RESUMEN
The radiative forcing (RF) of carbon dioxide (CO2) is the leading contribution to climate change from anthropogenic activities. Calculating CO2 RF requires detailed knowledge of spectral line parameters for thousands of infrared absorption lines. A reliable spectroscopic characterization of CO2 forcing is critical to scientific and policy assessments of present climate and climate change. Our results show that CO2 RF in a variety of atmospheres is remarkably insensitive to known uncertainties in the three main CO2 spectroscopic parameters: the line shapes, line strengths, and half widths. We specifically examine uncertainty in RF due to line mixing as this process is critical in determining line shapes in the far wings of CO2 absorption lines. RF computed with a Voigt line shape is also examined. Overall, the spectroscopic uncertainty in present-day CO2 RF is less than 1%, indicating a robust foundation in our understanding of how rising CO2 warms the climate system.
RESUMEN
The far-infrared spectroscopy of the troposphere (FIRST) instrument is a Fourier-transform spectrometer developed to measure the Earth's thermal emission spectrum with a particular emphasis on the far-infrared. FIRST has observed the atmosphere from both the ground looking up and from a high-altitude balloon looking down. A recent absolute laboratory calibration of FIRST under ground-like operating conditions showed accuracy to better than 0.3 K at near-ambient temperatures (270-325 K) but reduced accuracy at lower temperatures. This paper presents calibration results for balloon-flight conditions using a cold blackbody to simulate the space view used for on-board calibration. An unusual detector nonlinearity was discovered and corrected, and stray light was measured and removed. Over most of the range of Earth scene temperatures (205-300 K), the accuracy of FIRST is 0.35-0.15 K (one sigma).
RESUMEN
The far-infrared spectroscopy of the troposphere (FIRST) instrument is a Fourier transform spectrometer developed to measure the Earth's thermal emission spectrum with a particular emphasis on far-infrared (far-IR) wavelengths greater than 15 µm. FIRST was developed under NASA's Instrument Incubator Program to demonstrate technology for providing measurements from 10 to 100 µm (1000 to 100 cm(-1)) on a single focal plane with a spectral resolution finer than 1 cm(-1). Presently no spectrometers in orbit are capable of directly observing the Earth's far-IR spectrum. This fact, coupled with the fundamental importance of the far-IR to Earth's climate system, provided the impetus for the development of FIRST. In this paper the FIRST instrument is described and results of a detailed absolute laboratory calibration are presented. Specific channels in FIRST are shown to be accurate in the far-IR to better than 0.3 K at 270 K scene temperature, 0.5 K at 247 K, and 1 K at 225 K.
