Assessing data in the informal e-waste sector: The Agbogbloshie Scrapyard.

The Old-Fadama-Scrapyard, better known as Agbogbloshie, is located in Accra, Ghana. Over the last 20 years, the area has developed into a large scrapyard, where the informal sector processes mainly electronic waste (e-waste) and scrap metals. However, unsafe treatment methods, such as the open burning of cables and foams, and the spilling of hazardous liquids onto the ground, cause environmental pollution and create health risks by releasing persistent organic pollutants (POPs) and heavy metals. There is a recognized lack in literature of data on e-waste mass and material flows due to the lack of applicable methods to measure e-waste quantities in an informally managed treatment system. However, to establish sustainable e-waste management, e-waste mass and material flow data are crucial prerequisites. Therefore, the material flow analysis (MFA) methodology is proposed as a means for data collection within a limited time frame in the informal e-waste recycling context. In this case study, mass and material flows of e-waste processed at Agbogbloshie were estimated using two different approaches: Firstly, the kind, measures, constitution of load and number of loaded entering and exiting vehicles was observed and documented, and second, to validate the data collected, the mass and material flow of e-waste treatment processes on site were observed and documented. The resulting annual mass flows range between 13,090 t/a and 17,094 t/a of e-waste. Based on the data for Ghana from the Global E-waste Monitor, an average of 15,092 t/a (approximately 39% of the Ghanaian e-waste generation) is treated in Agbogbloshie.

Optimizing the co-digestion supply chain of sewage sludge and food waste by the demand oriented biogas supplying mechanism.

Co-digestion of sewage sludge with food waste is a beneficial pathway for sewage plants to enhance their biogas yield. This paper employs hybrid programming with system dynamics simulation to optimize such a co-digestion system from the perspective of demand-oriented biogas supply chain, thus to improve the efficiency of the biogas utilization. The optimum operational parameters of the co-digestion system are derived from the simulation model. It is demonstrated that the demand-oriented biogas supply mechanism can be effectively driven under market-oriented incentive policy. For better compensation of the external cost to assist the operations of the co-digestion supply chain, it is suggested that the substrate collection and transportation subsidy should be combined with the renewables portfolio standard to be implemented as the optimum incentives. The limitations of the study are discussed to lay the foundation for future improvements.

What influences buffet leftovers at event caterings? A German case study.

In recent years, a growing number of investigations have examined food waste in the food service sector, in which the catering of individual events received little attention. We aimed to contribute to fill this knowledge gap by presenting insights from a case study based on data from 239 event caterings. The case study presents findings about the influences of four variables, namely event type, season, event size, and menu prices, on buffet leftovers. We used a waste tracking system that allowed kitchen staff to quantify buffet leftovers for 4 years: from the beginning of 2014 until the end of 2017. Among the studied variables, the event size demonstrated the strongest influence on the generation of buffet leftovers in the case study. Buffet leftovers showed a trend of decreasing quantities relative to the number of guests for increasing event sizes. For instance, smaller events with less than 100 participants recorded the highest quantities of approximately 280 g of buffet leftovers per guest, and larger events of more than 500 participants recorded the lowest quantities of approximately 74 g per guest. In addition, we found that three food product groups-meat & poultry, finger food, and side dishes-caused approximately 54% of the overall quantity of buffet leftovers and approximately 65% of the corresponding monetary equivalents. Our findings emphasize that further research is necessary on food waste reduction strategies.

Fate and impact of pharmaceuticals and personal care products during septage co-composting using an in-vessel composter.

The present study aimed at understanding the impact of pharmaceutical and personal care product (PPCP) load on compost dynamics and fate of PPCPs during the composting. In addition, the compost dynamics during single PPCP degradation and multiple PPCPs degradation were investigated. Results revealed that co-composting could degrade the pharmaceutical, carbamazepine (CBZ) up to 83% during single pollutant degradation while it was 66% during multiple pollutant system, at an initial concentration (IC) of 5 mg/kg dw. In case of personal care product, namely triclosan (TCS), single pollutant degradation resulted in 86% removal whereas the removal efficiency was 83% in multiple pollutant system. Relatively high concentration of CBZ showed a negative impact on compost dynamics compared to that of TCS. Higher IC resulted in lower temperature development and relatively lower pollutant removal. The study on pollutant transfer in compost solid surface and in leachate revealed that TCS was not leached out while the leaching of CBZ was significant during composting process. The various transformation products formed during composting were identified and tentative pathways for CBZ and TCS degradation were proposed.

Enhanced composting as a way to a climate-friendly management of coffee by-products.

This study investigated the performance of aerobic windrow systems by using coffee by-products and green waste to reduce gaseous emissions. Thereafter, a comparison with the current treatment and gaseous emissions at a Coffee Mill in Costa Rica was made. Two different studies where performed in Germany (pile I and II) and one study in a Coffee Mill in Costa Rica (pile III). Temperature, water content, and pH were the key parameters controlled over 35 days in all the systems. Moreover, CH4 emission rates were quantified by a FTIR and by a portable gas detector device where the emissions reached values 100 times higher when coffee by-products as a unique material for the composting process was used. Results show that highest emission rates during the composting process for pile I was 0.007 g(m2)-1 h-1, for pile II 0.006 g(m2)-1 h-1, and for pile III 3.1 g(m2)-1 h-1. It was found that CH4 emissions could be avoided if the mixture and the formation of the windrow piles were performed following the key parameter for composting, and the usage of additional material is used. With this, the reduction of CH4 emissions at the Mill in Costa Rica could be achieved in the future.

Spatio-temporal variation of septage characteristics of a semi-arid metropolitan city in a developing country.

Septage is the solid sludge that accumulates in septic tanks over a period of time. Many of the developing countries in the world face the challenging task of septage management. Due to the high variability in the nature of septage, there is a need to study its physical and chemical characteristics in order to suggest a sustainable treatment methodology. The present study deals with the characterization of septage collected from different locations of Chennai city in India, in two different seasons (summer and winter). The characterization includes parameters such as solids, organics, inorganics, nutrients and heavy metals. Septage showed significant difference in concentrations of pollutants from one season to the other (p > 0.05). The average total solids concentration is found to be 1.6 times higher during winter season than compared to summer season. Average concentrations of solids were 2185 ± 1070 and 3555 ± 2935 mg/L during summer and winter, respectively. Liquid characterization of septage showed total chemical oxygen demands (COD) of 905 ± 603 mg/L (summer) and 1460 ± 1295 mg/L (winter). Similarly, average soluble biochemical oxygen demand (sBOD) was found to be 117 ± 54 mg/L during summer and 211 ± 220 mg/L during winter season. Studies also showed that septage was rich in nutrients such as total nitrogen (4-500 mg/L), ammoniacal nitrogen (2-129 mg/L), total phosphate (5-236 mg/L) and heavy metals such as copper, zinc, lead and manganese. Overall characterization indicates that the collected septage samples are highly variable in nature with respect to sources, season and locations of collection. As the septage is rich in organic matter and nutrients, it can be used as a resource like soil conditioner or as a substitute for chemical fertilizer in agriculture, after proper treatment, leading to a new evolution in sanitation.

Anthropogenic Trace Compounds (ATCs) in aquatic habitats - research needs on sources, fate, detection and toxicity to ensure timely elimination strategies and risk management.

Anthropogenic Trace Compounds (ATCs) that continuously grow in numbers and concentrations are an emerging issue for water quality in both natural and technical environments. The complex web of exposure pathways as well as the variety in the chemical structure and potency of ATCs represents immense challenges for future research and policy initiatives. This review summarizes current trends and identifies knowledge gaps in innovative, effective monitoring and management strategies while addressing the research questions concerning ATC occurrence, fate, detection and toxicity. We highlight the progressing sensitivity of chemical analytics and the challenges in harmonization of sampling protocols and methods, as well as the need for ATC indicator substances to enable cross-national valid monitoring routine. Secondly, the status quo in ecotoxicology is described to advocate for a better implementation of long-term tests, to address toxicity on community and environmental as well as on human-health levels, and to adapt various test levels and endpoints. Moreover, we discuss potential sources of ATCs and the current removal efficiency of wastewater treatment plants (WWTPs) to indicate the most effective places and elimination strategies. Knowledge gaps in transport and/or detainment of ATCs through their passage in surface waters and groundwaters are further emphasized in relation to their physico-chemical properties, abiotic conditions and biological interactions in order to highlight fundamental research needs. Finally, we demonstrate the importance and remaining challenges of an appropriate ATC risk assessment since this will greatly assist in identifying the most urgent calls for action, in selecting the most promising measures, and in evaluating the success of implemented management strategies.

Determination of methane emission rates on a biogas plant using data from laser absorption spectrometry.

The aim of the work was to establish a method for emission control of biogas plants especially the observation of fugitive methane emissions. The used method is in a developmental stage but the topic is crucial to environmental and economic issues. A remote sensing measurement method was adopted to determine methane emission rates of a biogas plant in Rhineland-Palatinate, Germany. An inverse dispersion model was used to deduce emission rates. This technique required one concentration measurement with an open path tunable diode laser absorption spectrometer (TDLAS) downwind and upwind the source and basic wind information, like wind speed and direction. Different operating conditions of the biogas plant occurring on the measuring day (December 2013) could be represented roughly in the results. During undisturbed operational modes the methane emission rate averaged 2.8 g/s, which corresponds to 4% of the methane gas production rate of the biogas plant.

A new approach to estimation of methane emission rates from landfills.

Methane emission monitoring has become increasingly essential for diffusive area sources, especially for landfills, which contribute to a significant fraction of the total anthropogenic methane emission globally. Statutorily, methane emission rate from landfills in Germany shall be examined on a semiannual basis; however, an appropriate approach has yet to be developed and adopted for general use. In this study, a new method is proposed based on experimental results, which utilizes a TDLAS (Tunable Diode Laser Absorption Spectroscopy) instrument - GasFinder2.0 system and a dispersion model LASAT (Lagrangian Simulation of Aerosol Transport) as the measurement device and calculation model, respectively. Between April 2010 and December 2011, a research project was conducted at a pilot scale landfill in the south of Germany. Drawing on the extensive research into this pilot project, an effective strategy of measurement setup was determined. Methane concentration was measured with GasFinder2.0 system in the upstream and downstream sections of the project site, while wind and turbulence data were measured simultaneously by an ultrasonic anemometer. The average methane emission rate from the source can be calculated by using the results as input data in the dispersion model. With this method, site-specific measurement approaches can be designed for not only landfills, but also different diffusive area sources with less workload and lower cost compared to conventional FID (Flame Ionization Detector) method.

Assessment of pharmaceutical waste management at selected hospitals and homes in Ghana.

The practice of use and disposal of waste from pharmaceuticals compromises the safety of the environment as well as representing a serious health risk, as they may accumulate and stay active for a long time in the aquatic environment. This article therefore presents the outcome of a study on pharmaceutical waste management practices at homes and hospitals in Ghana. The study was conducted at five healthcare institutions randomly selected in Ghana, namely two teaching hospitals (hospital A, hospital B), one regional hospital (hospital C), one district hospital (hospital D) and one quasi-governmental hospital (hospital E). Apart from hospital E which currently has a pharmaceutical waste separation programmr as well as drug return programme called DUMP (Disposal of Unused Medicines Program), all other hospitals visited do not have any separate collection and disposal programme for pharmaceutical waste. A survey was also carried out among the general public, involving the questioning of randomly selected participants in order to investigate the household disposal of unused and expired pharmaceuticals. The results from the survey showed that more than half of the respondents confirmed having unused, left-over or expired medicines at home and over 75% disposed of pharmaceutical waste through the normal waste bins which end up in the landfills or dump sites.

Model-based predictions of anaerobic digestion of agricultural substrates for biogas production.

A modified Anaerobic Digestion Model No. 1 (ADM1), calibrated on a laboratory digester with a feeding mix of 30% weight of cow manure and 70% weight of corn silage, was implemented, showing its performances of simulation as a decision-making and planning-supporting tool for the anaerobic digestion of agricultural substrates. The virtual fermenter obtained was used to conduct simulations with different feeding compositions and loading rates of cow manure, corn silage, grass silage and rape oil. All simulations were started at the same initial state which was represented by a steady state with an organic loading rate of 2.5 kg ODM/(mdigester3∗d). The effects of the different feeding combinations on biogas composition and biogas yield were predicted reasonably, and partly verified with the available literature data. Results demonstrated that the simulations could be helpful for taking decisions on agricultural biogas plant operation or experimental set-ups, if used advisedly.

Energy or compost from green waste? - A CO(2) - based assessment.

Green waste is increasingly extracted from the material recycling chain and, as a result of the financial subsidy arising from the German renewable energy law for the generation of energy from renewable raw materials; it is fed into the energy recovery process in biomass power stations. A reduction in climate relevant gases is also linked to the material recovery of green waste - in particular when using composts gained from the process as a new raw material in different types of potting compost and plant culture media as a replacement for peat. Unlike energy recovery, material valorisation is not currently subsidised. Through the analysis of material and energy valorisation methods for green waste, with particular emphasis on primary resource consumption and CO(2)-balance, it could be determined that the use of green waste for energy generation and its recovery for material and peat replacement purposes can be considered to be on a par. Based on energy recovery or material oriented scenarios, it can be further deduced that no method on its own will achieve the desired outcome and that a combination of recycling processes is more likely to lead to a significant decrease of greenhouse gas emissions.