RESUMEN
For next-generation gas sensors, conductive polymers have strong potential for overcoming the existing deficiencies of conventional inorganic sensors based on metallic oxides. However, the signal of organic gas sensors is inferior to that of inorganic metal oxide gas sensors because of organic gas sensors' poor charge carrier transport. Herein, the combination of an organic transistor-type gas sensor and a zeolite with strong gas-adsorbing properties is proposed and experimentally demonstrated. Among the various investigated zeolites, ZSM-5 with â¼5.5 Å pore openings enhanced the adsorption for small gas molecules when combined with a polymer active layer, where it provided a pathway for gas molecules to penetrate the zeolite channels. Moreover, nitrided ZSM-5 (N-ZSM-5) enhanced the sensing performance of NO2 molecules selectively because N in the N-ZSM-5 framework strongly interacted with NO2 molecules. These results open the possibility for zeolite-modified organic gas sensors that selectively adsorb target gas molecules via heteroatoms substituted into the zeolite framework.
RESUMEN
A highly crystalline pomegranate-like base-acid bifunctional beta zeolite was successfully synthesized by the steam-assisted crystallization method using a basic nitrided N-beta as the starting material. The secondary crystal growth of a beta zeolite generating acid functionality occurred over the outer surface and intercrystalline void spaces of the N-beta zeolite. The pomegranate-like N-beta@H-beta zeolite had a high surface area and base-acid dual functionality because of the well-connected framework topologies of the H-beta and N-beta crystallites. The N-beta@H-beta zeolite exhibited a superior yield of benzylidenemalononitrile during the tandem deacetalization-Knoevenagel condensation of benzaldehyde dimethyl acetal and malononitrile compared to H-beta, N-beta, and their physical mixture. This is likely due to the isolated and balanced activity of the base- and acid-catalyzed reactions.
RESUMEN
We described a technology for immobilizing radioiodine in the sod-cages by the interzeolite transformation of iodine-containing LTA (zeolite A) and FAU (zeolites X and Y) into a sodalite (SOD) structure. The immobilization of iodine in the sod-cage was confirmed using diverse characterization methods including powder XRD, elemental analysis, SEM-EDS, 127I MAS NMR, and I 3d XPS. Although both zeolites A (Na-A) and X (Na-X) were well converted into SOD structure in the presence of NaI and AgI, the iodide anions were fixed in the sod-cages only when NaI was used. The ability to adsorb methyl iodide (CH3I) was evaluated for zeolites A and X in which Na+ and/or Ag+ ions were exchanged, and Ag+ and zeolite X showed better adsorption properties than Na+ and zeolite A, respectively. However, when both CH3I adsorption ability and the successive immobilization of iodine by interzeolite transformation were considered, Na-X was determined to be the best candidate of adsorbent among the studied zeolites. More than 98% of the iodine was successfully immobilized in the sod-cage in the SOD structure by the interconversion of Na-X following CH3I adsorption, although the Na-X zeolite exhibited half the CH3I adsorption capacity of Ag-X.