radon regulation using tabulated values of temporal radon variation.

Mass measurements of indoor radon concentrations have been conducted for about 30 years. In most of the countries, a national reference/action/limit level is adopted, limiting the annual average indoor radon (AAIR) concentration. However, until now, there is no single and generally accepted international protocol for determining the AAIR with a known confidence interval, based on measurements of different durations. Obviously, as the duration of measurements increases, the uncertainty of the AAIR estimation decreases. The lack of the information about the confidence interval of the determined AAIR level does not allow correct comparison with the radon reference level. This greatly complicates development of an effective indoor radon measurement protocol and strategy. The paper proposes a general principle of indoor radon regulation, based on the simple criteria widely used in metrology, and introduces a new parameter - coefficient of temporal radon variation KV(t) that depends on the measurement duration and determines the uncertainty of the AAIR. An algorithm for determining KV(t) based on the results of annual continuous radon monitoring in experimental rooms is proposed. Included are indoor radon activity concentrations and equilibrium equivalent concentration (EEC) of radon progeny. The monitoring was conducted in 10 selected experimental rooms located in 7 buildings, mainly in the Moscow region (Russia), from 2006 to 2013. The experimental and tabulated values of KV(t) and also the values of the coefficient of temporal EEC variation depending on the mode and duration of the measurements were obtained. The recommendations to improve the efficiency and reliability of indoor radon regulation are given. The importance of taking into account the geological factors is discussed. The representativity of the results of the study is estimated and the approach for their verification is proposed.

The national survey of natural radioactivity in concrete produced in Israel.

The main goal of the current survey was to collect the results of the natural radiation tests of concrete produced in the country, to analyze the results statistically and make recommendations for further regulation on the national scale. Totally 109 concrete mixes produced commercially during the years 2012-2014 by concrete plants in Israel were analyzed. The average concentrations of NORM did not exceed the values recognized in the EU and were close to the values obtained from the Mediterranean countries such as Greece, Spain and Italy. It was also found that although the average value of the radon emanation coefficient of concrete containing coal fly ash (FA) was lower, than that of concrete mixes without FA, there was no significant difference between the indexes of both total radiation (addressing gamma radiation and radon together), and gamma radiation only, of the averages of the two sub-populations of concrete mixes: with and without FA.

Open charcoal chamber method for mass measurements of radon exhalation rate from soil surface.

Radon exhalation rate from the soil surface can serve as an important criterion in the evaluation of radon hazard of the land. Recently published international standard ISO 11665-7 (2012) is based on the accumulation of radon gas in a closed container. At the same time since 1998 in Russia, as a part of engineering and environmental studies for the construction, radon flux measurements are made using an open charcoal chamber for a sampling duration of 3-5 h. This method has a well-defined metrological justification and was tested in both favorable and unfavorable conditions. The article describes the characteristics of the method, as well as the means of sampling and measurement of the activity of radon absorbed. The results of the metrological study suggest that regardless of the sampling conditions (weather, the mechanism and rate of radon transport in the soil, soil properties and conditions), uncertainty of method does not exceed 20%, while the combined standard uncertainty of radon exhalation rate measured from the soil surface does not exceed 30%. The results of the daily measurements of radon exhalation rate from the soil surface at the experimental site during one year are reported.

New method and installation for rapid determination of radon diffusion coefficient in various materials.

The mathematical apparatus and the experimental installation for the rapid determination of radon diffusion coefficient in various materials are developed. The single test lasts not longer than 18 h and allows testing numerous materials, such as gaseous and liquid media, as well as soil, concrete and radon-proof membranes, in which diffusion coefficient of radon may vary in an extremely wide range, from 1·10(-12) to 5·10(-5) m(2)/s. The uncertainty of radon diffusion coefficient estimation depends on the permeability of the sample and varies from about 5% (for the most permeable materials) to 40% (for less permeable materials, such as radon-proof membranes).

Radon exhalation of hardening concrete: monitoring cement hydration and prediction of radon concentration in construction site.

The unique properties of radon as a noble gas are used for monitoring cement hydration and microstructural transformations in cementitious system. It is found that the radon concentration curve for hydrating cement paste enclosed in the chamber increases from zero (more accurately - background) concentrations, similar to unhydrated cement. However, radon concentrations developed within 3 days in the test chamber containing cement paste were approximately 20 times higher than those of unhydrated cement. This fact proves the importance of microstructural transformations taking place in the process of cement hydration, in comparison with cement grain, which is a time-stable material. It is concluded that monitoring cement hydration by means of radon exhalation method makes it possible to distinguish between three main stages, which are readily seen in the time dependence of radon concentration: stage I (dormant period), stage II (setting and intensive microstructural transformations) and stage III (densification of the structure and drying). The information presented improves our understanding of the main physical mechanisms resulting in the characteristic behavior of radon exhalation in the course of cement hydration. The maximum value of radon exhalation rate observed, when cement sets, can reach 0.6 mBq kg(-1) s(-1) and sometimes exceeds 1.0 mBq kg(-1) s(-1). These values exceed significantly to those known before for cementitious materials. At the same time, the minimum ventilation rate accepted in the design practice (0.5 h(-1)), guarantees that the concentrations in most of the cases will not exceed the action level and that they are not of any radiological concern for construction workers employed in concreting in closed spaces.

Utilization of industrial by-products for the production of controlled low strength materials (CLSM).

Industrial by-products were used for the production of controlled low-strength material (CLSM). CLSM, also known as 'flowable fill' is used as a replacement of compacted soil in cases where the application of the latter is difficult or impossible. The low mechanical requirements (compared with structural concrete) enable the use of industrial by-products for the production of CLSM. In this study cement kiln dust, asphalt dust, coal fly ash, coal bottom ash and quarry waste were tested for the possibility of producing CLSM with large proportions of those wastes. The results showed that in most cases, CLSM with good properties could be made with significant amounts of dust (25-50%w), especially when the dust has some cementing or pozzolanic potential as do fly ash and cement kiln dust.

Determination of the radon diffusion length in building materials using electrets and activated carbon.

This work presents a technique for determining the radon (222Rn) diffusion length in porous materials. A mathematical model that describes the process of radon diffusion in a closed chamber, divided into two sections by a porous building material, is proposed. The derived relations allow evaluating the radon diffusion length in the material from measurements of the radon concentrations in the two sections. Preliminary experimental results are presented for the diffusion lengths of concrete and gypsum obtained by measuring the radon concentration via two standard passive detection methods: electrostatic electret chambers and activated charcoal canisters. The electret measurements were checked by a solid state continuous radon monitor.